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Chemistry

Chemical engineering & processing

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Displaying 126 - 150 of 400

NIST 10 V Programmable Josephson Voltage Standard System Using a Low Capacity Cryocooler

November 6, 2014
Author(s)
Logan A. Howe, Anna Fox, Alain Rufenacht, Charles J. Burroughs, Paul Dresselhaus, Samuel Benz, Robert E. Schwall
Rising costs of and difficulty in obtaining liquid helium in many areas of the world provides strong motivation for cryogen-free operation of superconducting devices such as NIST Programmable Josephson Voltage Standard (PJVS) systems. However, operation on

Dielectrofluidics for Electronic-Based Chemical and Particle Analysis

August 18, 2014
Author(s)
James C. Booth, Spencer T. Egan, Charles A. Little, A Padilla, Yu Y. Wang, Nathan D. Orloff
The interactions of electromagnetic fields with matter are described by means of the polarization and magnetization of the material under study. Analogous to the way that magnetofluidics seeks to exploit magnetic interactions for sensing and manipulating

The Half-Life of 209Po : Revisited

August 13, 2014
Author(s)
Ronald Colle, Ryan P. Fitzgerald, Lizbeth Laureano-Perez
A substantial 25 % error in the then known and accepted (102  5) year half-life of 209Po was reported on in 2007. This error was detected from decay data from two separate primary standardizations of a 209Po solution standard, which were performed

In Search of Better Pressure Standards

August 1, 2014
Author(s)
Jay H. Hendricks, Jacob E. Ricker, Patrick F. Egan, Gregory F. Strouse
Based on highly accurate optical interferometry and fundamental quantum calculations, researchers at the National Institute of Standards and Technology (NIST) in the US are developing an improved definition of the SI unit for pressure that will consign the

Metrology for comparison of displacements at the picometer level

July 31, 2014
Author(s)
Jack A. Stone Jr., Patrick F. Egan, Jay H. Hendricks, Gregory F. Strouse, Douglas A. Olson, Jacob E. Ricker, Gregory E. Scace, Donavon Gerty
An apparatus capable of comparing displacements with picometer accuracy is currently being designed at NIST. In principle, we wish to compare one displacement in vacuum to a second, equal displacement in gas, in order to determine gas refractive index. If

Polyelectrolyte Multilayers in Microfluidic Systems for Biological Applications

July 31, 2014
Author(s)
Saugandhika S. Minnikanti, Aveek Gangopadhyay, Darwin Reyes-Hernandez
The formation of polyelectrolyte multilayers (PEMs) for the first time two decades ago demonstrating the assembly on charged substrates in a very simple and efficient way have proven to be a reliable method to obtain structures tunable at the nanometer

Sealed Gravitational Capillary Viscometers for Volatile Liquids

July 7, 2014
Author(s)
Arno R. Laesecke
The evolution of sealed gravitational capillary viscometers for measurements of volatile liquids is reviewed. Two corrections need to be applied to measurements with them: (i) the vapor buoyancy correction and, if coiled capillaries are used, (ii) the

A Demonstration of Fast and Accurate Discrimination and Quantification of Chemically Similar Species Utilizing a Single Cross-Selective Chemiresistor

June 14, 2014
Author(s)
Alexander (. Vergara Tinoco, Kurt D. Benkstein, Christopher B. Montgomery, Stephen Semancik
Performance characteristics of gas-phase microsensors will determine the ultimate utility of these devices for a wide range of chemical monitoring applications. Considerable effort has led to electronic nose devices that utilize multiple cross-selective

Design and Analysis of a 150 K Cascade Joule-Thomson Microcooler

June 9, 2014
Author(s)
Ray Radebaugh, Peter E. Bradley, Collin J. Coolidge, Ryan J. Lewis, Y.C. Lee
Lightweight and compact microcoolers are needed for advanced, hand-held infrared systems. A temperature of 150 K is adequate for high sensitivity with some of the latest IR detectors, which simplifies the cooling requirements compared to 80 K detectors

Acoustic Techniques for Measuring Transport Properties of Gases

May 22, 2014
Author(s)
Keith A. Gillis, Michael R. Moldover
We describe the principles, techniques, and performance of acoustic resonators used to measure the shear viscosity, the thermal conductivity, and the bulk viscosity in gases. We developed the Greenspan acoustic viscometer at NIST, where colleagues used it

