Skip to main content
U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

R Joseph Kline (Fed)

Research Interests

My research involves developing methods for X-ray metrology for complex 3D nanostructures for the semiconductor industry. I also develop methods for using soft and hard x-ray scattering to characterize the pattern shape and local chemistry in next generation lithographies such as directed-self assembly of block copolymers and extreme ultraviolet lithography. A method developed by our group called critical dimension small angle X-ray scattering (CDSAXS) was recently transferred to the semiconductor industry and is being used in memory fabs for characterizing high aspect ratio memory structures such as 3D-NAND. I am currently the project leader of the Metrology for Nanolithography project.

 

CDSAXS

Professional Service

Research Opportunities

National Research Council Postdoctoral Fellowship – Open to U.S. citizens with an annual stipend of $72,750 per year. Applications are due on either Feb. 1 or Aug. 1. Contact me if interested in an NRC post-doc for researching dimensional metrology for nanoelectronics, directed self-assembly of block copolymers, or X-ray scattering of polymers.

Selected Publications

  • “Buried Structure in Block Copolymer Films Revealed by Soft X-ray Reflectivity,” D.F. Sunday, J.L. Thelen, C. Zhou, J. Ren, P.F. Nealey, R.J. Kline, ACS Nano, 15, 6, 2021, 9577-9587 <Link>
  • “Influence of Additives on the Interfacial Width and Line Edge Roughness in Block Copolymer Lithography,” D.F. Sunday, X. Chen, T.R. Albrecht, D. Nowak, P.R. Delgadillo, T. Dazai, K. Miyagi, T. Maehashi, A. Yamazaki, P.F. Nealey, R.J. Kline, Chem. Mater. 32 (8), 2020, 2399-2407 <Link>
  • “X-ray characterization of contact holes for block copolymer lithography,” D.F. Sunday, F. Delachat, A. Gharbi, G. Freychet, C.D. Liman, R. Tiron, R.J. Kline, J. Appl. Cryst. 52 (1), 2019, 106-114 <Link>
  • “Metrology for the next generation of semiconductor devices,” N.G. Orji, M. Badaroglu, B.M. Barnes, C. Beitia, B.D. Bunday, U. Celano, R.J. Kline, M. Neisser, Y. Obeng, A.E. Vladar, Nature Electronics, 1 (10), 2018, 532-547 <Link>
  • "Determination of the Internal Morphology of Nanostructures Patterned by Directed Self Assembly," D.F. Sunday, M.R. Hammond, C. Wang, W.L. Wu, D.M. DeLongchamp, M. Tjio, J.Y. Cheng, J.W. Pitera, R.J. Kline, ACS Nano, 8 (8), 2014, 8426-8437 <Link>
  • "Molecular Origin of High Field-Effect Mobility in an Indacenodithiophene-Benzothiadiazole Copolymer," X. Zhang, H. Bronstein, A.J. Kronemeijer, J. Smith, Y. Kim, R.J. Kline, L.J. Richter, T.D. Anthopoulos, H. Sirringhaus, K. Song, M. Heeney, W. Zhang, I. McCulloch, D.M. DeLongchamp, Nature Comm. 4, 2013, 2238 <Link>
  • "Contact-induced crystallinity for high-performance soluble acene-based transistors and circuits," D. J. Gundlach, J. E. Royer, S. K. Park, S. Subramanian, O. D. Jurchescu, B. H. Hamadani, A. J. Moad, R. J. Kline, L. C. Teague, O. Kirillov, C. A. Richter, J. G. Kushmerick, L. J. Richter, S. R. Parkin, T. N. Jackson, and J. E. Anthony, Nature Materials 7 (3), (2008) 216-21 <Link>
  • "Liquid-Crystalline Semiconductoring Polymers with High-Charge Carrier Mobility," I. McCulloch, M. Heeney, C. Bailey, K. Genevicius, I. MacDonald, M. Shkunov, D. Sparrowe, S. Tierney, R. Wagner, W. Zhang, M.L. Chabinyc, R.J. Kline, M.D. McGehee, M.F. Toney, Nature Materials 5 (4), (2006) 328-333 <Link>
  • "Highly Oriented Crystals at the Buried Interface in Polythiophene Thin-Film Transistors," R.J. Kline, M.F. Toney, and M.D. McGehee, Nature Materials 5 (3), (2006) 222-228 <Link>

Awards

Publications

Acoustoelasticity, Theory and Experiment

Author(s)
L Jiang, Regis J. Kline, Y Yacobi, E Drescher-Krasicka
As a promising tool to characterize residual stress in engineering structural components, acoustoelasticity has been the subject of a great deal of research

X-Ray Metrology of Nanowire/ Nanosheet FETs for Advanced Technology Nodes

Author(s)
Madhulika S. Korde, Regis J. Kline, Daniel Sunday, Nick Keller, Subhadeep Kal, Cheryl Alix, Aelen Mosden, Alain C. Diebold
The three-dimensional architectures for field effect transistors (FETs) with vertical stacking of Gate-all-Around Nanowires provide a pathway to increased

Influence of Polymer Aggregation and Liquid Immiscibility on Morphology Tuning by Varying Composition in PffBT4T-2DT/Non-Fullerene Organic Solar Cells

Author(s)
Subhrangsu Mukherjee, Dean M. DeLongchamp, Regis J. Kline, Iain McCulloch, Zeinab Hamid, Andrew Wadsworth, Elham Rezasoltani, Sarah Holliday, Mohammed Azzouzi, Anne Guilbert, Yifan Dong, Marios Neophytou, Mark Little, Helen Bristow, Artem Bakulin, James Durrant, Jenny Nelson, Andrew A. Herzing
The temperature dependent aggregation behavior of PffBT4T polymers used in organic solar cells plays a critical role in the formation of a favorable morphology
Created October 9, 2019, Updated February 8, 2022