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Christopher Soles, Hyun W. Ro, Aaron Forster, Dave J. Krug, Vera Popova, Richard M. Laine
In this manuscript a series of cubic silsequioxane monomers with their eight vertices functionalized with different organic ligands terminated with triethoxysilane groups were acid hydrolyzed, spin cast into thin films, and then vitrified into hard
Edwin P. Chan, A M. Urbas, Joseph J. Walish, Edwin L. Thomas
Polymer gels are remarkable materials with physical structures that can adapt significantly and quite rapidly with changes in the local environmental changes such as temperature, light intensity, electrochemistry, and mechanical force. An interesting
Jae Hyun Kim, Nathanael A. Heckert, Walter G. McDonough, Kirk D. Rice, Gale A. Holmes
The Kolsky bar test has been widely used in measuring material behavior under high strain rate conditions. In particular, polymers used in ballistic applications have been characterized by this method to investigate high strain rate behaviors during the
Gale A. Holmes, Jae Hyun Kim, Nathanael A. Heckert, Walter G. McDonough, Stefan D. Leigh, Kirk D. Rice
The use of advanced fibers in applications where they are subjected to extremely energetic events has necessitated the need to develop measurement tools that quantify their properties at high strain rates (HSR). The split Hopkinson tension bar (SHTB) has
Jae Hyun Kim, Nathanael A. Heckert, Walter G. McDonough, Kirk D. Rice, Gale A. Holmes
The Kolsky bar test has been widely used in measuring material response under high strain rate conditions. Initial experiments in the literature applying this test to measure single fiber properties for fibers used in soft body armor with the Kolsky bar
Carl G. Simon Jr., Limin Sun, Laurence C. Chow, William Miles, Christopher K. Tison, Kaushik Chatterjee, Marian F. Young, Vinoy Thomas, Murugan Ramalingam
A 2-spinnerette approach has been developed for fabricating nanofiber scaffold gradients for use as 1) scaffold libraries for screening the effect of nanofiber properties on cell response and 2) templates for generating graded tissue interfaces. Although
Laura A. Smith Callahan, Yanrui Ma, Christopher Stafford, Matthew L. Becker
We demonstrate a versatile, well controlled, and highly reproducible surface density gradient fabrication strategy that allows for precise control over surface functionality and slope. Our approach involves of a novel "vacuum away" channel confinement
Jae Hyun Kim, Nathanael A. Heckert, Stefan D. Leigh, Haruki Kobayashi, Walter G. McDonough, Kirk D. Rice, Gale A. Holmes
Single fiber tensile tests using two different gripping methods were carried out on various fiber lengths. One method (the glue-tab grip) consists of mounting a fiber onto a rigid tab as specified in ASTM C1557-03 using an adhesive, while the other (the
Ke Zhang, Lei Cheng, Satoshi Imazato, Joseph M. Antonucci, Nancy Lin, Sheng Lin-Gibson, Yuxing Bai, Hockin H. Xu
Objectives: Secondary caries at restoration margins is the main reason for restoration failure. Antibacterial bonding agents are promising to inhibit biofilm acids at the tooth-restoration interfaces. The objective of this study was to investigate the
Junghyun Lee, Jun Y. Chung, Edwin Chan, Christopher Stafford
Understanding the degradation of polyamide-based (PA) thin-film composite membranes by chlorine is imperative to develop chlorine-resistant membranes, an important characteristic that is needed to provide the desired long-term performance of membrane-based
Yanrui Ma, Jukuan Zheng, Emily F. Amond, Christopher Stafford, Matthew L. Becker
Peptides, proteins and extracellular matrix act in concert to influence cellular function at the biotic-synthetic interface. However identifying the individual and synergistic contributions of the various combinations and concentration regimes is extremely
Sara V. Orski, Santanu Kundu, Richard Gross, Kathryn L. Beers
A two-dimensional model of a solid-supported enzyme catalyst bead is fabricated on a quartz crystal microbalance sensor to measure in situ stability and mechanical properties of Candida Antartica Lipase B (CAL B) layers under varied conditions relating to
