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Craig Brown (Fed)

NIST Fellow and Team Lead: Structure and Dynamics of Materials

A NIST Fellow, Adjunct Professor, Chemical Engineering, University of Delaware , and staff chemist at the NIST center for Neutron Research, where he is the team-lead for Structure and Dynamics of Materials. The team merges diffraction and spectroscopy, operating 7 neutron instruments. BT-1 and BT-8 for crystallography and engineering diffraction. MACSDCSFANSHFBS, and spin-echo for spectroscopy. He has also been an instrument scientist for the DCS Spectrometer and significantly involved with various aspects of the EERE hydrogen storage program where neutrons are an exceptional asset. He previously managed the NCNR efforts in the DoE/EERE Hydrogen Sorption Center of Excellence, sitting on the Steering Committee and co-leading the Strong Binding of Hydrogen sub-project with Dan Neumann and NREL.

Further details can be found here. 

Current interests include sculpting a Carbon dioxide capture, utilization and storage (CCUS) and direct air capture (DAC) project and developing a recently funded capability upgrade for several CHRNS funded neutron instruments.



  • Fellow of the Neutron Scattering Society of America.
  • Fellow of the American Crystallographic Society.
  • Recipient of the 2016 NIST Samuel Wesley Stratton Award recognizing an unusually significant research contribution to science or engineering that merits the acclaim of the scientific world and supports NIST's objectives.
  • Recipient of the 2016 DOE Hydrogen and Fuel Cells Program R&D Award for "outstanding achievements in absorbent-based hydrogen storage material research characterization".
  • Recipient of the 2011 Arthur S. Flemming Award for "seminal contributions to our understanding of new materials suited for hydrogen energy storage in next-generation, clean automobiles".
  • Recipient of the 2010 Department of Commerce Silver Medal for exceptional performance characterized by noteworthy or superlative contributions, which have a direct and lasting impact within the Department.
  • Recipient of the 2010 Neutron Scattering Society of America Science Prize with honorarium.
  • Recipient of the 2008 Presidential Early Career Award for Scientists and Engineers (PECASE). This is the highest honor bestowed by the United States government on young professionals in the early stages of their independent research careers and quite an amazing recognition of the environment and support I have benefited from whilst working at the NCNR and reflects upon the creativity and abilities of all of my collaborators.
  • Member of American Chemical Society Chemistry Society of Washington, American Crystallographic Association, Neutron Scattering Society of America

List of Talks (link)




2023, 2022, 2021, 2020, 2019, 2018, 2017, 2016, 2015, 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1996


  1. Flexing of a Metal–Organic Framework upon Hydrocarbon Adsorption: Atomic Level Insights from Neutron Scattering
    Trump, B.A., Qazvini, O.T., Lee, S.J., Jangodaz, E., Zhou, W., Brown, C.M., and Telfer, S.G., Chemistry of Materials (2023)


  1. Aluminum formate, Al(HCOO)3: An earth-abundant, scalable, and highly selective material for CO2 capture
    Evans, H.A., Mullangi, D., Deng, Z., Wang, Y., Peh, S.B., Wei, F., Wang, J., Brown, C.M., Zhao, D., Canepa, P., and Cheetham, A.K., Science Advances 8, eade1473 (2022)
  2. Influence of Inorganic Layer Thickness on Methylammonium Dynamics in Hybrid Perovskite Derivatives
    Koegel, A.A., Oswald, I.W.H., Rivera, C., Miller, S.L., Fallon, M.J., Prisk, T.R., Brown, C.M., and Neilson, J.R., Chemistry of Materials 34, 8316 (2022)
  3. Polyoxocationic antimony oxide cluster with acidic protons
    Watanabe, Y., Hyeon-Deuk, K., Yamamoto, T., Yabuuchi, M., Karakulina, O.M., Noda, Y., Kurihara, T., Chang, I.-Y., Higashi, M., Tomita, O., Tassel, C., Kato, D., Xia, J., Goto, T., Brown, C.M., Shimoyama, Y., Ogiwara, N., Hadermann, J., Abakumov, A.M., Uchida, S., Abe, R., and Kageyama, H., Science Advances 8, eabm5379 (2022)
  4. Turning Molecular Springs into Nano-Shock Absorbers: The Effect of Macroscopic Morphology and Crystal Size on the Dynamic Hysteresis of Water Intrusion–Extrusion into-from Hydrophobic Nanopores
    Zajdel, P., Madden, D.G., Babu, R., Tortora, M., Mirani, D., Tsyrin, N.N., Bartolomé, L., Amayuelas, E., Fairen-Jimenez, D., Lowe, A.R., Chorążewski, M., Leao, J.B., Brown, C.M., Bleuel, M., Stoudenets, V., Casciola, C.M., Echeverría, M., Bonilla, F., Grancini, G., Meloni, S., and Grosu, Y., ACS Applied Materials & Interfaces 14, 26699 (2022)
  5. Lattice Dynamics in the NASICON NaZr2(PO4)3 Solid Electrolyte from Temperature-Dependent Neutron Diffraction, NMR, and Ab Initio Computational Studies
    Morgan, E.E., Evans, H.A., Pilar, K., Brown, C.M., Clément, R.J., Maezono, R., Seshadri, R., Monserrat, B., and Cheetham, A.K., Chemistry of Materials 34, 4029 (2022)
  6. Magnetic-Field-Induced Dielectric Anomalies in Cobalt-Containing Garnets
    Neer, A.J., Milam-Guerrero, J., Fischer, V.A., Zheng, M., Spence, N.R., Cozzan, C., Gu, M., Rondinelli, J.M., Brown, C.M., and Melot, B.C., Inorganic Chemistry 61, 5452 (2022)
  7. Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor
    Sebti, E., Evans, H.A., Chen, H., Richardson, P.M., White, K.M., Giovine, R., Koirala, K.P., Xu, Y., Gonzalez-Correa, E., Wang, C., Brown, C.M., Cheetham, A.K., Canepa, P., and Clément, R.J., Journal of the American Chemical Society 144, 5795 (2022)
  8. Investigating the non-classical M-H2 bonding in OsClH3(PPh3)3
    Carter, C.C., Klein, R.A., Zhou, W., Udovic, T.J., Brown, C.M., Wen, T.-B., Cundari, T.R., and Yousufuddin, M., Journal of Alloys and Compounds 894, 162445 (2022)
  9. Neutron vibrational spectroscopic evidence for short H∙∙∙H contacts in the RNiInH1.4; 1.6 (R = Ce, La) metal hydride
    Klein, R.A., Balderas-Xicohténcatl, R., Maehlen, J.P., Udovic, T.J., Brown, C.M., Delaplane, R., Cheng, Y., Denys, R.V., Ramirez-Cuesta, A.J., and Yartys, V.A., Journal of Alloys and Compounds 894, 162381 (2022)
  10. Bi12O17Cl2 with a Sextuple Bi-O Layer Composed of Rock-Salt and Fluorite Units and its Structural Conversion through Fluorination to Enhance Photocatalytic Activity
    Kato, D., Tomita, O., Nelson, R., Kirsanova, M.A., Dronskowski, R., Suzuki, H., Zhong, C., Tassel, C., Ishida, K., Matsuzaki, Y., Brown, C.M., Fujita, K., Fujii, K., Yashima, M., Kobayashi, Y., Saeki, A., Oikawa, I., Takamura, H., Abe, R., Kageyama, H., Gorelik, T.E., and Abakumov, A.M., Advanced Functional Materials 32, 2204112 (2022)


