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Physics

Spectroscopy

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Displaying 676 - 700 of 911

High Accuracy Measurements of OH Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols.

March 4, 2011
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the

Differential Light Shift Cancellation in a B-Field Insensitive Transition of 87Rb

February 11, 2011
Author(s)
Radu S. Chicireanu, Karl D. Nelson, Steven M. Olmschenk, Nathan Lundblad, A. Derevianko, James V. Porto
We demonstrate substantial cancellation of the differential light shift of a magnetic-field-insensitive microwave hyperfine (clock) transition in 87Rb atoms trapped in an optical lattice. Up to 95.5% of the differential light shift is cancelled while

Comparison of the Sensitivity and Image Contrast in Spontaneous Raman and Coherent Stokes Raman Scattering Microscopy of Geometry Controlled Samples

February 9, 2011
Author(s)
Hyun M. Kim, Chris A. Michaels, Garnett W. Bryant, Stephan J. Stranick
We experimentally compare the performance and contrast differences between spontaneous and coherent Stokes Raman scattering microscopy. We demonstrate the differences on a series of geometry controlled samples that range in complexity from a point (array

Passive Intermodulation due to Self-Heating in Printed Transmission Lines*

February 2, 2011
Author(s)
Eduard Rocas, Juan C. Collado Gomez, Nathan D. Orloff, Jordi Mateu, James C. Booth, Juan M. O'Callaghan, Alberto Padilla
Abstract—This article proposes a mechanism by which third-order intermodulation distortion due to self-heating is generated in transmission lines. The work shows how transmission lines made of several materials whose properties are independent of the

Approximate theoretical model for the five electronic states (? = 5/2, 3/2, 3/2, 1/2, 1/2) arising from the ground 3d9 configuration in nickel halide molecules and for the rotational levels of the two ? = 1/2 states in this manifold

January 25, 2011
Author(s)
Jon T. Hougen
This paper is divided into two parts. In the first part an effective Hamiltonian for a non-rotating diatomic molecule containing only crystal-field and spin-orbit operators is set up to describe the energies of the five spin-orbit components that arise in

Performance of a coherent dual frequency comb spectrometer

January 1, 2011
Author(s)
Nathan R. Newbury, Esther Baumann, Ian R. Coddington, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
We discuss the performance of a coherent dual frequency comb spectrometer in terms of signal-to-noise ratio, resolution, and accuracy based on experimental data in the near and short-wave infrared centered at 1.5 and 3.4 micrometers.

Progress at NIST in measuring the D-lines of Li isotopes using an optical frequency comb

December 20, 2010
Author(s)
Clayton Simien, Samuel M. Brewer, Joseph N. Tan, John D. Gillaspy, Craig J. Sansonetti
Precise spectroscopic experiments with light atoms can provide information about nuclear properties that are very difficult to obtain in electron scattering experiments. For example, relative nuclear radii of low-Z isotopes can be determined accurately

A Microwave Study of Hydrogen-Transfer-Triggered Methyl-Group Rotation in 5-Methyltropolone

November 10, 2010
Author(s)
Vadim V. Ilyushin, Emily A. Cloessner, Yung-Ching Chou, Laura B. Picraux, Jon T. Hougen, Richard Lavrich
We present here the first experimental and theoretical study of the microwave spectrum of 5-methyltropolone, which can be visualized as a 7-membered aromatic carbon ring with a five-membered hydrogen-bonded cyclic structure at the top and a methyl group at

High precision, broadband optical measurements with fiber laser frequency combs

November 2, 2010
Author(s)
Nathan R. Newbury, Ian R. Coddington, Esther Baumann, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
Optical frequency combs have been used extensively, and with remarkable success, to measure the absolute frequency of cw lasers. The use of frequency combs has also expanded to include applications such as precision ranging, component metrology, and

Towards More Accurate Atomic Oscillator Strengths

October 28, 2010
Author(s)
Wolfgang L. Wiese, Jeffrey R. Fuhr, John M. Bridges
Accurate determinations of atomic oscillator strengths have been a problem for a long time, and discrepancies between various numerical results have been substantial. But in recent years considerable progress has been made, especially for weak lines

Fast high-resolution frequency agile spectroscopy of laser sources

October 24, 2010
Author(s)
Fabrizio R. Giorgetta, Ian R. Coddington, Esther Baumann, William C. Swann, Nathan R. Newbury
Time-resolved, high-accuracy and high-resolution spectroscopy of frequency-agile cw lasers is critical to realizing their full potential for sensing, but is not possible with conventional spectroscopy methods. We demonstrate a dual comb-based spectrometer

Organic Compounds in the C3H6O3 Family: Microwave Spectrum of cis-cis-Dimethyl Carbonate

October 18, 2010
Author(s)
Francis J. Lovas, David F. Plusquellic, Susanna L. Widicus Weaver, B. A. McGuire, G. A. Blake
Geometry optimization calculations on 13 members of the C3H6O3 family of organic species have been carried out to determine their relative binding energies. Dimethyl carbonate [(CH3)2CO3] is one of the lower energy species in this family, which includes

Thermochemistry of Ammonium Nitrate, NH4NO3, in the Gas Phase

October 7, 2010
Author(s)
Karl K. Irikura
Hildenbrand and coworkers have shown recently that the vapor above solid ammonium nitrate includes molecules of NH4NO3, not only NH3 and HNO3 as previously believed. Their measurements led to thermochemical values that imply an enthalpy change of D298 = 98

Revised interpretation of the Na I EUV absorption spectrum

September 27, 2010
Author(s)
Alexander Kramida
Spectral data for neutral sodium were recently compiled by Sansonetti (2008 J. Phys. Chem. Ref. Data 37 1659). In that compilation, some of the energy levels of the 2p53snl configurations were quoted from the studies of the absorption spectrum in the

X-Ray Spectroscopy of Highly Charged Ions in Laboratory and Astrophysical Plasmas

September 1, 2010
Author(s)
E. H. Silver, N Brickhouse, T. Lin, G X. Chen, K. Kirby, John D. Gillaspy, Joseph N. Tan, J M. Laming
This paper presents (1) new laboratory data on the x-ray spectra of He-like Ar XVII over a broad spectral range (300-3500 eV) at high resolution (2) the results of new measurements of K-shell x- ray reference lines in carbon, oxygen, iron, copper, and
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