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Chemistry

Thermochemical properties

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Displaying 301 - 325 of 781

Microwave measurements for gas thermometry up to the copper point

May 13, 2013
Author(s)
XiaoJuan Feng, Keith A. Gillis, Michael R. Moldover, James B. Mehl
We measured 5 microwave resonance frequencies f N of an argon-filled cylindrical cavity at temperatures up to 1349 K. The repeatability of both the measured frequencies u(f N) and the scaled half-widths u(g N)/ f N was better than 10 -6f N. The measurement

Assessment of the Thermophysical Properties of Thermally Stressed RP-1 and RP-2

May 2, 2013
Author(s)
Tara J. Fortin, Thomas J. Bruno
Density, speed of sound, and viscosity have been measured for samples of RP-1 and RP-2 that were stressed for 0.5 min at 475 °C and 510 °C at a pressure of 17 MPa. Density and speed of sound were measured from 5 °C to 50 °C for the samples stressed at 475

Correlation for the Viscosity of Hydrogen obtained from Symbolic Regression

March 27, 2013
Author(s)
Chris D. Muzny, Marcia L. Huber, Andrei F. Kazakov
We report the results of a symbolic regression methodology to obtain both the functional form and the coefficients for a wide-ranging correlation for the viscosity of normal hydrogen. The correlation covers the temperature range from the triple point

Critical thermal-conductivity enhancement in molecular fluids

March 2, 2013
Author(s)
Richard A. Perkins, Jan V. Sengers, Ilmutdin M. Abdulagatov, Marcia L. Huber
The available information for the thermal-conductivity enhancement is reviewed. We show that it can be represented by a simplified solution of the mode-coupling theory of critical dynamics with two critical amplitudes and one cutoff wave number as fluid

Experimental Study of the Thermal Conductivity of Water +Ammonia Refrigerant Mixtures at Temperatures from 278 K to 356 K and at Pressures up to 20 MPa

February 28, 2013
Author(s)
F. N. Shamsetdinov, Z. I. Zaripov, Ilmutdin M. Abdulagatov, Marcia L. Huber, F. M. Gumerov, F. R. Gabitov, Andrei F. Kazakov
The thermal conductivity of binary water + ammonia mixtures was measured over the temperature range from 278 K to 356 K and at pressures up to 20 MPa using the steady-state hot-wire method. Measurements were made for eight compositions over the entire

Advanced Calibration, Adjustment, and Operation of a Density and Sound Speed Analyzer

February 26, 2013
Author(s)
Tara J. Fortin, Arno D. Laesecke, Malte B. Freund, Stephanie L. Outcalt
Benchtop measurement systems have emerged as powerful tools in the ongoing quest for thermophysical property data. We demonstrate that these instruments can yield high quality data if operated in an informed manner. The importance of sample purity

Recommended viscosities of 11 dilute gases at 25?degC

December 13, 2012
Author(s)
Robert F. Berg, Michael R. Moldover
Commercially manufactured meters that measure the flow of a process gas are often calibrated with a known flow of a surrogate gas. This requires an accurate model of the flow meter and accurate values of the relevant thermophysical properties for both
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