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The structure of BaSrR4O8 (where R = La, Nd, Sm, Gd, Eu, Dy, Ho, Y, Er, Tm, Yb, and Lu) has been investigated, and the X-ray reference patterns of these compounds have been prepared using the Rietveld refinement technique. BaSrR2O4 are isostructural to
The objective of this work is to model the grinding forces and the associated stress and deformation fields generated in a ceramic workpiece during surface plunge grinding. A two-dimensional finite element model is constructed with the grinding parameters
T Yalcin, William E. Wallace, Charles M. Guttman, L Li
We have developed a substrate-assisted laser desorption ionization (LDI) mass spectrometric method for polyethylene analysis where cobalt, copper, nickel, or iron metal powders are used as a sample substarte and silver nitrate is used as the cationization
We have studied single crystals of Β-Si 3N 4 with polarization-resolved Raman spectroscopy in order to unambiguously obtain the symmetry character of zone center optical phonon modes. By applying ultraviolet excitation radiation, approaching resonance
C E. Evans, A C. Smith, D J. Burnett, A L. Marsh, Daniel A. Fischer, J L. Gland
Polymer formation within ordered monolayer and thin-film assemblies is measured using fluorescence yield near edge spectroscopy (FYNES). This spectroscopic method measures soft X-ray absorption in the 270 to 330 eV energy range, probing core-electron
The advent of controlled polymerization, advanced electronics, biomimetic materials, nanostructured systems, and a range of other new avenues for polymeric materials has raised the bar for measurements and standards research. This report of the 2002
Li Ma, J Zhou, A Lau, Samuel R. Low III, Roland deWit
Indentation process of the Rockwell diamond indenter pressing into inelastic material is studies for the analysis, simulation and prediction of Rockwell hardness tests. The geometrical characteristics of the cone-spherical-shaped Rockwell indenter are
S A. Prosandeev, Eric J. Cockayne, Benjamin P. Burton
KTaO3-based solid solutions exhibit a variety of interesting physical phenomena. To better understand these phenomena, we performed first-principles calculations on [K1-x,Lix]TaO3 (KLT) and K[Ta1-xNbx]O3 (KTN) supercells. Our results show Li displacements
The mechanisms controlling normal and exaggerated grain growth in lead magnesium niobate - lead titanate (PMN - PT) ceramics have been investigated by varying the PbO-based liquid phase volume fraction, the PT content and the MgO stoichiometry. There is a
Sheng Lin-Gibson, D L. Brunner, David L. VanderHart, Barry J. Bauer, B M. Fanconi, Kathleen M. Flynn, William E. Wallace
Polyolefins, saturated hydrocarbon polymers such as polyethylene (PE) and polypropylene, are, by production volume, the most widely used of all A new method for the mass spectrometry of saturated polyolefins whereby an organic cation is covalently bonded
Christopher M. Stafford, C Harrison, Alamgir Karim, Eric J. Amis
We present a high-throughput technique for measuring the Young s modulus of thin polymer films. This technique exploits a strain-induced buckling instability observed in films supported on elastomeric substrates. By employing a combinatorial polymer film
Sheng Lin-Gibson, L Brunner, David L. VanderHart, Barry J. Bauer, B M. Fanconi, Charles M. Guttman, William E. Wallace
Previously a new method was introduced for the mass spectrometry of polyolefins whereby an organic cation is covalently bonded to the polymer to produce the necessary ionization for the creation of intact gas?phase macromolecules by matrix-assisted laser
C Y. Kim, Michael Bedzyk, E J. Nelson, Joseph Woicik, L E. Berman
We have measured the site-specific valence-electronic structure of α-Fe 2O 3 by using a spatially modulated X-ray standing wave as the excitation source for photoemission. Contributions to the valence band density of states from oxygen and iron ions are
Charles C. Han, Haonan Wang, K Shimizu, H W. Kim, Erik K. Hobbie, Z G. Wang
Non-linear structural dynamics in polymer blends can be expected when dual or multiple phase ordering processes co-exist. In a typical case of liquid-liquid phase separation (LLPS) and crystallization co-existence in polyolefin blends, linear dynamics of
The phase diagrams of the BaO-Gd 2O 3-CuO z and BaO-Er 2O 3-CuO z systems were determined at 0.1% O 2 (810 C) using special apparatus and a procedure for preparing carbonate-free precursors based on BaO. The handling of these atmospherically sensitive
Current applications of BaO-Y 2O 3-CuO x phase equilibria are focused on the use of coated conductor technology for fabrication of superconducting tape. Although such processing is typically carried out with carbonate-free high T c precursors, the majority
Current interest in polycrystalline ceramics having properties that reflect anisotopic characteristics inherent to their single crystal forms has led to development of new processing techniques for producing textured microstructures. One such technique is
The origin of tribochemistry is from the rubbing of surfaces together. The precise nature of the chemical reactions and the driving force behind the reactions are not known except for a few simple chemical systems. In boundary lubrication, it is difficult
Ni-base alloys are the most widely used superalloys in applications involving high temperatures and severe environmental conditions. To model the various processing steps used for these alloys, improvements in thermodynamic databases are required. These
We report on preparing assemblies of gold nanoparticles with continuous gradients in number density on flat silica-covered substrates. The methodology consists of: i) first forming a one dimensional molecular gradient of amino groups (-NH2) on the
Laser scanning confocal microscopy (LSCM) has been applied to examine the filler particles and their distribution in BaTiO3-polymer composite films. We have measured thin-slice images of the composite films at various depths from the film surface and
This paper describes studies of matrix-assisted laser desorption ionization time-of-flight mass spectrometry of polyethylene using metal powder as the matrix where initimate polymer/matrix mixing is not necessary.
L M. Dieng, A Y. Ignalov, T A. Tyson, Mark Croft, A Dogan, C Y. Kim, Joseph Woicik, J Grow
To ascertain the role of bromination in the recovery of superconductivity in underdoped YBa 2Cu 3O 6+y (YBCO) we have performed polarized multiple-edge x-ray absorption fine structure (XAFS) measurements on normal (y nearly equal to} 0.6) and brominated
L M. Dieng, T A. Tyson, Mark Croft, T Dogan, C Y. Kim, Joseph Woicik, J Grow, A Y. Ignatov
To understand the role of bromination in the recovery of superconductivity in underdoped YBCO, the spatially resolved local structural changes in brominated single crystals have been measured and compared to those in a normal crystal. In polarized x-ray
Igor Levin, Terrell A. Vanderah, T J. Coutts, S M. Bell
Phase equilibria and dielectric properties were analyzed for selected compositions in both LaCao 5ZrO.503-CaTiO3 (LCZ-CT) [email protected],O,-SrTiO3 (LCZ-ST) systems using X-ray powder diffraction and transmission electron microscopy. The end-memberLaCao.,Zro