  1. Physical properties of the quasi-two-dimensional square lattice antiferromagnet ${\mathrm{Ba}}_{2}{\mathrm{FeSi}}_{2}{\mathrm{O}}_{7}$
    Jang, T.-H., Do, S.-H., Lee, M., Wu, H., Brown, C.M., Christianson, A.D., Cheong, S.-W., and Park, J.-H., Physical Review B 104, 214434 (2021)
  2. Observation of an Intermediate to H2 Binding in a Metal–Organic Framework
    Barnett, B.R., Evans, H.A., Su, G.M., Jiang, H.Z.H., Chakraborty, R., Banyeretse, D., Hartman, T.J., Martinez, M.B., Trump, B.A., Tarver, J.D., Dods, M.N., Funke, L.M., Börgel, J., Reimer, J.A., Drisdell, W.S., Hurst, K.E., Gennett, T., FitzGerald, S.A., Brown, C.M., Head-Gordon, M., and Long, J.R., Journal of the American Chemical Society 143, 14884 (2021)
  3. Magnetic properties and signatures of moment ordering in the triangular lattice antiferromagnet ${\mathrm{KCeO}}_{2}$
    Bordelon, M.M., Wang, X., Pajerowski, D.M., Banerjee, A., Sherwin, M., Brown, C.M., Eldeeb, M.S., Petersen, T., Hozoi, L., Rößler, U.K., Mourigal, M., and Wilson, S.D., Physical Review B 104, 094421 (2021)
  4. The Rietveld Refinement Method: Half of a Century Anniversary
    Runčevski, T. and Brown, C.M., Crystal Growth & Design 21, 4821 (2021)
  5. Neutron Scattering Studies of Materials for Hydrogen Storage
    Klein, R.A., Evans, H.A., Trump, B.A., Udovic, T.J., and Brown, C.M., Neutron Scattering Studies of Materials for Hydrogen Storage (Amsterdam, The Netherlands: Elsevier, 2021)
  6. Spin Reorientation in Antiferromagnetic Layered FePt5P
    Gui, X., Marshall, M., Dissanayaka Mudiyanselage, R.S., Klein, R.A., Chen, Q., Zhang, Q., Shelton, W., Zhou, H., Brown, C.M., Cao, H., Greenblatt, M., and Xie, W., ACS Applied Electronic Materials (2021)
  7. Enhanced Magnetic Interaction by Face-Shared Hydride Anions in 6H-BaCrO2H
    Higashi, K., Ochi, M., Nambu, Y., Yamamoto, T., Murakami, T., Yamashina, N., Tassel, C., Matsumoto, Y., Takatsu, H., Brown, C.M., and Kageyama, H., Inorganic Chemistry (2021)
  8. Antiferromagnetic Order and Spin-Canting Transition in the Corrugated Square Net Compound Cu3(TeO4)(SO4)·H2O
    Wang, Z.-C., Thanabalasingam, K., Scheifers, J.P., Streeter, A., McCandless, G.T., Gaudet, J., Brown, C.M., Segre, C.U., Chan, J.Y., and Tafti, F., Inorganic Chemistry (2021)
  9. Compact Thermal Actuation by Water and Flexible Hydrophobic Nanopore
    Chorążewski, M., Zajdel, P., Feng, T., Luo, D., Lowe, A.R., Brown, C.M., Leão, J.B., Li, M., Bleuel, M., Jensen, G., Li, D., Faik, A., and Grosu, Y., ACS Nano 15, 9048 (2021)
  10. Spin Frustration in Double Perovskite Oxides and Oxynitrides: Enhanced Frustration in La2MnTaO5N with a Large Octahedral Rotation
    Ishida, K., Tassel, C., Watabe, D., Takatsu, H., Brown, C.M., Nilsen, G.J., and Kageyama, H., Inorganic Chemistry (2021)
  11. Ambient-Temperature Hydrogen Storage via Vanadium(II)-Dihydrogen Complexation in a Metal–Organic Framework
    Jaramillo, D.E., Jiang, H.Z.H., Evans, H.A., Chakraborty, R., Furukawa, H., Brown, C.M., Head-Gordon, M., and Long, J.R., Journal of the American Chemical Society 143, 6248 (2021)
  12. Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis
    Nakada, A., Kato, D., Nelson, R., Takahira, H., Yabuuchi, M., Higashi, M., Suzuki, H., Kirsanova, M., Kakudou, N., Tassel, C., Yamamoto, T., Brown, C.M., Dronskowski, R., Saeki, A., Abakumov, A., Kageyama, H., and Abe, R., Journal of the American Chemical Society 143, 2491 (2021)
  13. Chemical Bonding Governs Complex Magnetism in MnPt5P
    Gui, X., Klein, R.A., Brown, C.M., and Xie, W., Inorganic Chemistry 60, 87 (2021)
  14. Néel ordering in the distorted honeycomb pyrosilicate: C–Er2Si2O7
    Hester, G., DeLazzer, T.N., Lim, S.S., Brown, C.M., and Ross, K.A., Journal of Physics: Condensed Matter 33, 125804 (2021)
  15. Structural resolution and mechanistic insight into hydrogen adsorption in flexible ZIF-7
    A. Klein, R., Shulda, S., A. Parilla, P., Magueres, P.L., K. Richardson, R., Morris, W., M. Brown, C., and Michael McGuirk, C., Chemical Science 12, 15620 (2021)
  16. Magnetic structure, excitations and short-range order in honeycomb Na2Ni2TeO6
    Episcopo, N., Chang, P.-H., Heitmann, T., Wangmo, K., Guthrie, J.M., Fitta, M., Klein, R., Poudel, N., Gofryk, K., Zope, R.R., Brown, C.M., and Nair, H.S., Journal of Physics: Condensed Matter (2021)


  1. Competing antiferromagnetic-ferromagnetic states in a ${d}^{7}$ Kitaev honeycomb magnet
    Vivanco, H.K., Trump, B.A., Brown, C.M., and McQueen, T.M., Physical Review B 102, 224411 (2020)
  2. Strain-induced creation and switching of anion vacancy layers in perovskite oxynitrides
    Yamamoto, T., Chikamatsu, A., Kitagawa, S., Izumo, N., Yamashita, S., Takatsu, H., Ochi, M., Maruyama, T., Namba, M., Sun, W., Nakashima, T., Takeiri, F., Fujii, K., Yashima, M., Sugisawa, Y., Sano, M., Hirose, Y., Sekiba, D., Brown, C.M., Honda, T., Ikeda, K., Otomo, T., Kuroki, K., Ishida, K., Mori, T., Kimoto, K., Hasegawa, T., and Kageyama, H., Nature Communications 11, 5923 (2020)
  3. Dynamics of Hydroxyl Anions Promotes Lithium Ion Conduction in Antiperovskite Li2OHCl
    Wang, F., Evans, H.A., Kim, K., Yin, L., Li, Y., Tsai, P.-C., Liu, J., Lapidus, S.H., Brown, C.M., Siegel, D.J., and Chiang, Y.-M., Chemistry of Materials 32, 8481 (2020)
  4. Elucidating the Structure of the Metal–Organic Framework Ru-HKUST-1
    Lorzing, G.R., Balto, K.P., Antonio, A.M., Trump, B.A., Brown, C.M., and Bloch, E.D., Chemistry of Materials 32, 7710 (2020)
  5. Peritectic Phase Transition of Benzene and Acetonitrile and Formation of a Cocrystal Relevant to Titan, Saturn’s Icy Moon
    McConville, C., Tao, Y., Evans, H., Trump, B.A., Lefton, J.B., Xu, W., Yakovenko, A., Kraka, E., Brown, C.M., and Runcevski, T., (2020)
  6. Self-adjusting binding pockets enhance H2 and CH4 adsorption in a uranium-based metal–organic framework
    Halter, D.P., Klein, R.A., Boreen, M.A., Trump, B.A., Brown, C.M., and Long, J.R., Chemical Science 11, 6709 (2020)
  7. Negative cooperativity upon hydrogen bond-stabilized O 2 adsorption in a redox-active metal–organic framework
    Oktawiec, J., Jiang, H.Z.H., Vitillo, J.G., Reed, D.A., Darago, L.E., Trump, B.A., Bernales, V., Li, H., Colwell, K.A., Furukawa, H., Brown, C.M., Gagliardi, L., and Long, J.R., Nature Communications 11, 3087 (2020)
  8. Inter-Kramers Transitions and Spin–Phonon Couplings in a Lanthanide-Based Single-Molecule Magnet
    Moseley, D.H., Stavretis, S.E., Zhu, Z., Guo, M., Brown, C.M., Ozerov, M., Cheng, Y., Daemen, L.L., Richardson, R., Knight, G., Thirunavukkuarasu, K., Ramirez-Cuesta, A.J., Tang, J., and Xue, Z.-L., Inorganic Chemistry 59, 5218 (2020)
  9. Metastability and Reversibility of Anionic Redox-Based Cathode for High-Energy Rechargeable Batteries
    Qiu, B., Zhang, M., Lee, S.-Y., Liu, H., Wynn, T.A., Wu, L., Zhu, Y., Wen, W., Brown, C.M., Zhou, D., Liu, Z., and Meng, Y.S., Cell Reports Physical Science 1, 100028 (2020)
  10. Long-range magnetic order in hydroxide-layer-doped $({\mathrm{Li}}_{1\ensuremath{-}x\ensuremath{-}y}{\mathrm{Fe}}_{x}{\mathrm{Mn}}_{y}\mathrm{OD})\mathrm{FeSe}$
    Wilfong, B., Zhou, X., Zheng, H., Babra, N., Brown, C.M., Lynn, J.W., Taddei, K.M., Paglione, J., and Rodriguez, E.E., Physical Review Materials 4, 034803 (2020)
  11. Certification of Standard Reference Material 660c for powder diffraction
    Black, D.R., Mendenhall, M.H., Brown, C.M., Henins, A., Filliben, J., and Cline, J.P., Powder Diffraction 35, 17 (2020)
  12. Special section – Crystallography and properties of metal–organic framework (MOF) compounds
    Brown, C.M. and Wong-Ng, W., Powder Diffraction 35, 2 (2020)
  13. Understanding How Ligand Functionalization Influences CO2 and N2 Adsorption in a Sodalite Metal–Organic Framework
    Asgari, M., Semino, R., Schouwink, P.A., Kochetygov, I., Tarver, J., Trukhina, O., Krishna, R., Brown, C.M., Ceriotti, M., and Queen, W.L., Chemistry of Materials 32, 1526 (2020)
  14. Molecular Insight into Fluorocarbon Adsorption in Pore Expanded Metal–Organic Framework Analogs
    Zheng, J., Barpaga, D., Trump, B.A., Shetty, M., Fan, Y., Bhattacharya, P., Jenks, J.J., Su, C.-Y., Brown, C.M., Maurin, G., McGrail, B.P., and Motkuri, R.K., Journal of the American Chemical Society 142, 3002 (2020)
  15. Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
    Skorupskii, G., Trump, B.A., Kasel, T.W., Brown, C.M., Hendon, C.H., and Dincă, M., Nature Chemistry 12, 131 (2020)
  16. Neutron diffraction structural study of CO 2 binding in mixed-metal CPM-200 metal–organic frameworks
    J. Campanella, A., A. Trump, B., J. Gosselin, E., D. Bloch, E., and M. Brown, C., Chemical Communications 56, 2574 (2020)


