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Chemistry

Chemical thermodynamics & chemical properties

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Displaying 1 - 25 of 522

Ionization Constant of Water

June 10, 2025
Author(s)
Hugues Arcis, Allan Harvey
This is an update of two tables in the CRC Handbook of Chemistry and Physics (for the 106th ed.) to reflect a new standard formulation adopted in 2024 by the International Association for the Properties of Water and Steam (IAPWS).

Random and systematic uncertainty in ship-based seawater carbonate chemistry observations

September 8, 2024
Author(s)
Brendan Carter, Jonathan Sharp, Maribel I. Garcia-Ibanez, Ryan J. Woosley, Michael Fong, Marta Alvarez, Leticia Barbero, Simon Clegg, Regina Easley, Andrea Fassbender, Xinyu Li, Katelyn Schockman, Zhaohui Aleck Wang, Andrew Dickson
Seawater carbonate chemistry observations are increasingly necessary to study a broad array of oceanographic challenges such as ocean acidification, carbon inventory tracking, and assessment of marine carbon dioxide removal strategies. As a result, efforts

Optical n(p, T_90) measurement suite 3: results at l = 1542 nm

August 3, 2024
Author(s)
Patrick Egan, Yuanchao Yang
Single-isotherm n(p, T90) results are reported for the gases Ar, N2, H2O, and D2O at vacuum wavelength λ = 1542.383(1) nm. The argon and nitrogen isotherms were measured near 303 K; the water isotherms were measured near 373 K. Combined with the two

Orthogonal Determination of Competing Surfactant Adsorption onto Single-Wall Carbon Nanotubes During Aqueous Two-Polymer Phase Extraction via Fluorescence Spectroscopy and Analytical Ultracentrifugation

July 31, 2024
Author(s)
Christopher Sims, Jeffrey Fagan
A combination of analytical ultracentrifugation (AUC) and fluorescence spectroscopy are utilized to orthogonally probe compositions of adsorbed surfactant layers on the surface of (7,5) species single-wall carbon nanotubes (SWCNTs) under conditions known

Index of Refraction of Liquid Water

May 1, 2024
Author(s)
Allan H. Harvey
This is an item for the CRC Handbook of Chemistry and Physics (105th ed.), giving values calculated from the IAPWS formulation for the refractive index.

Melting Points and Boiling Points for the Alkali Metals

February 29, 2024
Author(s)
Nikhila Narayana, Donald R. Burgess Jr.
In this work, we compiled, evaluated, and select recommended values for use for the melting points and boiling points of the alkali metals: lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), and francium (Fr). Here we provide all of the

Self-Diffusion and Binary-Diffusion Coefficients in Gases

February 29, 2024
Author(s)
Donald R. Burgess Jr.
In this work, we compiled and evaluated both self-diffusion and binary-diffusion coefficients D for gases as a function of temperature. In this paper, we provide recommended values for the diffusion coefficients at standard room temperature 298.15 K (D298)

Heats of Combustion and Related Properties of Pure Substances

December 5, 2023
Author(s)
Donald R. Burgess Jr., Anthony Hamins
In this work, we compiled and evaluated various properties pertaining to the heats of combustion of about 420 compounds of physical, chemical, and engineering interest. This includes boiling points, melting points, latent heats (enthalpies) of vaporization

The Magnetic Suspension Balance - 40 Years of Advancing Densimetry and Sorption Science Xiaoxian Yang1, Reiner Kleinrahm2, Mark O. McLinden3, Markus Richter1,

November 7, 2023
Author(s)
Xiaoxian Yang, Reiner Kleinrahm, Mark O. McLinden, Markus Richter
This paper reviews the 40-year evolution and application of the magnetic-suspension balance (MSB) and discusses some challenging issues of the technique. A MSB, as we define it here, is a magnetic-suspension coupling (MSC) connected with an analytical

Compressed liquid density and speed of sound measurements and correlation of the binary mixture Carbon dioxide (CO2) + 1,1-difluoroethene (R1132a)} at temperatures from 220 K to 350 K

August 25, 2023
Author(s)
Davide Menegazzo, Aaron Rowane, Laura Fedele, Sergio Bobbo, Giulia Lombardo, Mark O. McLinden
The blend of carbon dioxide and R1132a has been suggested as feasible alternative to R23 in low-temperature devices. In this work, we present a new set of experimental data for compressed-liquid density, vapour density and compressed-liquid speed of sound

An Equation of State for the Thermodynamic Properties of Helium

August 10, 2023
Author(s)
Diego Ortiz Vega, Kenneth Hall, James Holste, Allan H. Harvey, Eric W. Lemmon
This report documents the equation of state for fluid helium implemented in Version 10 of NIST's REFPROP Standard Reference Database. The equation of state is expressed as the molar Helmholtz energy as a function of temperature and density, and is valid

Thermochemical study of 2-adamantanone

July 24, 2023
Author(s)
Ala Bazyleva, Dzmitry Zaitsau, Gennady J. Kabo
The results of a thermochemical study of the standard molar enthalpy of combustion of 2-adamantanone in the crystalline phase state by isoperibol combustion calorimetry are presented. Two different approaches of combustion-calorimetry data processing (one

Uncertainty

February 1, 2023
Author(s)
Robert D. Chirico, Eugene Paulechka, Vladimir Diky, Ala Bazyleva
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