Viscosity-ratio measurements with capillary viscometers

May 20, 2014
Author(s)
Robert F. Berg, Eric F. May, Michael R. Moldover
Viscosity-ratio measurements made with capillary viscometers exploit the accurate values of the viscosity of helium resulting from ab initio calculations. Accurate values of the argon-to-helium viscosity ratio are now used for primary acoustic thermometry

Recent advances in vacuum sciences and applications

April 9, 2014
Author(s)
Miran Mozetic, Kostya Ostrikov, David Ruzic, Davide Curreli, Uros Cvelbar, Alenka Vesel, Gregor Primc, Manfred Leisch, Karl Jousten, Oleg Malyshev, Jay H. Hendricks, laszlo Kover, Alberto Tagliaferro, O Conde, Antonio Silvestre, J Giapintzakis, M Buljan, N Radi?, G Dra?i?, S Bernstorff, H Biederman, O Kyli?n, J Hanu?, S Milo?evi?, A Galtayries, P Dietrich, W Unger, K Stana-Kleinschek, A Drmota?Petri?, Jean-Jacques Pireaux, J W. Rogers, M Anderle, M Lehocky, V Sedlarik
Recent advances in vacuum sciences and applications are reviewed. Novel optical interferometer cavity devices enable pressure measurements with ppm accuracy. Innovative dynamic vacuum standard allows for pressure measurements with temporal resolution of 2

A comparison of literature models for the oxidation of normal heptane

February 1, 2014
Author(s)
David A. Sheen, Wing Tsang
The development of detailed chemical kinetic models has proceeded unabated since the pioneering work of Dixon-Lewis and coworkers forty-five years ago. In that time, computational power has increased ten million-fold, and yet, we do not have a consensus on

Acoustic Gas Thermometry

January 16, 2014
Author(s)
Michael R. Moldover, Roberto M. Gavioso, James B. Mehl, Laurent Pitre, Michael de Podesta, Jintao Zhang
Primary acoustic gas thermometry (AGT) exploits the simple relationship between the speed of sound in a dilute gas u and the thermodynamic temperature T of the gas. For monatomic gases such as argon and helium, u2 = (5/3) kT/m, in the limit of zero

Perfluorohexane Adsorption in BCR-704 Faujasite Zeolite Benchmark Studies for the Seventh Industrial Fluid Properties Simulation Challenge

January 6, 2014
Author(s)
Richard B. Ross, John K. Brennan, Kevin A. Frankel, Jonathan D. Moore, Raymond D. Mountain, Joshua D. Moore, Riaz Ahmad, Matthias Thommes, Vincent K. Shen, Nathan E. Schultz, Daniel Siderius, Kenneth D. Smith
The primary goal of the seventh industrial fluid properties simulation challenge was to test the ability of molecular simulation methods to predict the adsorption of organic adsorbates in zeolitic materials. The challenge focused, in particular, on the

Quantitative bottom-up proteomics depends on digestion conditions

December 2, 2013
Author(s)
Mark S. Lowenthal, Yuxue Liang, Karen W. Phinney, Stephen E. Stein
Accurate quantification is a fundamental requirement in the fields of proteomics and biomarker discovery, and for clinical diagnostic assays. To demonstrate the extent of quantitative variability in measurable peptide concentrations due to differences

Pressure-Sensitive Sampling Wands for Homeland Security Applications

December 1, 2013
Author(s)
Matthew E. Staymates, Jennifer R. Verkouteren, Jessica Grandner
This work discusses the use of Force Sensing Resistor (FSR) technology for Homeland Security applications. One area of particular focus is the optimization of wipe sampling of surfaces to facilitate enhanced trace contraband collection. Another focus area

Optical Coherence Tomography for Dimensional Metrology of Lab-on-a-chip devices

October 27, 2013
Author(s)
Darwin R. Reyes-Hernandez, Michael W. Halter, Jeeseong Hwang
Here we present a new metrology tool for the determination of the dimensions of channels from final product Lab-on-a-chip devices. Using Optical Coherence Tomography (OCT) areas of up to 12 mm x 12 mm can be imaged in less than 1 second, without the need

Connection between thermodynamics and dynamics of simple fluids in highly attractive pores

October 25, 2013
Author(s)
William P. Krekelberg, Vincent K. Shen, Daniel W. Siderius, Thomas M. Truskett, Jeffrey R. Errington
We investigate the structural and diffusive dynamics properties of a model fluid in highly-absorptive cylindrical pores. At subcritical temperatures, self diffusion displays three distinct regimes as a function of average pore density ρ: 1) a decrease in
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