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This study considers a physics-based and a kernel-based approach for characterizing pixels in a scene that may be linear (areal mixed) or nonlinear (intimately mixed). The physics-based method is based on earlier studies that indicate nonlinear mixtures in
This article reviews the mechanism of tip enhanced Raman spectroscopy (TERS) and its importance for characterizing graphene. The theoretical foundation of TERS and experimental implementation are discussed. Conventionally, Raman scattering is treated as a
Vladislav P. Gerginov, Sean P. Krzyzewski, Svenja A. Knappe
A scalar magnetic field sensor based on 87Rb vapor millimeter-size cell is described. The magnetometer uses co-propagating pump/probe laser beam, amplitude modulation of the pump beam and non-demolition polarization rotation detection of the probe beam
Li-Hong Xu, E. M. Reid, B. Guislain, Jon T. Hougen, Eugene A. Alekseev, I. Krapivin
Quantum chemistry packages can be used to predict with reasonable accuracy spin-rotation hyperfine interaction constants for methanol, which contains one methyl-top internal rotor. In this work we used these same packages to calculate components of the
Fabio Casu, Aaron Watson, Justin Yost, John Leffler, Gibson Gaylord, Frederic Barrows, Paul A. Sandifer, Dan Bearden, Michael R. Denson
In this study we investigated the metabolic effects of four different commercial soy-based protein products on red drum (Sciaenops ocellatus) using NMR-based metabolomics along with unsupervised principal component analysis (PCA) to evaluate metabolic
The specific refractive index increment (dn/dc) is an essential datum for the accurate quantitation of molar mass averages and distributions (inter alia) of macromolecules when refractometry, static light scattering, and/or viscometry detection are coupled
Donglin Zhao, Qinghe Wu, Luping Yu, Harald Ade, Dean DeLongchamp, Lee J. Richter, Subhrangsu Mukherjee, Andrew Herzing
Morphology can play a critical role in determining function in organic photovoltaic (OPV) systems. Recently molecular acceptors have showed promise to replace¬ fullerene derivatives as acceptor materials in bulk heterojunction solar cells and have achieved
In this paper we examine the two-dimensional tunneling formalism used previously to fit the hydrogen-transfer and internal-rotation splittings in the microwave spectrum of 2 methylmalonaldehyde in an effort to determine the origin of various
We have tested the suitability of a commercial flatbed scanner for digitizing photographic plates used for spectroscopy. The scanner has a bed size of 420 mm by 310 mm and a pixel size of about 10 um. Our tests show that the closest line pairs that can be
Evgheni Strelcov, Qingfeng Dong, Tao Li, Jungseok Chae, Yuchuan Shao, Yehao Deng, Alexei Gruveman, Jinsong Huang, Andrea Centrone
Ferrolectricity has been proposed as a plausible meachanism to explain the high photovoltaic conversion efficiency in organic-inorganic perovskites; however, convincing experimental evidence in support to this hypothesis is still missing. Identifying and
Anthony P. Kotula, Chad R. Snyder, Kalman D. Migler
The Raman spectra of polycaprolactones have been measured over a temperature range of 20 °C to 160 °C to distinguish ordered chain conformers in the melt state and determine the quantitative crystalline bands. Principal component analysis of the spectra in
John L. Molloy, Swarna Lakshmi, Tin L. Wong, Heather Neu, Sarah Michel, Eric A. Toth
3-hydroxyanthranilate 3,4-dioxygenase (3HAO) is an enzyme in the microglial branch of the kynurenine pathway of tryptophan degradation. 3HAO is a non-heme iron-containing, ring-cleaving extradiol dioxygenase that catalyzes addition of both atoms of O2 to
Melanie C. Ghysels, Philip Liu, Adam Fleisher, Joseph T. Hodges
We present a new cavity ring-down spectroscopy system which was developed for variable-temperature absorption measurements (220 K- 290 K) of atmospheric gases. This laser spectrometer was developed in the framework of the NASA Orbiting Carbon Observatory-2
Moving-window (MW) approaches to two-dimensional correlation spectroscopy (2D-COS) make it possible to characterize spectral changes occurring in a narrow range of perturbation variable (e.g., time, temperature, and concentration). Despite the wide range
Paul Lemaillet, Jeeseong Hwang, Heidrun Wabnitz, Dirk Grosenick, Lin Yang, David W. Allen
Diffuse materials that approximate the optical properties of human tissue are commonly used as phantoms. In order to use the phantoms in a manner that provides consistent results relative to independent measurements, the optical properties need to be tied
Wilfred Fullagar, Jens Uhlig, Ujjwal Mandal, Dharma Kurunthu, Amal El Nahhas, Hideyuki Tatsuno, Alireza Honarfar, Fredrik Gustafsson, Villy Sundstrom, Mikko Palosaari, Luis Miaja Avila, Young I. Joe, Daniel Swetz, Joel Ullom
The use of low temperature thermal detectors for avoiding Darwin-Bragg losses in lab-based ultrafast experiments has begun. An outline of the background of this new development is offered, showing the relevant history and initiative taken by this work.
