Instrument Purpose
To explore the "slow" atomic and molecular motions in condensed matter with sub-micro-electron volt precision, bridging the gap between structural and fast dynamics explored by Neutron Spin Echo and Time of Flight.
The NCNR Advantage
- Exceptional Energy Resolution: By utilizing a near-perfect backscattering geometry (𝜃 ≈ 90°), it achieves an energy resolution of < 1 eV, enabling the detection of molecular reorientations and diffusive motions occurring on nanosecond timescales.
- World-Leading Intensity: The HFBS is one of the highest-intensity instruments of its kind globally. It utilizes a unique Phase-Space Transformation (PST) chopper that provides a 4.2x gain in neutron flux, enabling the measurement of small samples or those with a weaker neutron scattering cross-section.
- Unmatched Dynamic Range: Features a high-speed Doppler-driven monochromator that extends the accessible energy transfer to ±50 μeV, more than that of typical reactor-based backscattering spectrometers.
- Low-Background Vacuum Design: Unlike most similar instruments, the entire scattering chamber operates under vacuum, significantly reducing air scattering and improving the signal-to-noise ratio for delicate biological and soft-matter samples.
Research Domains
- Liquids: Probing the diffusion, rotations and molecular relaxations in simple and glassy liquids.
- Polymers and Polymer Blends: Investigating segmental and chain dynamics as well as rotations and tunneling of side groups.
- Biological Systems: Internal motions of biomolecules along with the dynamics of surrounding hydration water. In membranes, lipid dynamics is probed, including molecular rotation, lateral diffusion, and thickness fluctuations.
- Chemical Physics: Investigating hydrogen storage materials, molecular tunneling, and the diffusion of water in nanoporous minerals (e.g., zeolites, clays).
- Energy Materials: Tracking ion hopping and diffusion mechanisms in solid-state battery conductors. Organic cation dynamics and proton/ion diffusion in perovskites.
- Magnetic Materials: Probing low-energy magnetic excitations.
What You Can Measure
- Quasielastic Neutron Scattering (QENS): Quantifying both diffusive and localized motions, as well as relaxation times.
- Fixed Window Scans (FWS): Identifying " transitions" as a function of temperature in materials (e.g., finding the onset of molecular dynamics and phase transitions).
- Inelastic Tunneling: Observing the quantum rotational tunneling of small molecules like methane or methyl groups.
Technical Specifications
| Parameter | Specification |
|---|
| Source Type | Cold Neutrons (NG-2 Guide) |
| Incident Energy (E0) | 2.08 meV |
| Wavelength (𝜆0) | 6.271 Å |
| Energy Resolution ΔE) | 0.8 𝜇eV to 1.0 𝜇eV (FWHM) |
| Dynamic Range | up to 35 𝜇eV |
| Momentum Transfer (Q) | 0.25 Å-1 to 1.75 Å-1 |
| Detector Array | 16 high-pressure 3He detectors covering 165° |
Specialized Sample Environments
- HFBS-Specific CCR: A dedicated top-loading Closed-Cycle Refrigerator (CCR) optimized for the HFBS geometry (3.4 K to 700 K).
- Cryostats: Liquid Helium "Orange" cryostats for ultra-low temperature studies down to 1.5 K. ICE dilution fridge insert can further lower temperatures down to 60mK.
- High-Temperature Furnaces: Specialized furnace for studying high-temperature diffusion and phase transitions up to 1675 K (requires niobium or titanium sample cans).
- Sample Containers: Standardized aluminum annular cans designed to minimize multiple scattering; flat plate sample holders for powders and films; Titanium cans for materials that react with aluminum; specialized pressure and gas-loading cells are also available.
- Goniometer-mounted sample stick: A motor-driven goniometer can be mounted on a sample stick, allowing measurements to be taken as a function of angle for crystal lattices and magnetic ordering.
Expertise & Support
- CHRNS Partnership: Jointly funded by NIST and the National Science Foundation (NSF), ensuring high-level support for a diverse national user community.
- The HFBS Science Team: Expert staff (e.g., Dr. Madhusudan Tyagi and Dr. Richard Azuah) provide deep expertise in quasi-elastic scattering analysis and molecular dynamics.
- Software & Data Analysis:
- DAVE: The NIST-developed "Data Analysis and Visualization Environment" is the primary suite for HFBS data reduction and fitting. https://www.ncnr.nist.gov/dave/
- NICE: Modern instrument control for automated quasi-elastic (fixed temperature) and fixed-window scans (temperature ramped).
Access & Resources
Instrument Contacts
madhusudan.tyagi [at] nist.gov (madhusudan[dot]tyagi[at]nist[dot]gov)
(301) 975-2046
richard.azuah [at] nist.gov (richard[dot]azuah[at]nist[dot]gov)
(301) 975-5604