  1. Realization of interlayer ferromagnetic interaction in $\mathrm{MnS}{\mathrm{b}}_{2}\mathrm{T}{\mathrm{e}}_{4}$ toward the magnetic Weyl semimetal state
    Murakami, T., Nambu, Y., Koretsune, T., Xiangyu, G., Yamamoto, T., Brown, C.M., and Kageyama, H., Physical Review B 100, 195103 (2019)
  2. Elusive Valence Transition in Mixed-Valence Sesquioxide Cs4O6
    Colman, R.H., Okur, H.E., Kockelmann, W., Brown, C.M., Sans, A., Felser, C., Jansen, M., and Prassides, K., Inorganic Chemistry (2019)
  3. Common acoustic phonon lifetimes in inorganic and hybrid lead halide perovskites
    Songvilay, M., Giles-Donovan, N., Bari, M., Ye, Z.-G., Minns, J.L., Green, M.A., Xu, G., Gehring, P.M., Schmalzl, K., Ratcliff, W.D., Brown, C.M., Chernyshov, D., van Beek, W., Cochran, S., and Stock, C., Physical Review Materials 3, 093602 (2019)
  4. Dynamical Phase Transitions and Cation Orientation-Dependent Photoconductivity in CH(NH2)2PbBr3
    Mozur, E.M., Trowbridge, J.C., Maughan, A.E., Gorman, M.J., Brown, C.M., Prisk, T.R., and Neilson, J.R., ACS Materials Letters 1, 260 (2019)
  5. Accessing New Charge-Transfer Complexes by Mechanochemistry: A Tetrathiafulvalene Chloranilic Acid Polymorph Containing Segregated Tetrathiafulvalene Stacks
    Jones, J., Ta Phuoc, V., del Campo, L., Massa, N.E., Brown, C.M., and Pagola, S., Crystal Growth & Design (2019)
  6. Understanding Gas Storage in Cuboctahedral Porous Coordination Cages
    Lorzing, G.R., Gosselin, E.J., Trump, B.A., York, A.H.P., Sturluson, A., Rowland, C.A., Yap, G.P.A., Brown, C.M., Simon, C.M., and Bloch, E.D., Journal of the American Chemical Society 141, 12128 (2019)
  7. Competing Polar and Antipolar Structures in the Ruddlesden–Popper Layered Perovskite Li2SrNb2O7
    Uppuluri, R., Akamatsu, H., Sen Gupta, A., Wang, H., Brown, C.M., Agueda Lopez, K.E., Alem, N., Gopalan, V., and Mallouk, T.E., Chemistry of Materials 31, 4418 (2019)
  8. High-Pressure Synthesis of Non-Stoichiometric LixWO3 (0.5 ≤ x ≤ 1.0) with LiNbO3 Structure
    Ishida, K., Ikeuchi, Y., Tassel, C., Takatsu, H., Brown, C.M., and Kageyama, H., Inorganics 7, 63 (2019)
  9. Rattling Behavior in a Simple Perovskite NaWO3
    Ikeuchi, Y., Takatsu, H., Tassel, C., Brown, C.M., Murakami, T., Matsumoto, Y., Okamoto, Y., and Kageyama, H., Inorganic Chemistry (2019)
  10. New insights into water dynamics of Portland cement paste with nano-additives using quasielastic neutron scattering
    Kupwade-Patil, K., Bumajdad, A., Brown, C.M., Tyagi, M., Butch, N.P., Jamsheer, A.F., and Büyüköztürk, O., Journal of Materials Science 54, 4710 (2019)
  11. An In-Situ Neutron Diffraction and DFT Study of Hydrogen Adsorption in a Sodalite-Type Metal–Organic Framework, Cu-BTTri
    Asgari, M., Semino, R., Schouwink, P., Kochetygov, I., Trukhina, O., Tarver, J.D., Bulut, S., Yang, S., Brown, C.M., Ceriotti, M., and Queen, W.L., European Journal of Inorganic Chemistry 2019, 1147 (2019)
  12. Probing Magnetic Excitations in CoII Single-Molecule Magnets by Inelastic Neutron Scattering
    Stavretis, S.E., Cheng, Y., Daemen, L.L., Brown, C.M., Moseley, D.H., Bill, E., Atanasov, M., Ramirez-Cuesta, A.J., Neese, F., and Xue, Z.-L., European Journal of Inorganic Chemistry 2019, 1055 (2019)
  13. Neutron Instruments for Research in Coordination Chemistry
    Xue, Z.-L., Ramirez-Cuesta, A.J., Brown, C.M., Calder, S., Cao, H., Chakoumakos, B.C., Daemen, L.L., Huq, A., Kolesnikov, A.I., Mamontov, E., Podlesnyak, A.A., and Wang, X., European Journal of Inorganic Chemistry 2019, 1065 (2019)
  14. “Field-tunable quantum disordered ground state in the triangular lattice antiferromagnet NaYbO$_2$” Bordelon, M., Kenney, E., Hogan, T., Posthuma, L., Kavand, M., Lyu, Y., Sherwin, M., Brown, C., Graf, M.J., Balents, L., and Wilson, S.D., ArXiv:1901.09408 [Cond-Mat] (2019)
  15. $\mathrm{N}{\mathrm{i}}_{2}\mathrm{M}{\mathrm{o}}_{3}{\mathrm{O}}_{8}$: Complex antiferromagnetic order on a honeycomb lattice
    Morey, J.R., Scheie, A., Sheckelton, J.P., Brown, C.M., and McQueen, T.M., Physical Review Materials 3, 014410 (2019)
  16. Deciphering structural and magnetic disorder in the chiral skyrmion host materials ${\mathrm{Co}}_{x}{\mathrm{Zn}}_{y}{\mathrm{Mn}}_{z}$ ($x+y+z=20$)
    Bocarsly, J.D., Heikes, C., Brown, C.M., Wilson, S.D., and Seshadri, R., Physical Review Materials 3, 014402 (2019)


  1. Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni2(m-dobdc) at Near-Ambient Temperatures
    Kapelewski, M.T., Runčevski, T., Tarver, J.D., Jiang, H.Z.H., Hurst, K.E., Parilla, P.A., Ayala, A., Gennett, T., FitzGerald, S.A., Brown, C.M., and Long, J.R., Chemistry of Materials 30, 8179 (2018)
  2. Defect-driven extreme magnetoresistance in an I-Mn-V semiconductor
    Yang, J., Wegner, A., Brown, C.M., and Louca, D., Applied Physics Letters 113, 122105 (2018)
  3. Methane Storage in Paddlewheel-Based Porous Coordination Cages
    Rowland, C.A., Lorzing, G.R., Gosselin, E.J., Trump, B.A., Yap, G.P.A., Brown, C.M., and Bloch, E.D., Journal of the American Chemical Society 140, 11153 (2018)
  4. Certification of Standard Reference Material 1879b respirable cristobalite
    Black, D.R., Mendenhall, M.H., Whitfield, P.S., Brown, C.M., Henins, A., Filliben, J.J., and Cline, J.P., Powder Diffraction 33, 202 (2018)
  5. Spin–phonon couplings in transition metal complexes with slow magnetic relaxation
    Moseley, D.H., Stavretis, S.E., Thirunavukkuarasu, K., Ozerov, M., Cheng, Y., Daemen, L.L., Ludwig, J., Lu, Z., Smirnov, D., Brown, C.M., Pandey, A., Ramirez-Cuesta, A.J., Lamb, A.C., Atanasov, M., Bill, E., Neese, F., and Xue, Z.-L., Nature Communications 9, 2572 (2018)
  6. Proton and ammonia intercalation into layered iron chalcogenides
    Zhou, X., Wilfong, B., Liou, S.-C., Hodovanets, H., Brown, C.M., and Rodriguez, E.E., Chemical Communications54, 6895 (2018)
  7. An experimental and computational study of CO2 adsorption in the sodalite-type M-BTT (M = Cr, Mn, Fe, Cu) metal–organic frameworks featuring open metal sites
    Asgari, M., Jawahery, S., Bloch, E.D., Hudson, M.R., Flacau, R., Vlaisavljevich, B., Long, J.R., Brown, C.M., and Queen, W.L., Chemical Science 9, 4579 (2018)
  8. Magnetic ordering in a frustrated bow-tie lattice
    Stimpson, L.J.V., Rodriguez, E.E., Brown, C.M., Stenning, G.B.G., Jura, M., and Arnold, D.C., Journal of Materials Chemistry C 6, 4541 (2018)
  9. Quantum Dynamics of ${\mathrm{H}}_{2}$ Trapped within Organic Clathrate Cages
    Strobel, T.A., Ramirez-Cuesta, A.J., Daemen, L.L., Bhadram, V.S., Jenkins, T.A., Brown, C.M., and Cheng, Y., Physical Review Letters 120, 120402 (2018)
  10. Unravelling Solid-State Redox Chemistry in Li1.3Nb0.3Mn0.4O2 Single-Crystal Cathode Material
    Kan, W.H., Chen, D., Papp, J.K., Shukla, A.K., Huq, A., Brown, C.M., McCloskey, B.D., and Chen, G., Chemistry of Materials 30, 1655 (2018)
  11. Selective Hydride Occupation in BaVO3–xHx (0.3 ≤ x ≤ 0.8) with Face- and Corner-Shared Octahedra
    Yamamoto, T., Shitara, K., Kitagawa, S., Kuwabara, A., Kuroe, M., Ishida, K., Ochi, M., Kuroki, K., Fujii, K., Yashima, M., Brown, C.M., Takatsu, H., Tassel, C., and Kageyama, H., Chemistry of Materials 30, 1566 (2018)
  12. Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks
    Gonzalez, M.I., Kapelewski, M.T., Bloch, E.D., Milner, P.J., Reed, D.A., Hudson, M.R., Mason, J.A., Barin, G., Brown, C.M., and Long, J.R., Journal of the American Chemical Society 140, 3412 (2018)
  13. Rapid Microwave Preparation and Composition Tuning of the High-Performance Magnetocalorics (Mn,Fe)2(P,Si)
    Grebenkemper, J.H., Bocarsly, J.D., Levin, E.E., Seward, G., Heikes, C., Brown, C., Misra, S., Seeler, F., Schierle-Arndt, K., Wilson, S.D., and Seshadri, R., ACS Applied Materials & Interfaces 10, 7208 (2018)
  14. H2 Adsorption on Cu(I)–SSZ-13
    Ipek, B., Pollock, R.A., Brown, C.M., Uner, D., and Lobo, R.F., The Journal of Physical Chemistry C 122, 540 (2018)
  15. Gas adsorption in an isostructural series of pillared coordination cages
    J. Gosselin, E., R. Lorzing, G., A. Trump, B., M. Brown, C., and D. Bloch, E., Chemical Communications 54, 6392 (2018)