Secondary fluorescence, the final term in the familiar matrix correction triumvirate Z·A·F, is the most challenging for Monte Carlo models to simulate. In fact, only two implementations of Monte Carlo models commonly used to simulate electron probe x-ray
Sujitra J. Pookpanratana, Katelyn Goetz, Ruslan Ovsyannikov, Erika Giangrisostomi, Emily G. Bittle, Oana Jurchescu, Steven W. Robey, Christina A. Hacker
In organic electronics, the highest estimated charge mobility in a device is typically achieved when the organic semiconductor is a single crystal. However, the measurement of the electronic and chemical structure of organic single crystals by
Georg Ramer, Florian Reisenbauer, Benedikt Steindl, Wolfgang Tomischko, Bernhard Lendl
Photothermal induced resonance (PTIR) is a method for optical spectroscopy that allows for infrared chemical imaging at spatial resolution below the limit of diffraction. By using the mechanical resonance of the cantilever for amplification the technique
Column selection is probably the single most important aspect of method development that will directly affect measurement accuracy and precision of liquid chromatographic (LC) measurements. An understanding of physical and chemical properties of LC columns
Joshua R. Biller, Karl F. Stupic, Anthony B. Kos, Timothy Weilert, George Rinard, Yoshi Nakashima, John M. Moreland
A low-field nuclear magnetic resonance (NMR) instrument is an important tool for investigating a wide variety of samples under different conditions. In this paper, we describe a system constructed primarily with commercially available hardware and control
New wavelength measurements in the vacuum ultraviolet (VUV), ultraviolet and visible spectral regions have been combined with available literature data to refine and extend the description of the spectrum of singly ionized copper (Cu II). In the VUV region
Rohit J. Jacob, Diana Ortiz-Montalvo, Kyle R. Overdeep, Timothy P. Weihs, Michael R. Zachariah
Exothermic reactions between oxophilic metals and transition/ post transition metal-oxides have been well documented owing to their fast reaction time scales (10 μs). This article examines the extent of reaction in nano-aluminum based thermite systems
Gillian Nave, Craig J. Sansonetti, Keeley I. Townley-Smith, J C. Pickering, Florence Liggins, Anne P. Thorne, Christian Clear
We summarize recent work at the National Institute of Standards and Technology and Imperial College London on wavelengths, hyperfi ne structure, energy levels, and analysis of singly-ionized iron-group elements of astrophysical interest.
James E. Lawler, Chris Sneden, Gillian Nave, E. A. Den Hartog, N Emrahoglu, John J. Cowan
New emission branching fraction (BF) measurements for 183 lines of the second spectrum of chromium (Cr II) and new radiative lifetime measurements from laser induced fluorescence for eight levels of the z4F and z4D levels of ionized Cr are reported. The