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Displaying 576 - 600 of 1896

ROLE OF SALT ON ADHESION OF AN EPOXY/ALUMINUM (OXIDE) INTERFACE IN AQUEOUS ENVIRONMENTS

November 5, 2015
Author(s)
Kar T. Tan, Christopher C. White, Donald L. Hunston, Justin M. Gorham, Michael Imburgia, Aaron M. Forster, Vogt D. Bryan
Engineering joints consisting of polymer/inorganic interfaces are commonly exposed to less than ideal conditions during normal service; these environmental conditions present a significant challenge for maintaining the structural integrity of the interface

Detecting Carbon in Carbon: Application of Differential Charging to Obtain Information on the Chemical Identity and Spatial Location of Carbon Nanotube Aggregates in Composites by Imaging X-ray Photoelectron Spectroscopy

October 24, 2015
Author(s)
Justin M. Gorham, William A. Osborn, Jeremiah W. Woodcock, Keana C. Scott, John M. Heddleston, Angela R. Hight Walker, Jeffrey W. Gilman
The surface contributions and dispersion properties of multiwalled carbon nanotubes (MWCNT) within a composite are important measurements to perform on nano-enabled products in order to help answer environmental health and safety questions associated with

Applied Strain on Sealant Samples Exposed to Outdoor Weather

October 19, 2015
Author(s)
Christopher C. White, Donald L. Hunston, Kar tean Tan
In outdoor exposures used to establish durability of sealant formulations, applied strain is typically absent. It is a critical aspect of the in-service environment. This research employs two recently available techniques to examine how the presence of

Equilibrium Self-Assembly, Structure, and Dynamics of Clusters of Star-Like Micelles

October 17, 2015
Author(s)
Vivek M. Prabhu, Shrinivas Venkataraman, Yi Yan Yang, James Hedrick
Small-angle neutron scattering and static and dynamic light scattering have characterized the hierar-chical structure and dynamics of clusters of self-assembled star-like micelles formed by oligocarbonate-fluorene func-tionalized polyethylene glycol

Structural origins of enhanced capacity retention in novel copolymerized sulfur-based composite cathodes for high-energy density Li-S batteries

September 17, 2015
Author(s)
Vladimir P. Oleshko, Jenny J. Kim, Jennifer L. Schaefer, Steven D. Hudson, Christopher L. Soles, Adam Simmonds, Jared Griebel, Kookheon Char, Jeff Pyun
Poly(sulfur-random-(1,3-diisopropenylbenzene) (poly(S-r-DIB)) copolymers synthesized via inverse vulcanization form high molecular mass electrochemically active polymers capable of realizing enhanced capacity retention (1005 mAh/g at 100 cycles) and

SYNTHESIS AND PROPERTIES OF THERMOPLASTIC POLYURETHANES WITH ISOSORBIDE CHAIN EXTENDER

August 28, 2015
Author(s)
Fan Zhang, Ivan Javni, Olivera Bili?, Nikola Bili? , Zoran S. Petrovic, Jan Ilavsky
Isosorbide, a renewable diol derived from starch, was used in combination with butane diol or alone as the chain extender in two series of thermoplastic polyurethanes with 50 and 70% soft segment concentration (SSC). Polyurethanes with 50% SSC based on

Classification of Semiconducting Polymeric Mesophases to Optimize Device Post-Processing

August 17, 2015
Author(s)
Chad R. Snyder, Regis J. Kline, Dean M. DeLongchamp, Ryan C. Nieuwendaal, Lee J. Richter, Martin Heeney, Iain McCulloch
Semiconducting polymers form a variety of phases and mesophases that respond differently to post-deposition solvent or thermal treatments. Here it is shown that classification of these materials into their appropriate mesophases can be a useful tool to

In-Situ Method for Measuring the Mechanical Properties of Nafion Thin Films during Hydration Cycles

August 15, 2015
Author(s)
Kirt A. Page, Jae W. Shin, Scott Eastman, Brandon W. Rowe, Sangcheol Kim, Ahmet Kusoglu, Kevin G. Yager, Gery R. Stafford
Perfluorinated ionomers, in particular Nafion, are an essential component in hydrogen fuel cells, as both the proton exchange membrane and the binder within the catalyst layer. During normal operation of a hydrogen fuel cell the ionomer will progressively

Infrared Imaging and Spectroscopy Beyond the Diffraction Limit

July 22, 2015
Author(s)
Andrea Centrone
Progress in nanotechnology is enabled by and dependent on the availability of measurement methods with spatial resolution commensurate with nanomaterials’ length scales. Chemical imaging techniques, such as scattering scanning near-field optical microscopy

Aging of Polymeric Films used in Protective Glazing Systems

July 7, 2015
Author(s)
Christopher C. White, Donald L. Hunston, Kar T. Tan
The toughness of polymer and glass laminates or win-dow glazing, are used to protect buildings and occupants from shattered glass resulting from natural disasters (e.g., hurricanes, tornadoes, seismic events), and intentional events (e.g., robbery

Tuning Open-Circuit Voltage in Organic Solar Cells with Molecular Orientation

June 24, 2015
Author(s)
Brent Kitchen, Omar Awartani, Regis J. Kline, Terry McAfee, Harald Ade, Brendan T. O'Connor
The role of molecular orientation of a polar conjugated polymer in a polymer-fullerene organic photovoltaic (OPV) cells is investigated. A planar heterojunction (PHJ) OPV cell composed of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid

Mesomorphic Pathway in Early Stage Crystallization of Polyethylene

June 18, 2015
Author(s)
Kalman D. Migler, Angela R. Hight Walker, Anthony P. Kotula
The kinetic pathway by which a molten polymer transforms into a multi-length scale semi-crystalline structure upon cooling is an unsolved problem in polymer physics, yet it is critical to the processing, properties and ultimate performance of these
Displaying 576 - 600 of 1896
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