  1. Pressure tuning of collapse of helimagnetic structure in ${\mathrm{Au}}_{2}\mathrm{Mn}$
    Liu, I.-L., Pascale, M.J., Leao, J.B., Brown, C.M., Ratcliff, W.D., Huang, Q., and Butch, N.P., Physical Review B96, 184429 (2017)
  2. Electronic Conductivity in a Porous Vanadyl Prussian Blue Analogue upon Air Exposure
    Manumpil, M.A., Leal-Cervantes, C., Hudson, M.R., Brown, C.M., and Karunadasa, H.I., Inorganic Chemistry 56, 12682 (2017)
  3. Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal–Organic Polyhedra
    Lorzing, G.R., Trump, B.A., Brown, C.M., and Bloch, E.D., Chemistry of Materials 29, 8583 (2017)
  4. Origin of long lifetime of band-edge charge carriers in organic–inorganic lead iodide perovskites
    Chen, T., Chen, W.-L., Foley, B.J., Lee, J., Ruff, J.P.C., Ko, J.Y.P., Brown, C.M., Harriger, L.W., Zhang, D., Park, C., Yoon, M., Chang, Y.-M., Choi, J.J., and Lee, S.-H., Proceedings of the National Academy of Sciences 114, 7519 (2017)
  5. Formation of [Cu 2 O 2 ] 2+ and [Cu 2 O] 2+ toward C–H Bond Activation in Cu-SSZ-13 and Cu-SSZ-39
    Ipek, B., Wulfers, M.J., Kim, H., Göltl, F., Hermans, I., Smith, J.P., Booksh, K.S., Brown, C.M., and Lobo, R.F., ACS Catalysis 7, 4291 (2017)
  6. Metal–insulator transition tuned by magnetic field in Bi1.7V8O16 hollandite
    Larson, A.M., Wilfong, B., Moetakef, P., Brown, C.M., Zavalij, P., and Rodriguez, E.E., Journal of Materials Chemistry C 5, 4967 (2017)
  7. Reversible Capture and Release of Cl 2 and Br 2 with a Redox-Active Metal–Organic Framework
    Tulchinsky, Y., Hendon, C.H., Lomachenko, K.A., Borfecchia, E., Melot, B.C., Hudson, M.R., Tarver, J.D., Korzyński, M.D., Stubbs, A.W., Kagan, J.J., Lamberti, C., Brown, C.M., and Dincă, M., Journal of the American Chemical Society 139, 5992 (2017)
  8. Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an $S=1$ quantum antiferromagnet
    Brambleby, J., Manson, J.L., Goddard, P.A., Stone, M.B., Johnson, R.D., Manuel, P., Villa, J.A., Brown, C.M., Lu, H., Chikara, S., Zapf, V., Lapidus, S.H., Scatena, R., Macchi, P., Chen, Y., Wu, L.-C., and Singleton, J., Physical Review B 95, 134435 (2017)
  9. Ising-like antiferromagnetism on the octahedral sublattice of a cobalt-containing garnet and the potential for quantum criticality
    Neer, A.J., Milam-Guerrero, J., So, J.E., Melot, B.C., Ross, K.A., Hulvey, Z., Brown, C.M., Sokol, A.A., and Scanlon, D.O., Physical Review B 95, 144419 (2017)
  10. Cubic lead perovskite ${\mathrm{PbMoO}}_{3}$ with anomalous metallic behavior
    Takatsu, H., Hernandez, O., Yoshimune, W., Prestipino, C., Yamamoto, T., Tassel, C., Kobayashi, Y., Batuk, D., Shibata, Y., Abakumov, A.M., Brown, C.M., and Kageyama, H., Physical Review B 95, 155105 (2017)
  11. On the Structure-Property Relationships of Cation-Exchanged ZK-5 Zeolites for CO 2 Adsorption
    Pham, T.D., Hudson, M.R., Brown, C.M., and Lobo, R.F., ChemSusChem 10, 946 (2017)
  12. Performance of van der Waals Corrected Functionals for Guest Adsorption in the M 2 (dobdc) Metal–Organic Frameworks
    Vlaisavljevich, B., Huck, J., Hulvey, Z., Lee, K., Mason, J.A., Neaton, J.B., Long, J.R., Brown, C.M., Alfè, D., Michaelides, A., and Smit, B., The Journal of Physical Chemistry A 121, 4139 (2017)


  1. Metastable Layered Cobalt Chalcogenides from Topochemical Deintercalation
    Zhou, X., Wilfong, B., Vivanco, H., Paglione, J., Brown, C.M., and Rodriguez, E.E., Journal of the American Chemical Society 138, 16432 (2016)
  2. ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure
    Kuno, Y., Tassel, C., Fujita, K., Batuk, D., Abakumov, A.M., Shitara, K., Kuwabara, A., Moriwake, H., Watabe, D., Ritter, C., Brown, C.M., Yamamoto, T., Takeiri, F., Abe, R., Kobayashi, Y., Tanaka, K., and Kageyama, H., Journal of the American Chemical Society 138, 15950 (2016)
  3. Tuning the Adsorption-Induced Phase Change in the Flexible Metal–Organic Framework Co(bdp)
    Taylor, M.K., Runčevski, T., Oktawiec, J., Gonzalez, M.I., Siegelman, R.L., Mason, J.A., Ye, J., Brown, C.M., and Long, J.R., Journal of the American Chemical Society 138, 15019 (2016)
  4. Entropy-driven structural transition and kinetic trapping in formamidinium lead iodide perovskite
    Chen, T., Foley, B.J., Park, C., Brown, C.M., Harriger, L.W., Lee, J., Ruff, J., Yoon, M., Choi, J.J., and Lee, S.-H., Science Advances 2, e1601650 (2016)
  5. Three-dimensional protonic conductivity in porous organic cage solids
    Liu, M., Chen, L., Lewis, S., Chong, S.Y., Little, M.A., Hasell, T., Aldous, I.M., Brown, C.M., Smith, M.W., Morrison, C.A., Hardwick, L.J., and Cooper, A.I., Nature Communications 7, 12750 (2016)
  6. High-Pressure Synthesis of Manganese Oxyhydride with Partial Anion Order
    Tassel, C., Goto, Y., Watabe, D., Tang, Y., Lu, H., Kuno, Y., Takeiri, F., Yamamoto, T., Brown, C.M., Hester, J., Kobayashi, Y., and Kageyama, H., Angewandte Chemie 128, 9819 (2016)
  7. Water dynamics in cement paste at early age prepared with pozzolanic volcanic ash and Ordinary Portland Cement using quasielastic neutron scattering
    Kupwade-Patil, K., Tyagi, M., Brown, C.M., and Büyüköztürk, O., Cement and Concrete Research 86, 55 (2016)
  8. Hydrogen Storage and Selective, Reversible O 2 Adsorption in a Metal-Organic Framework with Open Chromium(II) Sites
    Bloch, E.D., Queen, W.L., Hudson, M.R., Mason, J.A., Xiao, D.J., Murray, L.J., Flacau, R., Brown, C.M., and Long, J.R., Angewandte Chemie International Edition 55, 8605 (2016)
  9. Quasi-Elastic Neutron Scattering Studies of Hydrogen Dynamics for Nanoconfined NaAlH 4
    NaraseGowda, S., Brown, C.M., Tyagi, M., Jenkins, T., and Dobbins, T.A., The Journal of Physical Chemistry C120, 14863 (2016)
  10. Strong correlations between vacancy and magnetic ordering in superconducting ${\mathrm{K}}_{0.8}{\mathrm{Fe}}_{2\ensuremath{-}y}{\mathrm{Se}}_{2}$
    Yang, J., Duan, C., Huang, Q., Brown, C., Neuefeind, J., and Louca, D., Physical Review B 94, 024503 (2016)
  11. High Thermopower with Metallic Conductivity in p -Type Li-Substituted PbPdO 2
    Lamontagne, L.K., Laurita, G., Gaultois, M.W., Knight, M., Ghadbeigi, L., Sparks, T.D., Gruner, M.E., Pentcheva, R., Brown, C.M., and Seshadri, R., Chemistry of Materials 28, 3367 (2016)
  12. Physical properties of the ${\mathrm{Ce}}_{2}M\mathrm{Al}{}_{7}{\mathrm{Ge}}_{4}$ heavy-fermion compounds $(M=\text{Co},\text{Ir},\text{Ni},\text{Pd})$
    Ghimire, N.J., Cary, S.K., Eley, S., Wakeham, N.A., Rosa, P.F.S., Albrecht-Schmitt, T., Lee, Y., Janoschek, M., Brown, C.M., Civale, L., Thompson, J.D., Ronning, F., and Bauer, E.D., Physical Review B 93, 205141 (2016)
  13. Hydration-induced spin-glass state in a frustrated Na-Mn-O triangular lattice
    Bakaimi, I., Brescia, R., Brown, C.M., Tsirlin, A.A., Green, M.A., and Lappas, A., Physical Review B 93, 184422 (2016)
  14. Dynamics of Pyramidal SiH 3 – Ions in ASiH 3 (A = K and Rb) Investigated with Quasielastic Neutron Scattering
    Österberg, C., Fahlquist, H., Häussermann, U., Brown, C.M., Udovic, T.J., and Karlsson, M., The Journal of Physical Chemistry C 120, 6369 (2016)
  15. Topochemical Nitridation with Anion Vacancy-Assisted N3–/O2– Exchange
    Mikita, R., Aharen, T., Yamamoto, T., Takeiri, F., Ya, T., Yoshimune, W., Fujita, K., Yoshida, S., Tanaka, K., Batuk, D., Abakumov, A.M., Brown, C.M., Kobayashi, Y., and Kageyama, H., Journal of the American Chemical Society138, 3211 (2016)
  16. Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
    Gygi, D., Bloch, E.D., Mason, J.A., Hudson, M.R., Gonzalez, M.I., Siegelman, R.L., Darwish, T.A., Queen, W.L., Brown, C.M., and Long, J.R., Chemistry of Materials 28, 1128 (2016)
  17. Improved Catalytic Activity and Stability of a Palladium Pincer Complex by Incorporation into a Metal–Organic Framework
    Burgess, S.A., Kassie, A., Baranowski, S.A., Fritzsching, K.J., Schmidt-Rohr, K., Brown, C.M., and Wade, C.R., Journal of the American Chemical Society 138, 1780 (2016)
  18. Local Jahn-Teller distortions and orbital ordering in ${\mathrm{Ba}}_{3}{\mathrm{Cu}}_{1+x}{\mathrm{Sb}}_{2\ensuremath{-}x}{\mathrm{O}}_{9}$ investigated by neutron scattering
    Li, B., Louca, D., Feygenson, M., Brown, C.M., Copley, J.R.D., and Iida, K., Physical Review B 93, 014423 (2016)
  19. Outlook and challenges for hydrogen storage in nanoporous materials
    Broom, D.P., Webb, C.J., Hurst, K.E., Parilla, P.A., Gennett, T., Brown, C.M., Zacharia, R., Tylianakis, E., Klontzas, E., Froudakis, G.E., Steriotis, T.A., Trikalitis, P.N., Anton, D.L., Hardy, B., Tamburello, D., Corgnale, C., van Hassel, B.A., Cossement, D., Chahine, R., and Hirscher, M., Applied Physics A 122, (2016)
  20. Adsorption of two gas molecules at a single metal site in a metal–organic framework
    Runčevski, T., Kapelewski, M.T., Torres-Gavosto, R.M., Tarver, J.D., Brown, C.M., and Long, J.R., Chemical Communications 52, 8251 (2016)
  21. The low-temperature structural behavior of sodium 1-carba- closo -decaborate: NaCB 9 H 10
    Wu, H., Tang, W.S., Zhou, W., Tarver, J.D., Stavila, V., Brown, C.M., and Udovic, T.J., Journal of Solid State Chemistry 243, 162 (2016)
  22. The magnetic transitions and dynamics in the multiferroic Lu0.5Sc0.5FeO3
    Yang, J., Duan, C., Copley, J.R.D., Brown, C.M., and Louca, D., MRS Advances 1, 565 (2016)


