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Jon T. Hougen, Yueyue Zhao, Ha Vanh L. Nguyen, Wolfgang Stahl
The molecular beam Fourier-transform microwave spectrum of pinacolone (methyl tert-butyl ketone) has been measured in several regions between 4 and 40 GHz. Fits of the assigned spectrum using several computer programs based on different models for treating
A new hybrid-model fitting program for methylamine-like molecules has been developed, based on an effective Hamiltonian in which the ammonia-like inversion motion is treated using a tunneling formalism, while the internal-rotation motion is treated using
Coherent anti-Stokes Raman scattering (CARS) microspectroscopy has demonstrated significant potential for biological and materials imaging. To date, however, the primary mechanism of disseminating CARS spectroscopic information is through pseudocolor
The microwave spectrum of the molecular complex of sulfur dioxide (SO2) with carbon monoxide (CO) has been studied with a pulsed-beam Fourier Transform Microwave Spectrometer (FTMW) from a pair of gas samples of 1 % by volume of SO2 and CO in Ar, and
Aaron M. Katzenmeyer, Glenn E. Holland, Jungseok Chae, Alan H. Band, Kevin Kjoller, Andrea Centrone
An atomic force microscope equipped with temperature sensitive probes was used to measure locally the photothermal effect induced by IR light absorption. This novel instrument opens a pathway to correlated topographical, chemical composition, and thermal
The Annellation Theory was applied for the establishment of the locations of maximum absorbance for the p and β bands in the UV-Vis spectra of 8 benzenoid cata-condensed polycyclic aromatic hydrocarbons, PAHs, with molecular formula C26H16 and no available
Jungseok Chae, Basudev Lahiri, John M. Kohoutek, Glenn Holland, Henri Lezec, Andrea Centrone
Plasmonic nanostructures presenting either structural asymmetry or metal-dielectric-metal (M-D-M) architecture are commonly used structures to increase the quality factor and the near-field confinement in plasmonic materials. This characteristic can be
Metal-Organic Frameworks (MOFs) are three-dimensional coordination polymers that are well known for large pore surface area and their ability to adsorb molecules from both the gaseous and solution phases. In general, MOFs are electrically insulating, but
Justin M. Shaw, Daniel Hickstein, Franklin Dollar, Patrik Grychtol, Jennifer Ellis, Carlos Hernandez-Garcia, Ronny J. Knut, Christian Gentry, Henry Kapteyn, Margaret Murnane
We generate ultrashort pulses of angularly isolated, circularly polarized extreme ultraviolet (EUV) light through the first implementation of noncollinear high harmonic generation with circularly polarized driving lasers. The noncollinear geometry offers
Fabrizio R. Giorgetta, Greg B. Rieker, Esther Baumann, William C. Swann, Laura C. Sinclair, Jonathan Kofler, Ian R. Coddington, Nathan R. Newbury
Broadband atmospheric phase spectra are measured at sub-milliradian uncertainty corresponding to a 10-13 refractive index change, despite strong decoherence from atmospheric turbulence. A phase-sensitive dual-comb spectrometer acquires spectra over 233 cm
Richard W. Hendler, Curtis Meuse, David Travis Gallagher, Joerg Labahn, Jan Kubicek, Paul D. Smith, John W. Kakareka
It has long been known in spectroscopy that light not passing through a sample, but reaching the detector (i.e. stray light) results in a distortion of the spectrum known as absorption- flattening. In spectroscopy with crystals, one must either include
Muffin tin potentials are the standard tool for calculating the potential surface of a cluster of atoms for use in the analysis of extended x-ray-absorption fine-structure (EXAFS) data. The set of Cartesian coordinates used to define the positions of atoms
Kurt D. Benkstein, Wilbur S. Hurst, Douglas C. Meier, Pamela M. Chu
Chemical detectors are crucial tools for first responders during emergency-response scenarios and for continuous monitoring of public spaces for general safety. For those who depend upon chemical detectors for safety and security, ensuring that detectors