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Bioscience

Biomaterials

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Displaying 726 - 750 of 3439

Structural origins of enhanced capacity retention in novel copolymerized sulfur-based composite cathodes for high-energy density Li-S batteries

September 17, 2015
Author(s)
Vladimir P. Oleshko, Jenny J. Kim, Jennifer L. Schaefer, Steven D. Hudson, Christopher L. Soles, Adam Simmonds, Jared Griebel, Kookheon Char, Jeff Pyun
Poly(sulfur-random-(1,3-diisopropenylbenzene) (poly(S-r-DIB)) copolymers synthesized via inverse vulcanization form high molecular mass electrochemically active polymers capable of realizing enhanced capacity retention (1005 mAh/g at 100 cycles) and

SYNTHESIS AND PROPERTIES OF THERMOPLASTIC POLYURETHANES WITH ISOSORBIDE CHAIN EXTENDER

August 28, 2015
Author(s)
Fan Zhang, Ivan Javni, Olivera Bili?, Nikola Bili? , Zoran S. Petrovic, Jan Ilavsky
Isosorbide, a renewable diol derived from starch, was used in combination with butane diol or alone as the chain extender in two series of thermoplastic polyurethanes with 50 and 70% soft segment concentration (SSC). Polyurethanes with 50% SSC based on

In-Situ Method for Measuring the Mechanical Properties of Nafion Thin Films during Hydration Cycles

August 15, 2015
Author(s)
Kirt A. Page, Jae W. Shin, Scott Eastman, Brandon W. Rowe, Sangcheol Kim, Ahmet Kusoglu, Kevin G. Yager, Gery R. Stafford
Perfluorinated ionomers, in particular Nafion, are an essential component in hydrogen fuel cells, as both the proton exchange membrane and the binder within the catalyst layer. During normal operation of a hydrogen fuel cell the ionomer will progressively

Field-based simulations of nanostructured polyelectrolyte gels

August 11, 2015
Author(s)
Debra J. Audus, Glenn Fredrickson
Nanostructured, responsive hydrogels composed of oppositely charged triblock copolymers with charged end-blocks and neutral, hydrophilic mid-blocks in aqueous solution were recently discovered. Due to electrostatic interactions, the end-blocks microphase

Heterogeneity and length scale effects in PEG-based hydrogels

August 10, 2015
Author(s)
Brian G. Bush, Jenna M. Shapiro, Frank W. DelRio, Robert F. Cook, Michelle L. Oyen
Colloidal-probe spherical indentation load-relaxation experiments are conducted on poly(ethylene glycol) (PEG) hydrogel materials to quantify the steady-state mechanical properties and time-dependent transport properties in a single experiment. A probe

Diff use interface methods for modeling drug eluting stent coatings

July 17, 2015
Author(s)
James A. Warren, David Saylor, Christopher Forrey, Changsoo Kim
An overview of diff use interface models specific to drug eluting stent coatings is presented. Microscale heterogeneities, both in the coating and use environment, dictate the performance of these coatings. Using diffuse interface methods, these

The evolution of carbon nanotube network structure in unidirectional nanocomposites resolved by quantitative electron tomography

June 23, 2015
Author(s)
Bharath NMN Natarajan, Noa Lachman, Thomas F. Lam, Douglas Jacobs, Christian J. Long, Minhua Zhao, Brian L. Wardle, Renu Sharma, James A. Liddle
Carbon nanotube (CNT) reinforced polymers are next-generation, high-performance, multifunctional materials with a wide array of promising applications. The successful introduction of such materials is hampered by the lack of a quantitative understanding of

Mesomorphic Pathway in Early Stage Crystallization of Polyethylene

June 18, 2015
Author(s)
Kalman D. Migler, Angela R. Hight Walker, Anthony P. Kotula
The kinetic pathway by which a molten polymer transforms into a multi-length scale semi-crystalline structure upon cooling is an unsolved problem in polymer physics, yet it is critical to the processing, properties and ultimate performance of these

Small-Angle X-ray Scattering of Ionic Liquids

June 1, 2015
Author(s)
Fan Zhang, Joshua A. Hammons, Jan Ilavsky
Small angle X-ray scattering (SAXS) is a powerful technique that is used to resolve the size and structure of phases on the nanometer scale, within a sample. While these features may also be observed with other techniques, such as: electron microscopy or
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