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Displaying 1076 - 1100 of 2084

Impact of surface roughness on diffusion of confined fluids

October 17, 2011
Author(s)
William P. Krekelberg, Vincent K. Shen, Jeffrey R. Errington, Thomas M. Truskett
Using event-driven molecular dynamics simulations, we quantify how the self diffusivity of confined hard-sphere fluids depends on the nature of the confining boundaries. We explore systems with featureless confining boundaries that treat particle-boundary

In Situ Gas Phase Diagnostics for Titanium Nitride Atomic Layer Deposition

October 14, 2011
Author(s)
James E. Maslar, William A. Kimes, Brent A. Sperling
This report describes the performance of a technique for the simultaneous, rapid measurement of major gas phase species present during titanium nitride thermal atomic layer deposition involving tetrakis(dimethylamido) titanium (TDMAT) and ammonia. In this

Chromatographic Sample Collection from Two Phase (gas + liquid) Flows

October 12, 2011
Author(s)
Thomas J. Bruno, Bret Windom
A particularly challenging sample presentation in analytical chemistry is a flowing stream that consists of both a gas and liquid phase, in the situation in which an analysis is needed for both phases, separately. In these cases, the vapor and liquid must

High Frequency Characterization of Contact Resistance and Conductivity of Platinum Nanowires*

October 1, 2011
Author(s)
Kichul Kim, Paul Rice, Thomas M. Wallis, Dazhen Gu, SangHyun S. Lim, Atif A. Imtiaz, Pavel Kabos, Dejan Filipovic
Abstract— Individual platinum (Pt) nanowires (NWs) with 100 nm and 250 nm diameters, embedded in coplanar waveguide (CPW) structures are investigated. Three approaches for characterization of their contact resistance and conductivity at high frequencies

Compressed-Liquid Density Measurements of Methyl Oleate and Methyl Linoleate

September 30, 2011
Author(s)
Stephanie L. Outcalt
Compressed liquid densities of the fatty acid methyl esters methyl linoleate and methyl oleate have been measured with a vibrating-tube densimeter. The temperature and pressure range of the measured data is from 270 K to 470 K, and 0.5 MPa to 50 MPa. The

Reexamination of the C2H3+ microwave and infrared spectra

September 29, 2011
Author(s)
Jon T. Hougen, Laurent H. Coudert
The high-resolution infrared spectrum of C2H3 recorded in the 3 CH stretching region (J. Phys. Chem. 99 (1995) 15611-15623) is re-analyzed using an effective internal axis method (IAM) accounting for the large amplitude hydrogen migration motion. The

Reversed-Flow Chromatographic Determination of Binary Diffusion Coefficients

September 19, 2011
Author(s)
William S. McGivern, Jeffrey A. Manion
A reversed-flow chromatographic apparatus for the measurement of binary diffusion coefficients is described. Hydrocarbons are detected using flame ionization detection, and inert species can be detected by thermal conductivity. We have measured the binary

Construction of a High Power OPO Laser system for Differential Absorption LIDAR

September 13, 2011
Author(s)
Kevin O. Douglass, Stephen E. Maxwell, David F. Plusquellic, Joseph T. Hodges, Roger D. van Zee, Daniel V. Samarov, James R. Whetstone
Our goal is to develop and characterize optical measurement technology to enable accurate quantification of greenhouse-gas emissions to meet the needs of industry and regulators. A 1064 nm pumped high energy optical parametric oscillator (OPO) operating

On the electronic excited state dynamics of vibronic transitions. High resolution electronic spectra of acenaphthene and its argon van der Waals complex in the gas phase.

September 1, 2011
Author(s)
Leonardo Avarez-Valtierra, David F. Plusquellic, John T. Yi, David W. Pratt
Rotationally resolved fluorescence excitation spectroscopy has been used to study the dynamics, electronic distribution, and the relative orientation of the transition moment vector in several vibronic transitions of acenaphthene (ACN) and in its Ar van

Rotationally Resolved C2 Symmetric Conformers of Bis-(4-hydroxyphenyl)methane: Textbook Examples of Excitonic Coupling in the S1 and S2 Electronic States

September 1, 2011
Author(s)
Shin G. Chou, Chirantha P. Rodrigo, Christian Muller, Kevin O. Douglass, Timothy Zwier, David F. Plusquellic
Rotationally resolved microwave and ultraviolet spectra of jet-cooled bis-4 hydroxy)-diphenylmethane (b4HBM) have been obtained using Fourier-transform microwave and UV laser/molecular beam spectrometers. A recent vibronic level study of b4HPM1 has

Development of a Candidate Reference Measurement Procedure for the Determination of Phenytoin, Phenobarbital, Lamotrigine, and Topiramate in Human Serum Using Isotope-Dilution Liquid Chromotography/Tandem Mass Spectrometry

August 28, 2011
Author(s)
Susan Tai, Karen W. Phinney, Chia-Yi Yeh
Phenytoin (PHT), phenobarbital (PHB), lamotrigine (LTG), and topiramate (TPM) are some of the most widely used antiepileptic drugs (AEDs). Monitoring of their concentrations in serum is important for the treatment of epilepsy. A candidate reference

Electron-exchange assisted photon energy up-conversion in thin films of ?-conjugated polymeric composites

August 4, 2011
Author(s)
Panagiotis Keivanidis, Frederic Laquai, Joseph W. Robertson, Baluschev Stanislav, Josemon Jacob, Klaus Mullen, Gerhard Wegner
The mechanism of triplet-triplet annihilation (TTA) induced up-converted delayed luminescence is studied in two different binary organic systems consisting of platinum(II) octaethyl porphyrin mixed with either poly(fluorene) (PF26) or ladder-type

A fitting program for molecules with two inequivalent methyl tops and a plane of symmetry at equilibrium. Application to new microwave and millimeter-wave measurements in methyl acetate

July 25, 2011
Author(s)
Marcela Tudorie, Isabelle Kleiner, Jon T. Hougen, Sonia Melandri, Lilian Sutikdja, Wolfgang Stahl
A program for fitting the high-resolution torsion-rotation spectra of molecules having two inequivalent methyl rotors and a plane of symmetry at equilibrium is described and then applied to methyl acetate [CH3-O-C(=O)-CH3]. The G18 permutation-inversion

In Situ Gas Phase Measurements During Metal Alkylamide Atomic Layer Deposition

July 12, 2011
Author(s)
James E. Maslar, William A. Kimes, Brent A. Sperling
Metal alkylamide compounds, such as tetrakis(ethylmethylamido) hafnium (TEMAH), represent a technologically important class of metalorganic precursors for the deposition of metal oxides and metal nitrides via atomic layer deposition (ALD) or chemical vapor

Evaluating the characteristics of multiwall carbon nanotubes

July 1, 2011
Author(s)
John H. Lehman, M. Terrones, Elisabeth Mansfield, Katie Hurst, Vincent Muenier
During the past 20 years, multiwall carbon nanotubes (MWCNTs) have become an important industrial material. Hundreds of tons are produced each year. This review is a survey of the scientific literature, motivated by industrial requirements and guidelines

Mass Spectrometry Characterization for Chemoenzymatic Glycoprotein Synthesis

July 1, 2011
Author(s)
John E. Schiel, Mark S. Lowenthal, Karen W. Phinney
Glycoproteins exist as heterogeneous mixtures of glycoforms due to glycosylation at multiple sites with various glycans. The glycosylation pattern has significant implications for clinical diagnostics and biopharmaceutical development because it affects
Displaying 1076 - 1100 of 2084
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