  1. Magnetic Structure and Exchange Interactions in Quasi-One-Dimensional MnCl2(urea)2
    Manson, J.L., Huang, Q., Brown, C.M., Lynn, J.W., Stone, M.B., Singleton, J., and Xiao, F., Inorganic Chemistry54, 11897 (2015)
  2. A labile hydride strategy for the synthesis of heavily nitridized BaTiO3
    Yajima, T., Takeiri, F., Aidzu, K., Akamatsu, H., Fujita, K., Yoshimune, W., Ohkura, M., Lei, S., Gopalan, V., Tanaka, K., Brown, C.M., Green, M.A., Yamamoto, T., Kobayashi, Y., and Kageyama, H., Nature Chemistry 7, 1017 (2015)
  3. Observation of drastic change of generalized phonon density-of-states in nanostructured half-Heusler using inelastic neutron scattering
    Wong-Ng, W., Lynn, J.W., Huang, Q., Brown, C.M., Kaduk, J.A., and Joshi, G., Applied Physics Letters 107, 213901 (2015)
  4. Methane storage in flexible metal–organic frameworks with intrinsic thermal management
    Mason, J.A., Oktawiec, J., Taylor, M.K., Hudson, M.R., Rodriguez, J., Bachman, J.E., Gonzalez, M.I., Cervellino, A., Guagliardi, A., Brown, C.M., Llewellyn, P.L., Masciocchi, N., and Long, J.R., Nature 527, 357 (2015)
  5. Oxygen interstitials and vacancies in LaSrGa3O7-based melilites
    Xu, J., Li, X., Lu, F., Fu, H., Brown, C.M., and Kuang, X., Journal of Solid State Chemistry 230, 309 (2015)
  6. Critical Factors Driving the High Volumetric Uptake of Methane in Cu 3 (btc) 2
    Hulvey, Z., Vlaisavljevich, B., Mason, J.A., Tsivion, E., Dougherty, T.P., Bloch, E.D., Head-Gordon, M., Smit, B., Long, J.R., and Brown, C.M., Journal of the American Chemical Society 137, 10816 (2015)
  7. Evolution of magnetism in the Na3−δ(Na1−xMgx)Ir2O6 series of honeycomb iridates
    Wallace, D.C., Brown, C.M., and McQueen, T.M., Journal of Solid State Chemistry 224, 28 (2015)
  8. Gradual Release of Strongly Bound Nitric Oxide from Fe 2 (NO) 2 (dobdc)
    Bloch, E.D., Queen, W.L., Chavan, S., Wheatley, P.S., Zadrozny, J.M., Morris, R., Brown, C.M., Lamberti, C., Bordiga, S., and Long, J.R., Journal of the American Chemical Society 137, 3466 (2015)
  9. Inducing Ferrimagnetism in Insulating Hollandite Ba1.2Mn8O16
    Larson, A.M., Moetakef, P., Gaskell, K., Brown, C.M., King, G., and Rodriguez, E.E., Chemistry of Materials 27, 515 (2015)
  10. MnTaO2N: Polar LiNbO3-type Oxynitride with a Helical Spin Order
    Tassel, C., Kuno, Y., Goto, Y., Yamamoto, T., Brown, C.M., Hester, J., Fujita, K., Higashi, M., Abe, R., Tanaka, K., Kobayashi, Y., and Kageyama, H., Angewandte Chemie International Edition 54, 516 (2015)
  11. Flexible metal-organic framework compounds: In situ studies for selective CO 2 capture
    Allen, A.J., Espinal, L., Wong-Ng, W., Queen, W.L., Brown, C.M., Kline, S.R., Kauffman, K.L., Culp, J.T., and Matranga, C., Journal of Alloys and Compounds 647, 24 (2015)
  12. Rotational dynamics of organic cations in the CH 3 NH 3 PbI 3 perovskite
    Chen, T., Foley, B.J., Ipek, B., Tyagi, M., Copley, J.R.D., Brown, C.M., Choi, J.J., and Lee, S.-H., Physical Chemistry Chemical Physics 17, 31278 (2015)
  13. Stabilization of cubic Sr 2 FeMoO 6 through topochemical reduction
    D. Taylor, D., J. Schreiber, N., M. Brown, C., M. Arevalo-Lopez, A., and E. Rodriguez, E., Chemical Communications 51, 12201 (2015)
  14. Understanding Small-Molecule Interactions in Metal-Organic Frameworks: Coupling Experiment with Theory
    Lee, J.S., Vlaisavljevich, B., Britt, D.K., Brown, C.M., Haranczyk, M., Neaton, J.B., Smit, B., Long, J.R., and Queen, W.L., Advanced Materials 27, 5785 (2015)


