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Fahriye N. Sari, Marcia J. Holden, M P. Mayhew, V L. Vilker, B Coxon
The backbone dynamics of uniformly 15N-labeled reduced and oxidized putidaredoxin (Pdx) have been studied by 2D 15N NMR relaxation measurements. 15N T 1 and T 2 values and 1H- 15N NOE s have been measured for the diamagnetic region of the protein. These
Redox enzyme mediated biocatalysis has the potential to regio - and stereo-specificity oxidive hydrocarbons producing valuable products with minimal by-product formation. In-vitro reactions of the Camphor (cytochrome P-450) 5-monooxygenase enzyme system
The 2nd Annual Green Chemistry and Engineering Conference was held in Washington, DC in early July, 1998. After two days of technical presentations by international experts on cutting-edge technological advances in sustainable chemistry and engineering, a
Terrence J. Jach, Yanbao Zhang, R. Colella, M. De Boissieu, M. Boudard, A. I. Goldman, T Lograsso, D W. Delaney, S. Kycia
We have observed dynamical diffraction in the [024024] and[046046] reflections of the icosahedral quasicrystal A1PdMn in the back-reflection geometry (θ B = 90 ). The x-ray fluorescence from the Al and Pd atoms exhibits strong standing wave behavior
The theory and implementation of quantitative gas phase absorption measurements based on cavity-ringdown spectroscopy with pulsed lasers is discussed. The response of ringdown cavities is modeled using an eigenmode description of the electromagnetic field
J F. Morrison, L T. Sniegoski, W J. Yoo, Alim A. Fatah
Supercritical fluid extraction (SFE) was investigated as an environmentally friendly alternative to currently used wet chemical procedures in hair drug testing protocols. The SFE behavior of cocaine and its primary metabolite benzoylecgonine was studied
Lee J. Richter, T Petralli-Mallow, John C. Stephenson
We present a novel procedure for vibrationally-resolved sum-frequency generation (SFG) in which a broad-bandwidth IR pulse is mixed with a narrow-bandwidth visible pulse. The resultant SFG spectrum is dispersed with a spectrograph and detected in parallel
N G. Abdulaev, G N. Karaschuk, Jane E. Ladner, D L. Kakuev, A V. Yakhyaev, M. Tordova, I O. Gaidarov, V I. Popov, J H. Fujiwara, D Chinchilla, E Eisenstein, G L. Gilliland, K D. Ridge
A. E. Roitberg, Marcia J. Holden, M P. Mayhew, I V. Kurnikov, D N. Beratan, V L. Vilker
A necessary step in understanding biological function in multiple metalloprotein redox systems is the description of protein-protein binding and electron transfer between two distant metal centers. In this communication, we present experimental and