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Physics

Spectroscopy

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Displaying 626 - 650 of 948

Immobilization of Proteins on Carboxylic Acid-Functionalized Nanopatterns

November 28, 2012
Author(s)
John Peter Ngunjiri, Daniel J. Stark, Tian Tian, Kimberly Briggman, Jayne C. Garno
The immobilization of proteins on nanopatterned surfaces was investigated using in situ atomic force microscopy (AFM) and ex situ infrared reflectance-absorption spectroscopy (IRAS). The AFM-based lithography technique of nanografting provided control of

EUV magnetic-dipole lines from highly-charged high-Z ions with an open $3d$ shell

November 27, 2012
Author(s)
Yuri Ralchenko, John D. Gillaspy, Joseph Reader, Dmitry D. Osin
The electron beam ion trap (EBIT) at the National Institute of Standards and Technology was used to produce highly-charged ions of hafnium, tantalum and gold with an open $3d$ shell. The extreme-ultraviolet (EUV) spectra from these ions were recorded with

Absolute line intensities for ethylene from 1800 to 2350 cm-1.

November 17, 2012
Author(s)
Walter J. Lafferty, Jean-Marie Flaud, A. Ben Hassen, F. K. Kwabia Tchana, X Landsheere, H Aroui
Fourteen Fourier transform spectra of ethylene (C2H4) have been recorded in the 1800-2350 spectral domain with different path-lengths and pressures and used to derive individual line intensities for lines belonging to the ν7 + ν8, ν4 + ν8 , ν6 + ν10, ν6 +

High-resolution infrared studies of the V10, V11, V14, and V18 levels of [1.1.1] propellane

November 15, 2012
Author(s)
Robynne Kirkpatrick, Tony Masiello, Mathew A. Martin, Joseph W. Nibler, Arthur Maki, Alfons Weber, Thomas A. Blake
This paper is a continuation of earlier work for which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions

EUV spectra of Rb-like to Cu-like gadolinium ions in an electron beam ion trap

October 8, 2012
Author(s)
Yuri Ralchenko, Deirdre Kilbane, G. O'Sullivan, John D. Gillaspy, Joseph Reader
Measurements of extreme ultraviolet radiation from highly-charged gadolinium ions were made at the National Institute of Standards and Technology. The ions were produced and confined in an electron beam ion trap (EBIT) and the spectra were recorded with a

Biosynthesis of Athmu, a alpha,gamma-hydroxy-ss-amino acid of pahayokolides A-B

October 2, 2012
Author(s)
Li Liu, Dan Bearden, Juan C. Rodriguez, Kathleen S. Rein
Pahayokolides A-B are cyanobacteria derived non-ribosomal peptides which exhibit cytotoxicity against a number of cancer cell lines. The biosynthetic origin of the 3-amino-2,5,7,8- tetrahydroxy-10-methylundecanoic acid (Athmu) moiety has been investigated

Controlling Thermochromism in a Photonic Block Copolymer Gel

September 26, 2012
Author(s)
Joseph J. Walish, Yin Fan , Andrea Centrone, Edwin L. Thomas
Controlling the color via temperature-induced changes of self-assembled photonic materials is important for their application in sensors and displays. The thermochromic behavior of a PS-P2VP photonic gel was studied (UV-VIS, FTIR) and found to originate

Near-infrared calibration systems for precise radial-velocity measurements

September 24, 2012
Author(s)
Stephen L. Redman, Florian Kerber, Gillian Nave, Suvrath Mahadevan, Lawrence W. Ramsey, Jonathan Smoker, H-U Kaufl, Pedro Figueira
We present work done to prepare two new near-infrared calibration sources for use on high-precision astrophysical spectrographs. Uranium-neon is an atomic calibration source, commercially available as a hollow-cathode lamp, with over 10 000 known emission

Measuring Single-Walled Carbon Nanotube Length Distributions from Diffusional Trajectories

August 27, 2012
Author(s)
Jason Streit, Sergei M. Bachilo, Anton V. Naumov, Constantine Y. Khripin, Ming Zheng, R B. Weisman
A new method is demonstrated for measuring the length distributions of dispersed single-walled carbon nanotube (SWCNT) samples by analyzing diffusional motions of many individual nanotubes in parallel. In this method, termed Length Analysis by Nanotube

Towards One-electron Ions in Rydberg States for Laser Spectroscopy

July 30, 2012
Author(s)
Joseph Tan, Samuel Brewer, Nicholas D. Guise
Simple quantum systems play important roles in the determination of fundamental constants. Very recently at NIST, bare nuclei created in an EBIT were extracted and captured in a novel compact Penning trap. This is a step towards production of one-electron

Highly Charged Ions in Rare Earth Permanent Magnet Penning Traps

July 13, 2012
Author(s)
Nicholas D. Guise, Samuel Brewer, Joseph Tan
A newly constructed apparatus at the United States National Institute of Standards and Technology (NIST) is designed for the isolation, manipulation, and study of highly charged ions. Highly charged ions are produced in the NIST electron-beam ion trap

Identification of Isethionic Acid and Other Small Molecule Metabolites of Fragilariopsis cylindrus with Nuclear Magnetic Resonance

July 8, 2012
Author(s)
Dan Bearden, Arezue F. Boroujerdi, Peter A. Lee, Giacomo R. DiTullio, Michael G. Janech, Sarah B. Vied
Nuclear magnetic resonance (NMR)-spectroscopy has been used to obtain metabolic profiles of the polar diatom Fragilariopsis cylindrus, leading to the identification of a novel metabolite in this organism. Initial results from an ongoing metabolomics study

A Guide to Using SRM 2569 to Validate Analytical Methods

May 17, 2012
Author(s)
John R. Sieber, John L. Molloy
A user’s guide is presented for Standard Reference Material (SRM) 2569 Lead in Paint Films for Children’s Products. This SRM consists of paint films on coupons of polyester with the paint characterized for mass fraction of Pb, mass of Pb per unit area

Light, atoms and nuclei: the optical discovery of deuterium

May 1, 2012
Author(s)
Charles W. Clark, Joseph Reader
Deuterium was discovered by atomic spectroscopy 80 years ago, and led to the rapid development of nuclear energy and isotope chemistry. Atomic spectroscopy of deuterium remains vibrant, with a recent application to understanding the early universe.

Nanoscale Fullerene Compression of an Yttrium Carbide Cluster

April 13, 2012
Author(s)
Jianyuan Zhang, Fuhrer Tim, Wujun Fu, Jiechao Ge, Dan Bearden, Jerry Dallas, Duchamp James, Kenneth Walker, Hunter Champion, Hugo Azurmendi, Kim Harich, Harry C. Dorn
The encapsulation of clusters (or small molecules) in spheroidal fullerene cages provides a unique isolated environment that is important in describing their shape, dynamics, and physical properties. For the case of yttrium carbide clusters, we find that
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