  1. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn
    Douglas, J.E., Chater, P.A., Brown, C.M., Pollock, T.M., and Seshadri, R., Journal of Applied Physics 116, 163514 (2014)
  2. Comprehensive study of carbon dioxide adsorption in the metal organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)
    Queen, W.L., Hudson, M.R., Bloch, E.D., Mason, J.A., Gonzalez, M.I., Lee, J.S., Gygi, D., Howe, J.D., Lee, K., Darwish, T.A., James, M., Peterson, V.K., Teat, S.J., Smit, B., Neaton, J.B., Long, J.R., and Brown, C.M., Chem. Sci. 5, 4569 (2014)
  3. M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
    Kapelewski, M.T., Geier, S.J., Hudson, M.R., Stück, D., Mason, J.A., Nelson, J.N., Xiao, D.J., Hulvey, Z., Gilmour, E., FitzGerald, S.A., Head-Gordon, M., Brown, C.M., and Long, J.R., Journal of the American Chemical Society136, 12119 (2014)
  4. Kinetic Trapping of D 2 in MIL-53(Al) Observed Using Neutron Scattering
    Pollock, R.A., Her, J.-H., Brown, C.M., Liu, Y., and Dailly, A., The Journal of Physical Chemistry C 118, 18197 (2014)
  5. Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in Metal Organic Frameworks with Exposed Divalent Metal Cations
    Bloch, E.D., Hudson, M.R., Mason, J.A., Chavan, S., Crocellà, V., Howe, J.D., Lee, K., Dzubak, A.L., Queen, W.L., Zadrozny, J.M., Geier, S.J., Lin, L.-C., Gagliardi, L., Smit, B., Neaton, J.B., Bordiga, S., Brown, C.M., and Long, J.R., Journal of the American Chemical Society 136, 10752 (2014)
  6. Solid-State 29 Si NMR and Neutron-Diffraction Studies of Sr 0.7 K 0.3 SiO 2.85 Oxide Ion Conductors
    Xu, J., Wang, X., Fu, H., Brown, C.M., Jing, X., Liao, F., Lu, F., Li, X., Kuang, X., and Wu, M., Inorganic Chemistry 53, 6962 (2014)
  7. Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
    Xiao, D.J., Bloch, E.D., Mason, J.A., Queen, W.L., Hudson, M.R., Planas, N., Borycz, J., Dzubak, A.L., Verma, P., Lee, K., Bonino, F., Crocellà, V., Yano, J., Bordiga, S., Truhlar, D.G., Gagliardi, L., Brown, C.M., and Long, J.R., Nature Chemistry 6, 590 (2014)
  8. Electronic correlations in $\mathrm{Fe}{\mathrm{Ga}}_{3}$ and the effect of hole doping on its magnetic properties
    Gamża, M.B., Tomczak, J.M., Brown, C., Puri, A., Kotliar, G., and Aronson, M.C., Physical Review B 89, 195102 (2014)
  9. Design of a Metal Organic Framework with Enhanced Back Bonding for Separation of N2 and CH4
    Lee, K., Isley, W.C., Dzubak, A.L., Verma, P., Stoneburner, S.J., Lin, L.-C., Howe, J.D., Bloch, E.D., Reed, D.A., Hudson, M.R., Brown, C.M., Long, J.R., Neaton, J.B., Smit, B., Cramer, C.J., Truhlar, D.G., and Gagliardi, L., Journal of the American Chemical Society 136, 698 (2014)
  10. Molecular Basis for the High CO 2 Adsorption Capacity of Chabazite Zeolites
    Pham, T.D., Hudson, M.R., Brown, C.M., and Lobo, R.F., ChemSusChem 7, 3031 (2014)
  11. “Correlations between structure and gas-adsorption / separation properties of metal-organic frameworks” Queen, W.L., Lee, J., Gonzalez, M.I., Grier, S.J., Mason, J.A., Long, J.R., Brown, C.M., Hudson, M.R., and Teat, S.J., Transactions of the American Crystallographic Assn. 44, 120 (2014)


  1. Chemical spectroscopy using neutrons
    Brown, C.M., Ramirez-Cuesta, A. (Timmy) J., Johnson, M.R., and García-Sakai, V., Chemical Physics 427, 1 (2013)
  2. Muon spin relaxation and electron/neutron diffraction studies of BaTi${}_{2}$(As${}_{1\ensuremath{-}x}$Sb${}_{x}$)${}_{2}$O: Absence of static magnetism and superlattice reflections
    Nozaki, Y., Nakano, K., Yajima, T., Kageyama, H., Frandsen, B., Liu, L., Cheung, S., Goko, T., Uemura, Y.J., Munsie, T.S.J., Medina, T., Luke, G.M., Munevar, J., Nishio-Hamane, D., and Brown, C.M., Physical Review B 88, 214506 (2013)
  3. Noble Gas Adsorption in Copper Trimesate HKUST-1 An Experimental and Computational Study
    Hulvey, Z., Lawler, K.V., Qiao, Z., Zhou, J., Fairen-Jimenez, D., Snurr, R.Q., Ushakov, S.V., Navrotsky, A., Brown, C.M., and Forster, P.M., The Journal of Physical Chemistry C 117, 20116 (2013)
  4. Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
    Herm, Z.R., Wiers, B.M., Mason, J.A., van Baten, J.M., Hudson, M.R., Zajdel, P., Brown, C.M., Masciocchi, N., Krishna, R., and Long, J.R., Science 340, 960 (2013)
  5. Mn(dca)2(o-phen) {dca=dicyanamide; o-phen=1,10-phenanthroline}: Long-range magnetic order in a low-dimensional Mn-dca polymer
    Manson, J.L., Brown, C.M., Huang, Q., Schlueter, J.A., Lancaster, T., Blundell, S.J., Singleton, J., Lynn, J.W., and Pratt, F.L., Polyhedron 52, 679 (2013)
  6. Evaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture
    Bae, T.-H., Hudson, M.R., Mason, J.A., Queen, W.L., Dutton, J.J., Sumida, K., Micklash, K.J., Kaye, S.S., Brown, C.M., and Long, J.R., Energy Environ. Sci. 6, 128 (2013)
  7. Structure and spectroscopy of hydrogen adsorbed in a nickel metal–organic framework
    Brown, C.M., Ramirez-Cuesta, A.J., Her, J.-H., Wheatley, P.S., and Morris, R.E., Chemical Physics 427, 3 (2013)
  8. Selective adsorption of ethylene over ethane and propylene over propane in the metal organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
    Geier, S.J., Mason, J.A., Bloch, E.D., Queen, W.L., Hudson, M.R., Brown, C.M., and Long, J.R., Chemical Science4, 2054 (2013)
  9. Surface compression of light adsorbates inside microporous PFA-derived carbons
    Qajar, A., Peer, M., Rajagopalan, R., Liu, Y., Brown, C., and Foley, H.C., Carbon 60, 538 (2013)


  1. Spectroscopic Identification of Hydrogen Spillover Species in Ruthenium-Modified High Surface Area Carbons by Diffuse Reflectance Infrared Fourier Transform Spectroscopy
    Blackburn, J.L., Engtrakul, C., Bult, J.B., Hurst, K., Zhao, Y., Xu, Q., Parilla, P.A., Simpson, L.J., Rocha, J.-D.R., Hudson, M.R., Brown, C.M., and Gennett, T., The Journal of Physical Chemistry C 116, 26744 (2012)
  2. Hydrogen diffusion in potassium intercalated graphite studied by quasielastic neutron scattering
    Purewal, J., Keith, J.B., Ahn, C.C., Brown, C.M., Tyagi, M., and Fultz, B., The Journal of Chemical Physics 137, 224704 (2012)
  3. Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
    Bloch, E.D., Queen, W.L., Krishna, R., Zadrozny, J.M., Brown, C.M., and Long, J.R., Science 335, 1606 (2012)
  4. Anharmonic phonons and magnons in BiFeO${}_{3}$
    Delaire, O., Stone, M.B., Ma, J., Huq, A., Gout, D., Brown, C., Wang, K.F., and Ren, Z.F., Physical Review B 85, 064405 (2012)
  5. Hydrogen species motion in piezoelectrics: A quasi-elastic neutron scattering study
    Alvine, K.J., Tyagi, M., Brown, C.M., Udovic, T.J., Jenkins, T., and Pitman, S.G., Journal of Applied Physics 111, 053505 (2012)
  6. Unconventional, Highly Selective CO2 Adsorption in Zeolite SSZ-13
    Hudson, M.R., Queen, W.L., Mason, J.A., Fickel, D.W., Lobo, R.F., and Brown, C.M., Journal of the American Chemical Society 134, 1970 (2012)
  7. Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns
    Liu, Y., Brown, C.M., Neumann, D.A., Geohegan, D.B., Puretzky, A.A., Rouleau, C.M., Hu, H., Styers-Barnett, D., Krasnov, P.O., and Yakobson, B.I., Carbon 50, 4953 (2012)
  8. Hydrogen adsorption in the metal organic frameworks Fe 2 (dobdc) and Fe 2 (O 2)(dobdc)
    Queen, W.L., Bloch, E.D., Brown, C.M., Hudson, M.R., Mason, J.A., Murray, L.J., Ramirez-Cuesta, A.J., Peterson, V.K., and Long, J.R., Dalton Transactions 41, 4180 (2012)