Hockin D. Xu, Lei Cheng, Michael D. Weir, Joseph M. Antonucci, Nancy Lin, Sheng Lin-Gibson, Laurence Chow
Secondary caries is a frequent reason for dental restoration failure, resulting from acidogenic bacteria and their biofilms. Our objectives were to develop the first generation of bioactive nanocomposites and nano-structured bonding agents with
Edwin P. Chan, Allison P. Young, Jung-Hyun Lee, Jun-Young Chung, Christopher M. Stafford
We study the water swelling behavior of semi-aromatic crosslinked polyamide ultrathin films in order to characterize the materials properties of the polymer network. Specifically, we utilize X-ray reflectivity and quartz crystal microbalance to measure
Edwin P. Chan, Jung-Hyun Lee, Jun-Young Chung, Christopher M. Stafford
We present the design of an automated spin-coater that facilitates fabrication of polymer films based on molecular layer-by-layer (mLbL) assembly. Specifically, we demonstrate the synthesis of ultrathin crosslinked fully-aromatic polyamide films that are
Christopher L. Soles, Hyun W. Ro, K. J. Alvine, Oleg Shpyrko, Yenling Dai, Alec Sandy, Suresh Narayanan
The surface dynamics of thin molten polystyrene films supported by nanoscale periodic silicon line-space gratings were investigated with X-ray photon correlation spectroscopy. Surface dynamics over these nanostructures exhibit high directional anisotropy
Microstructures of biomedical scaffolds can greatly affect cellular activities in tissue regeneration. In particular, scaffolds used in bone tissue regeneration should have several microstructural characteristics, including high porosity, appropriate pore
Adam J. Berro, Andrew J. Berglund, Peter T. Carmichael, Jong S. Kim, James Alexander Liddle
Chemically amplified resists are the principal lithographic materials used in the semiconductor industry. The photoacid distribution generated upon exposure and its subsequent evolution during post-exposure bake is one of the most important factors that
Joseph J. Walish, Yin Fan , Andrea Centrone, Edwin L. Thomas
Controlling the color via temperature-induced changes of self-assembled photonic materials is important for their application in sensors and displays. The thermochromic behavior of a PS-P2VP photonic gel was studied (UV-VIS, FTIR) and found to originate
Constantine Y. Khripin, Xiaomin X. Tu, John Howarter, Jeffrey A. Fagan, Ming Zheng
Determination of the colloid concentration for a given single-wall carbon nanotube (SWCNT) dispersion is a basic requirement for many studies. The commonly used optical absorption based concentration measurement is complicated by the spectral change due to
Fred B. Bateman, Xinyu Li, Xiaoshi Qian, Haiming Gu, Xiangzhong Chen, Sheng-Guo Lu, Minren Lin, Qiming Zhang
We present directly measured electrocaloric effect (ECE) from the P(VDF-TrFE) 65/35 mol% copolymer which displays a first order FE-PE transition. The data reveal that there is a large difference in the ECE between that measured in applying field and in
Edwin P. Chan, Qinhuang Lin, Christopher M. Stafford
We apply thermal wrinkling, which is a surface instability that occurs during thermal annealing of polymer films geometrically confined by a rigid substrate and a flexible superstrate, to study the elasticity and viscosity of chemically-crosslinked polymer
Sara E. Campbell, Virginia L. Ferguson, Donna C. Hurley
The bone-cartilage, or osteochondral, interface resists remarkably high shear stresses and rarely fails, yet its mechanical characteristics are largely unknown. A complete understanding of this hierarchical system requires mechanical-property information
Hyun Wook Ro, Bulent Akgun, Regis J. Kline, Chad R. Snyder, Sushil K. Satija, Christopher L. Soles, Dean M. DeLongchamp, Michael F. Toney, Alexander L. Ayzner, Brendan T. O'Connor, Matthew Hammond
The mixing behavior of the hole and electron transporting materials in bulk heterojunction (BHJ) organic photovoltaic (OPV) blends plays a key role in determining the nanoscale morphology, which is believed to be a decisive factor in determining device