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Displaying 101 - 125 of 188

Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18

October 30, 2015
Author(s)
Vladimir L. Orkin, James B. Burkholder, S. P. Sander, J. P. D. Abbatt D. Abbatt, J. R. Barker, Robert E. Huie, C E. Kolb, Michael J. Kurylo III, David M. Wilmouth, P. H. Wine
This is the eighteenth in a series of evaluated sets of rate constants, photochemical cross sections, heterogeneous parameters, and thermochemical parameters compiled by the NASA Panel for Data Evaluation. The data are used primarily to model stratospheric

SIMULATIONS TO CHARACTERIZE A PASSIVE MICROWAVE BLACKBODY DESIGN

July 29, 2015
Author(s)
Derek A. Houtz, Dave K. Walker, Dazhen Gu
This paper discusses the design of a microwave blackbody to be used as a primary laboratory standard for passive remote sensing applications. The design is required to have excellent performance over the frequencies ranging from 10 GHz to 220 GHz and will

High accuracy CO2 line intensities determined from theory and experiment

June 15, 2015
Author(s)
Joseph T. Hodges, Oleg L. Polyansky, Katarzyna E. Bielska, Melanie C. Ghysels, Lorenzo Lodi, N Zobov, Jonathan Tennyson
The atmospheric concentration of carbon dioxide (CO2), with its consequences for the greenhouse effect and climate change, is being closely monitored by a variety of space-borne and ground-based remote sensing experiments. These experiments require a

Application of the Hartmann-Tran profile to analysis of H2O spectra

June 9, 2015
Author(s)
D Lisak, A. Cygan, D Bermejo, J L. Domenech, Joseph T. Hodges, Ha Tran
The Hartmann-Tran profile (HTP), which has been recently recommended as a new standard in spectroscopic databases, is used to analyze spectra of several lines of H$_2$O diluted in N$_2$, SF$_6$, and in pure H$_2$O. This profile accounts for various

The impact of current CH4 and N2O atmospheric loss process uncertainties on calculated ozone abundances and trends

May 29, 2015
Author(s)
Vladimir L. Orkin, Eric L. Fleming, Christian George, Dwayne E. Heard, Charles H. Jackman, Michael J. Kurylo , Abdelwahid Mellouki , J B. Burkholder
The atmospheric loss processes of N2O and CH4, their estimated uncertainties, lifetimes, and impacts on ozone abundance and long-term trends are examined using atmospheric model calculations and updated kinetic and photochemical parameters and uncertainty

Design and Capabilities of NISTs Scale-Model Smokestack Simulator (SMSS)

April 17, 2015
Author(s)
Aaron N. Johnson, Joey T. Boyd, Eric Harman, Mohammad M. Khalil, Jacob E. Ricker, Christopher J. Crowley, Rodney A. Bryant, Iosif I. Shinder
The amount of CO 2 emitted from a coal-fired power plant (CFPP) is measured by continuous emissions monitoring systems (CEMS) permanently installed in the exhaust smokestack. Both the CO 2 concentration and the bulk flow are continuously measured by CEMS

Cavity ring-down spectrometer for high-fidelity molecular absorption measurements

April 1, 2015
Author(s)
Vincent T. Sironneau, Hong Lin, Zachary Reed, Joseph T. Hodges
We present a cavity ring-down spectrometer which was developed for near-infrared measurements of laser absorption by atmospheric greenhouse gases. This system has several important attributes that make it possible to conduct broad spectral surveys and to

Update on Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the Montreal Protocol, Chapter 1 in Scientific Assessment of Ozone Depletion: 2014, Global Ozone Research and Monitoring Project-Report No.55, 416 pp., World Meteorological Organiz

December 30, 2014
Author(s)
Lucy J. Carpenter, Stefan Reimann, Andreas Engel, Stephen Montzka, James B. Burkholder, Cathy Clerbaux, Bradley Hall, Shari A. Yvon-Lewis, Donald R. Blake, Marcel Dorf, Geoffre S. Dutton, Paul J. Fraser, Lucien Froidevaux, Fran?ois Hendrick, Jianxin Hu, Ashley Jones, Paul B. Krummel, Lambert J. Kuijpers, Michael J. Kurylo, Qing Liang, Emmanuel Mahieu, Jens M?hle, Simon O?Doherty, Keiichi Ohnishi, Vladimir L. Orkin, Klaus Pfeilsticker, Matt Rigby, Isobel J. Simpson, Yoko Yokouchi
Changes in the global atmospheric abundance of a substance are determined by the balance between its emissions and removal. Declines observed for ozone-depleting substances (ODSs) controlled under the Montreal Protocol are due to global emission reductions

Observations of Dicke narrowing and speed dependence in air-broadened CO2 lineshape near 2.06 um

November 3, 2014
Author(s)
Thinh Q. Bui, David Long, Agata Cygan, Vincent T. Sironneau, Daniel Hogan, Priyanka M. Rapusinghe, Mitchio Okumura
Frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) was used to study CO2 lineshapes in the (20013)←(00001) band centered near 2.06 um. Two rovibrational transitions were chosen for this study to measure non-Voigt collisional effects for air

Frequency-Comb-Based Remote Sensing of Greenhouse Gases over Kilometer Air Paths

October 29, 2014
Author(s)
Greg B. Rieker, Fabrizio R. Giorgetta, William C. Swann, Jonathan Kofler, Alexander M. Zolot, Laura C. Sinclair, Esther Baumann, Christopher L. Cromer, G. Petron, Colm Sweeney, P P. Tans, Ian R. Coddington, Nathan R. Newbury
We demonstrate frequency comb tooth-by-tooth measurements of atmospheric gas absorption across a 2-km, turbulent, open-air path through coherent dual-comb spectroscopy. High accuracy, high signal-to-noise transmission spectra are acquired spanning 5990 to

Photochemical Properties of Hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: Reactivity toward OH, IR Absorption Cross Sections, Atmospheric Lifetimes and Global Warming Potentials

September 22, 2014
Author(s)
Vladimir L. Orkin, Victor Khamaganov, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially fluorinated ethers, CH3OCF3 (kHFE-143a), CH3OCHF2 (kHFE-152a), and CHF2OCH2CF3 (kHFE-245fa), were measured using a discharge flow – electron paramagnetic resonance technique

Recommended isolated-line profile for representing high-resolution spectroscopic transitions

September 11, 2014
Author(s)
Joseph T. Hodges, Jonathan Tennyson, P F. Bernath, Alain Campargue, A Csaszar, L Daumont, R R. Gamache, D Lisak, Olga Naumenko, Lawrence Rothman, Ha Tran, N Zobov, Boone Chris, L Gianfrani, Jean M. Hartmann
Recommendations of an IUPAC Task Group formed in 2011 on “Intensities and line shapes in high-resolution spectra of water isotopologues from Experiment and Theory" (Project No. 2011-022-2- 100) on line profiles of high-resolution rotational-vibrational

Mid-Infrared Time-Resolved Frequency Comb Spectroscopy of Transient Free Radicals

June 10, 2014
Author(s)
Adam J. Fleisher, Bryce Bjork, Thinh Q. Bui, Kevin C. Cossel, Mitchio Okumura, Jun Ye
Quantitative measurements in chemical kinetics require unambiguous determinations of reactant, intermediate, and product concentrations on time scales faster than the reaction rate. Direct absorption spectroscopy in the mid-infrared (mid-IR) can fulfill
Displaying 101 - 125 of 188