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The stress during Pb underpotential deposition (upd) on (111)-textured Au has been examined on a cantilever beam electrode in perchloric acid supporting electrolyte. The upd peaks change from double to single going from higher to lower sweep rates, while a
Kar T. Tan, Christopher C. White, Donald L. Hunston, Vogt D. Bryan, Anthony Haag
Water is ubiquitous in any uncontrolled setting and affects world wide commerce by instigating device and structural failures. This can be a result of corrosion, electrical shorting, or adhesive failure. For adhesive failure, the environmental attack of
Christopher M. Stafford, Adam J. Nolte, Gale A. Holmes, Sheng Lin-Gibson, John A. Howarter
NIST s involvement in adhesion research has been wide ranging and is ultimately in response to interactions between individual project leaders and our industrial partners. In this way, NIST s participation in the Adhesion Society has been instrumental in
Najib Cheggour, Loren F. Goodrich, Theodore C. Stauffer, Jolene D. Splett, Xifeng Lu, A. K. Ghosh, G. Ambrosio
Nb 3Sn superconducting wires made with restacked-rod process (RRP®) were found to have a dramatically improved resilience to axial tensile strain when alloyed with Ti as compared to Ta. Whereas Ta-alloyed Nb 3Sn in RRP wires showed permanent damage to its
Katie Hurst, Christopher L. Cromer, Elisabeth Mansfield, Roop Mahajan, John H. Lehman, Gurpreet Singh
We describe the development of two next-generation optical coatings; amorphous polymer-derived silicon carbonitride (SiCN) particles and a composite consisting of SiCN surrounding a multiwalled carbon nanotube (MWCNT) core. Laser-induced damage testing of
M Cai, S C. Langford, Richard E. Ricker, Lyle E. Levine, J T. Dickinson
Many metals emit electrons when exposed to UV radiation from excimer lasers (photon energies 4 eV to 8 eV). Deformation can significantly affect the intensity of these emissions. In the case of reactive metals, these emissions are also altered by the
Calvin Chan, Lee J. Richter, Brad A. Dinardo, Cherno Jaye, Brad Conrad, Hyun Wook Ro, David Germack, Daniel A. Fischer, Dean M. DeLongchamp, David J. Gundlach
Mickey Richardson, Eun S. Park, Jaehyun Kim, Gale A. Holmes
A small series of functionalized C60-fullerene/epoxy nanocomposites were prepared, and their respective ultimate tensile strengths were determined. The functionalization route of the fullerenes was performed using the well-known Prato reaction, with
Gale A. Holmes, Jae Hyun Kim, Stefan D. Leigh, Walter G. McDonough
The exact theories advanced by Curtin et al. (1991) and Hui, Phoenix, et al. (1995) to describe the fiber break evolution process in single fiber composites were found to be incorrect when compared to experimental data. In contrast to theoretical
Compressive stresses in stiff polymer coatings can give rise to surface instabilities in which the coating adopts a sinusoidally wrinkled morphology with a dominant wavelength, d, as displayed in Figure 1a. Such instabilities are generally observed for
We demonstrate that thermal wrinkling can be utilized to measure the rubbery modulus and shear viscosity of polystyrene (PS) thin films as a function of temperature. Specifically, we use surface laser-light scattering (SLS) to characterize the wrinkled
Jonathan W. Martin, Xiaohong Gu, Tinh Nguyen, Joannie W. Chin
NIST has initiated a research program for improving the quality of the data input for making economic sustainability assessments of polymeric infrastructure materials through improvements in the measurement science for this data. Sustainability assessments
Superconformal film growth is a key process in state-of-the-art Cu metallization of electronic devices. Superfilling of recessed surface features results from competition between electrolyte additives that accelerate or inhibit Cu electroplating. In situ
Effects of sample surface free energy (s) and relative humidity (RH) of the tip-sample environment on image contrast and friction characteristics measured with lateral force microscopy (LFM) have been investigated. Samples having a wide range of surface
Coralie Bernard, Tinh Nguyen, Bastien T. Pellegrin, Mat Celina, Alexander J. Shapiro, Deborah Jacobs, Kar T. Tan, Sungjin Park, R. S. Ruoff, Joannie W. Chin
Graphene oxides are potentially a new class of nanomaterial to enhance multifunctional properties of polymers because of their remarkable thermal conductivity, mechanical strength, and more importantly, low cost. The graphene oxides, produced by
The Outer Shell of the jacket and pants of the firefighter s protective clothing is constructed of a fabric that is commonly a blend of polyaramid, polybenzimidazole, and/or poly(melamine-formaldehyde) fibers. The Outer Shell contributes to the thermal and
Objectives: Determination of material and fractographic properties of a dental indirect resin composite material. Methods: A resin composite (Paradigm, 3M-ESPE, MN) was characterized by strength, static elastic modulus, Knoop hardness, fracture toughness
Although existing techniques can measure the viscoelastic properties of bulk polymers, few are available for measuring these properties in polymer thin films. This information has become increasingly important as polymers thin films are developed in a
Donald L. Hunston, Kar T. Tan, Bryan D. Vogt, Sushil K. Satija, Cyril Clerici, David E. White
The ability of water to dramatically weaken many types of adhesive bonds has been widely studied. One surprising result is the existence of a critical moisture level in the bond. Above this level the strength drops to very low values. Numerous studies have
Kar T. Tan, Christopher C. White, Donald L. Hunston, Kristen L. Steffens, Hatlee Timothy, Kristen Hamilton, Vogt D. Bryan
Adhesion loss due to moisture is a fundamental problem in a large diversity of industries ranging from microelectronics and automotive to aerospace. This study investigates the durability of model adhesive joints consisting of a homologous series of poly(n
A major goal of materials research over the past two decades has been the development of high throughput methods for rapid discovery and optimization of processing routes. These methods rely on highly parallel materials synthesis to efficiently create