  1. Site Specific CO2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network
    Queen, W.L., Brown, C.M., Britt, D.K., Zajdel, P., Hudson, M.R., and Yaghi, O.M., The Journal of Physical Chemistry C 115, 24915 (2011)
  2. Selective Binding of O2 over N2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
    Bloch, E.D., Murray, L.J., Queen, W.L., Chavan, S., Maximoff, S.N., Bigi, J.P., Krishna, R., Peterson, V.K., Grandjean, F., Long, G.J., Smit, B., Bordiga, S., Brown, C.M., and Long, J.R., Journal of the American Chemical Society 133, 14814 (2011)
  3. Redox-Promoting Protein Motions in Rubredoxin
    Borreguero, J.M., He, J., Meilleur, F., Weiss, K.L., Brown, C.M., Myles, D.A., Herwig, K.W., and Agarwal, P.K., The Journal of Physical Chemistry B 115, 8925 (2011)
  4. Low-energy magnetic excitations in Co/CoO core/shell nanoparticles
    Feygenson, M., Teng, X., Inderhees, S.E., Yiu, Y., Du, W., Han, W., Wen, J., Xu, Z., Podlesnyak, A.A., Niedziela, J.L., Hagen, M., Qiu, Y., Brown, C.M., Zhang, L., and Aronson, M.C., Physical Review B 83, 174414 (2011)
  5. Structural Study of D 2 within the Trimodal Pore System of a Metal Organic Framework
    Peterson, V.K., Brown, C.M., Liu, Y., and Kepert, C.J., The Journal of Physical Chemistry C 115, 8851 (2011)
  6. Neutron Scattering and Spectroscopic Studies of Hydrogen Adsorption in Cr 3 (BTC) 2 —A Metal−Organic Framework with Exposed Cr 2+ Sites
    Sumida, K., Her, J.-H., Dincă, M., Murray, L.J., Schloss, J.M., Pierce, C.J., Thompson, B.A., FitzGerald, S.A., Brown, C.M., and Long, J.R., The Journal of Physical Chemistry C 115, 8414 (2011)
  7. Hydrogen storage properties and neutron scattering studies of Mg 2 (dobdc) - a metal organic framework with open Mg 2+ adsorption sites
    Sumida, K., Brown, C.M., Herm, Z.R., Chavan, S., Bordiga, S., and Long, J.R., Chem. Commun. 47, 1157 (2011)
  8. Micro-channel development and hydrogen adsorption properties in templated microporous carbons containing platinum nanoparticles
    Yang, Y., Brown, C.M., Zhao, C., Chaffee, A.L., Nick, B., Zhao, D., Webley, P.A., Schalch, J., Simmons, J.M., Liu, Y., Her, J.-H., Buckley, C.E., and Sheppard, D.A., Carbon 49, 1305 (2011)


  1. Identifying the Specific Nanostructures Responsible for the High Thermoelectric Performance of (Bi,Sb)2Te3 Nanocomposites
    Xie, W., He, J., Kang, H.J., Tang, X., Zhu, S., Laver, M., Wang, S., Copley, J.R.D., Brown, C.M., Zhang, Q., and Tritt, T.M., Nano Letters 10, 3283 (2010)
  2. Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2
    Murray, L.J., Dinca, M., Yano, J., Chavan, S., Bordiga, S., Brown, C.M., and Long, J.R., Journal of the American Chemical Society 132, 7856 (2010)
  3. Metal-Organic Frameworks with Exceptionally High Methane Uptake: Where and How is Methane Stored?
    Wu, H., Simmons, J.M., Liu, Y., Brown, C.M., Wang, X.-S., Ma, S., Peterson, V.K., Southon, P.D., Kepert, C.J., Zhou, H.-C., Yildirim, T., and Zhou, W., Chemistry - A European Journal 16, 5205 (2010)
  4. Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal–organic framework (Fe-BTT) discovered via high-throughput methods
    Sumida, K., Horike, S., Kaye, S.S., Herm, Z.R., Queen, W.L., Brown, C.M., Grandjean, F., Long, G.J., Dailly, A., and Long, J.R., Chemical Science 1, 184 (2010)


  1. Neutron scattering evidence for isolated spin-$\frac{1}{2}$ ladders in ${({\text{C}}_{5}{\text{D}}_{12}\text{N})}_{2}{\text{CuBr}}_{4}$
    Savici, A.T., Granroth, G.E., Broholm, C.L., Pajerowski, D.M., Brown, C.M., Talham, D.R., Meisel, M.W., Schmidt, K.P., Uhrig, G.S., and Nagler, S.E., Physical Review B 80, 094411 (2009)
  2. User Facilities: The Education of New Neutron Users
    Hernández, Y. and Brown, C.M., AIP Conference Proceedings 1164, 52 (2009)
  3. One-Dimensional Magnetic Fluctuations in the Spin-2 Triangular Lattice $\ensuremath{\alpha}\mathrm{\text{\ensuremath{-}}}{\mathrm{NaMnO}}_{2}$
    Stock, C., Chapon, L.C., Adamopoulos, O., Lappas, A., Giot, M., Taylor, J.W., Green, M.A., Brown, C.M., and Radaelli, P.G., Physical Review Letters 103, 077202 (2009)
  4. Role of Cation Size on the Structural Behavior of the Alkali-Metal Dodecahydro- closo -Dodecaborates
    Her, J.-H., Zhou, W., Stavila, V., Brown, C.M., and Udovic, T.J., The Journal of Physical Chemistry C 113, 11187 (2009)
  5. Hydrogen adsorption in HKUST-1: a combined inelastic neutron scattering and first-principles study
    Brown, C.M., Liu, Y., Yildirim, T., Peterson, V.K., and Kepert, C.J., Nanotechnology 20, 204025 (2009)
  6. Time-of-Flight Spectroscopy at the NIST Center for Neutron Research
    Copley, J.R.D., Brown, C.M., and Qiu, Y., Neutron News 20, 28 (2009)
  7. Detection of Hydrogen Spillover in Palladium-Modified Activated Carbon Fibers during Hydrogen Adsorption
    Contescu, C.I., Brown, C.M., Liu, Y., Bhat, V.V., and Gallego, N.C., The Journal of Physical Chemistry C 113, 5886 (2009)
  8. Adsorption and melting of hydrogen in potassium-intercalated graphite
    Purewal, J.J., Keith, J.B., Ahn, C.C., Fultz, B., Brown, C.M., and Tyagi, M., Physical Review B 79, (2009)
  9. High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites
    Lin, X., Telepeni, I., Blake, A.J., Dailly, A., Brown, C.M., Simmons, J.M., Zoppi, M., Walker, G.S., Thomas, K.M., Mays, T.J., Hubberstey, P., Champness, N.R., and Schröder, M., Journal of the American Chemical Society 131, 2159 (2009)
  10. DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data
    Azuah, R.T., Kneller, L.R., Qiu, Y., Tregenna-Piggott, P.L.W., Brown, C.M., Copley, J.R.D., and Dimeo, R.M., Journal of Research of the National Institute of Standards and Technology 114, 341 (2009)


  1. Inelastic neutron scattering from confined molecular oxygen
    Kilburn, D., Sokol, P.E., and Brown, C.M., Physical Review B 78, (2008)
  2. Crystalline Electric Field as a Probe for Long-Range Antiferromagnetic Order and Superconducting State of ${\mathrm{CeFeAsO}}_{1\ensuremath{-}x}{\mathrm{F}}_{x}$
    Chi, S., Adroja, D.T., Guidi, T., Bewley, R., Li, S., Zhao, J., Lynn, J.W., Brown, C.M., Qiu, Y., Chen, G.F., Lou, J.L., Wang, N.L., and Dai, P., Physical Review Letters 101, 217002 (2008)
  3. “Neutron Powder Diffraction of Metal Organic Frameworks for Hydrogen Storage” Brown, C.M., Liu, Y., and Neumann, D.A., PRAMANA J. Physics 71, 755 (2008)
  4. Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis
    Liu, Y., Her, J.-H., Dailly, A., Ramirez-Cuesta, A.J., Neumann, D.A., and Brown, C.M., Journal of the American Chemical Society 130, 11813 (2008)
  5. The design of a bismuth-based auxiliary filter for the removal of spurious background scattering associated with filter-analyzer neutron spectrometers
    Udovic, T.J., Brown, C.M., Leão, J.B., Brand, P.C., Jiggetts, R.D., Zeitoun, R., Pierce, T.A., Peral, I., Copley, J.R.D., Huang, Q., Neumann, D.A., and Fields, R.J., Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 588, 406 (2008)
  6. Quasielastic neutron scattering of –NH3 and –BH3 rotational dynamics in orthorhombic ammonia borane
    Hess, N.J., Hartman, M.R., Brown, C.M., Mamontov, E., Karkamkar, A., Heldebrant, D.J., Daemen, L.L., and Autrey, T., Chemical Physics Letters 459, 85 (2008)
  7. Increasing the Density of Adsorbed Hydrogen with Coordinatively Unsaturated Metal Centers in Metal−Organic Frameworks
    Liu, Y., Kabbour, H., Brown, C.M., Neumann, D.A., and Ahn, C.C., Langmuir 24, 4772 (2008)
  8. Hydrogen Adsorption in a Highly Stable Porous Rare-Earth Metal-Organic Framework: Sorption Properties and Neutron Diffraction Studies
    Luo, J., Xu, H., Liu, Y., Zhao, Y., Daemen, L.L., Brown, C., Timofeeva, T.V., Ma, S., and Zhou, H.-C., Journal of the American Chemical Society 130, 9626 (2008)


