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Displaying 1251 - 1275 of 1729

Crystal Structures and Reference Diffraction Patterns of BaSrR 4 O 8

September 1, 2002
Author(s)
Winnie K. Wong-Ng, James A. Kaduk, J Dillingham
The structure of BaSrR4O8 (where R = La, Nd, Sm, Gd, Eu, Dy, Ho, Y, Er, Tm, Yb, and Lu) has been investigated, and the X-ray reference patterns of these compounds have been prepared using the Rietveld refinement technique. BaSrR2O4 are isostructural to

Finite Element Simulation of Straight Plunge Grinding for Advanced Ceramics

September 1, 2002
Author(s)
Tze J. Chuang, S Jahanmir, Hai C. Tang
The objective of this work is to model the grinding forces and the associated stress and deformation fields generated in a ceramic workpiece during surface plunge grinding. A two-dimensional finite element model is constructed with the grinding parameters

Polarized Ultraviolet Raman Spectroscopy of B-Si 3 N 4

September 1, 2002
Author(s)
R Vogelgesang, M Grimsditch, Jay S. Wallace
We have studied single crystals of Β-Si 3N 4 with polarization-resolved Raman spectroscopy in order to unambiguously obtain the symmetry character of zone center optical phonon modes. By applying ultraviolet excitation radiation, approaching resonance

First Principles Studies of KnbO 3 , KtaO 3 and LiTaO 3 Solid Solutions

August 1, 2002
Author(s)
S A. Prosandeev, Eric J. Cockayne, Benjamin P. Burton
KTaO3-based solid solutions exhibit a variety of interesting physical phenomena. To better understand these phenomena, we performed first-principles calculations on [K1-x,Lix]TaO3 (KLT) and K[Ta1-xNbx]O3 (KTN) supercells. Our results show Li displacements

Grain Growth in Relaxor Ferroelectrics

August 1, 2002
Author(s)
J Blendell, Jay S. Wallace
The mechanisms controlling normal and exaggerated grain growth in lead magnesium niobate - lead titanate (PMN - PT) ceramics have been investigated by varying the PbO-based liquid phase volume fraction, the PT content and the MgO stoichiometry. There is a

MALDI MS Characterization of Covalent Cationized Polyethylene

August 1, 2002
Author(s)
Sheng Lin-Gibson, D L. Brunner, David L. VanderHart, Barry J. Bauer, B M. Fanconi, Kathleen M. Flynn, William E. Wallace
Polyolefins, saturated hydrocarbon polymers such as polyethylene (PE) and polypropylene, are, by production volume, the most widely used of all A new method for the mass spectrometry of saturated polyolefins whereby an organic cation is covalently bonded

MeasuringThe Modulus of Polymer Films by Strain-Induced Buckling Instabilities

August 1, 2002
Author(s)
Christopher M. Stafford, C Harrison, Alamgir Karim, Eric J. Amis
We present a high-throughput technique for measuring the Young s modulus of thin polymer films. This technique exploits a strain-induced buckling instability observed in films supported on elastomeric substrates. By employing a combinatorial polymer film

Optimizing the Covalent Cationization Method for the Mass Spectrometry of Polyolefins

August 1, 2002
Author(s)
Sheng Lin-Gibson, L Brunner, David L. VanderHart, Barry J. Bauer, B M. Fanconi, Charles M. Guttman, William E. Wallace
Previously a new method was introduced for the mass spectrometry of polyolefins whereby an organic cation is covalently bonded to the polymer to produce the necessary ionization for the creation of intact gas?phase macromolecules by matrix-assisted laser

Site-Specific Valence-Band Photoemission Study of A-Fe 2 O 3

August 1, 2002
Author(s)
C Y. Kim, Michael Bedzyk, E J. Nelson, Joseph Woicik, L E. Berman
We have measured the site-specific valence-electronic structure of α-Fe 2O 3 by using a spatially modulated X-ray standing wave as the excitation source for photoemission. Contributions to the valence band density of states from oxygen and iron ions are

The Nature and Origin of Tribochemistry

August 1, 2002
Author(s)
Stephen M. Hsu, J Zhang, Z Yin
The origin of tribochemistry is from the rubbing of surfaces together. The precise nature of the chemical reactions and the driving force behind the reactions are not known except for a few simple chemical systems. In boundary lubrication, it is difficult

Fabricating Planar Nanoparticle Assemblies With Number Density Gradients

July 1, 2002
Author(s)
R R. Bhat, Daniel A. Fischer, Jan Genzer
We report on preparing assemblies of gold nanoparticles with continuous gradients in number density on flat silica-covered substrates. The methodology consists of: i) first forming a one dimensional molecular gradient of amino groups (-NH2) on the

Investigation of Morphology and Interface in Polymer Composite Thin Films

July 1, 2002
Author(s)
C. K. Chiang, Li Piin Sung, R Popielarz
Laser scanning confocal microscopy (LSCM) has been applied to examine the filler particles and their distribution in BaTiO3-polymer composite films. We have measured thin-slice images of the composite films at various depths from the film surface and
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