  1. Inelastic neutron scattering study of hydrogen in d8-THF∕D2O ice clathrate
    Tait, K.T., Trouw, F., Zhao, Y., Brown, C.M., and Downs, R.T., The Journal of Chemical Physics 127, 134505 (2007)
  2. Studies of intrinsic exchange interactions in Zn(Mn)O, Zn(Mn)S and Zn(Mn)Te at 4 kbar by inelastic neutron scattering
    Wiren, Z.Q., Kepa, H., Brown, C.M., Leao, J., Kolesnik, S., Dabrowski, B., Furdyna, J.K., and Giebultowicz, T.M., AIP Conference Proceedings 893, 1197 (2007)
  3. Dynamics and Structure of Hydration Water on Rutile and Cassiterite Nanopowders Studied by Quasielastic Neutron Scattering and Molecular Dynamics Simulations
    Mamontov, E., Vlcek, L., Wesolowski, D.J., Cummings, P.T., Wang, W., Anovitz, L.M., Rosenqvist, J., Brown, C.M., and Garcia Sakai, V., The Journal of Physical Chemistry C 111, 4328 (2007)
  4. Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite-Type Metal–Organic Framework
    Dincă, M., Han, W.S., Liu, Y., Dailly, A., Brown, C.M., and Long, J.R., Angewandte Chemie International Edition46, 1419 (2007)
  5. “Applications of Neutron Scattering Techniques to Hydrogen Storage Materials” Liu, Y., Brown, C.M., Baumann, T.F., and Neumann, D.A., Trans. Amer. Nucl. Soc. 97, 319 (2007)
  6. Inelastic neutron scattering of H2 adsorbed on boron substituted single walled carbon nanotubes
    Liu, Y., Brown, C.M., Blackburn, J.L., Neumann, D.A., Gennett, T., Simpson, L., Parilla, P., Dillon, A.C., and Heben, M.J., Journal of Alloys and Compounds 446–447, 368 (2007)
  7. Hydrogen Adsorption in MOF-74 Studied by Inelastic Neutron Scattering
    Liu, Y., Brown, C.M., Neumann, D.A., Kabbour, H., and Ahn, C.C., MRS Online Proceedings Library Archive1041, (2007)
  8. Inelastic neutron scattering of H 2 adsorbed in HKUST-1
    Liu, Y., Brown, C.M., Neumann, D.A., Peterson, V.K., and Kepert, C.J., Journal of Alloys and Compounds 446–447, 385 (2007)
  9. Neutron vibrational spectroscopy of the Pr2Fe17-based hydrides
    Udovic, T.J., Zhou, W., Wu, H., Brown, C.M., Rush, J.J., Yildirim, T., Mamontov, E., and Isnard, O., Journal of Alloys and Compounds 446–447, 504 (2007)


  1. Inelastic neutron scattering from antiferromagnetically coupled nearest-neighbor spin pairs in Zn(Mn)O and Zn(Mn)Te
    Kępa, H., Kolesnik, S., Wiren, Z., Leao, J., Brown, C.M., Dabrowski, B., Furdyna, J.K., and Giebultowicz, T.M., Physica B: Condensed Matter 385–386, 388 (2006)
  2. Quasielastic and inelastic neutron scattering study of the hydration of monoclinic and triclinic tricalcium silicate
    Peterson, V.K., Brown, C.M., and Livingston, R.A., Chemical Physics 326, 381 (2006)
  3. Determination of antiferromagnetic interactions in Zn(Mn)O, Zn(Co)O, and Zn(Mn)Te by inelastic neutron scattering
    Kolesnik, S., Dabrowski, B., Wiren, Z.Q., Kepa, H., Giebultowicz, T.M., Brown, C.M., Lëao, J., and Furdyna, J.K., Journal of Applied Physics 99, 08M122 (2006)
  4. Static and dynamic Jahn-Teller effect in the alkali metal fulleride salts A 4 C 60 ( A = K , Rb , Cs )
    Klupp, G., Kamarás, K., Nemes, N.M., Brown, C.M., and Leão, J., Physical Review B 73, (2006)
  5. Dynamics of ammonia borane using neutron scattering
    Brown, C.M., Jacques, T.L., Hess, N.J., Daemen, L.L., Mamontov, E., Linehan, J.C., Stowe, A.C., and Autrey, T., Physica B: Condensed Matter 385–386, 266 (2006)
  6. Hydrogen Storage in a Microporous Metal Organic Framework with Exposed Mn2+  Coordination Sites
    Dinca, M., Dailly, A., Liu, Y., Brown, C.M., Neumann, D.A., and Long, J.R., Journal of the American Chemical Society 128, 16876 (2006)
  7. Neutron Powder Diffraction Study of D2 Sorption in Cu3(1,3,5-benzenetricarboxylate)2
    Peterson, V.K., Liu, Y., Brown, C.M., and Kepert, C.J., Journal of the American Chemical Society 128, 15578 (2006)


  1. Investigation of the State of Water in Hydrating Layered Sodium Disilicate in Crystalline and Amorphous Forms by Quasi-Elastic Neutron Scattering
    Phair, J.W., Livingston, R.A., Brown, C.M., and Benesi, A.J., Chemistry of Materials 16, 5042 (2004)
  2. Distortion and orientation of fulleride ions in A4C60
    Klupp, G., Kamarás, K., Nemes, N.M., Brown, C.M., and Leao, J., AIP Conference Proceedings 723, 8 (2004)
  3. The Crystalline Enol of 1,3-Cyclohexanedione and Its Complex with Benzene:  Vibrational Spectra, Simulation of Structure and Dynamics and Evidence for Cooperative Hydrogen Bonding
    Hudson, B.S., Braden, D.A., Allis, D.G., Jenkins, T., Baronov, S., Middleton, C., Withnall, R., and Brown, C.M., The Journal of Physical Chemistry A 108, 7356 (2004)
  4. Determination of hole-induced ferromagnetic Mn–Mn exchange in p-type Zn1−xMnxTe by inelastic neutron scattering
    Kępa, H., Van Khoi, L., Brown, C.M., Dietl, T., Furdyna, J.K., and Giebultowicz, T.M., Physica B: Condensed Matter 350, 36 (2004)
  5. Determination of hole-induced ferromagnetic exchange between nearest-neighbor Mn spins in p-type Zn1−xMnxTe
    Kępa, H., Khoi, L.V., Brown, C.M., Dietl, T., Furdyna, J.K., and Giebultowicz, T.M., Journal of Magnetism and Magnetic Materials 272–276, E1545 (2004)
  6. Origin and removal of spurious background peaks in vibrational spectra measured by filter-analyzer neutron spectrometers
    Udovic, T.J., Neumann, D.A., Leão, J., and Brown, C.M., Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 517, 189 (2004)


  1. Structure and dynamics of superconducting ${\mathrm{Na}}_{x}{\mathrm{CoO}}_{2}$ hydrate and its unhydrated analog
    Lynn, J.W., Huang, Q., Brown, C.M., Miller, V.L., Foo, M.L., Schaak, R.E., Jones, C.Y., Mackey, E.A., and Cava, R.J., Physical Review B 68, 214516 (2003)
  2. Dynamics of supercooled water in mesoporous silica matrix MCM-48-S
    Faraone, A., Liu, L., Mou, C.-Y., Shih, P.-C., Brown, C., Copley, J.R.D., Dimeo, R.M., and Chen, S.-H., The European Physical Journal E 12, 59 (2003)
  3. Probing Hole-Induced Ferromagnetic Exchange in Magnetic Semiconductors by Inelastic Neutron Scattering
    Kępa, H., Le, V.K., Brown, C.M., Sawicki, M., Furdyna, J.K., Giebultowicz, T.M., and Dietl, T., Physical Review Letters 91, 087205 (2003)
  4. Terahertz spectroscopy of short-chain polypeptides
    Kutteruf, M.R., Brown, C.M., Iwaki, L.K., Campbell, M.B., Korter, T.M., and Heilweil, E.J., Chemical Physics Letters 375, 337 (2003)
  5. Comparison of Boson Peaks in Polypropylenes
    Annis, B.K., Kim, M.-H., and Brown, C., Macromolecules 36, 520 (2003)


  1. Probing Vibrational Dynamics of Hydrogen-Bonded Inclusion Compounds with Inelastic Neutron Scattering and Ab Initio Calculations
    Pivovar, A.M., Ward, M.D., Brown, C.M., and Neumann, D.A., The Journal of Physical Chemistry B 106, 4916 (2002)
  2. Rotational dynamics of hydration water in dicalcium silicate by quasielastic neutron scattering
    Faraone, A., Chen, S.-H., Fratini, E., Baglioni, P., Liu, L., and Brown, C., Physical Review E 65, 040501 (2002)
  3. Solid-State Ligand Dynamics in Interpenetrating Mn[N(CN) 2 ] 2 (Pyrazine): A Neutron Spectroscopy Study
    Brown, C.M. and Manson, J.L., Journal of the American Chemical Society 124, 12600 (2002)


  1. Incoherent Quasi-elastic Neutron Scattering from Fructose−Water Solutions
    Feeney, M., Brown, C., Tsai, A., Neumann, D., and Debenedetti, P.G., The Journal of Physical Chemistry B 105, 7799 (2001)
  2. Giant Anharmonicity and Nonlinear Electron-Phonon Coupling in ${\mathrm{MgB}}_{2}$: A Combined First-Principles Calculation and Neutron Scattering Study
    Yildirim, T., Gülseren, O., Lynn, J.W., Brown, C.M., Udovic, T.J., Huang, Q., Rogado, N., Regan, K.A., Hayward, M.A., Slusky, J.S., He, T., Haas, M.K., Khalifah, P., Inumaru, K., and Cava, R.J., Physical Review Letters 87, 037001 (2001)
  3. Large Harmonic Softening of the Phonon Density of States of Uranium
    Manley, M.E., Fultz, B., McQueeney, R.J., Brown, C.M., Hults, W.L., Smith, J.L., Thoma, D.J., Osborn, R., and Robertson, J.L., Physical Review Letters 86, 3076 (2001)
  4. Muon-spin-rotation and magnetization study of metal-organic magnets based on the dicyanamide anion
    Jestädt, T., Kurmoo, M., Blundell, S.J., Pratt, F.L., Kepert, C.J., Prassides, K., Lovett, B.W., Marshall, I.M., A Husmann, Chow, K.H., Valladares, R.M., Brown, C.M., and Lappas, A., Journal of Physics: Condensed Matter 13, 2263 (2001)


  1. A view of dynamics changes in the molten globule-native folding step by quasielastic neutron scattering
    Bu, Z., Neumann, D.A., Lee, S.-H., Brown, C.M., Engelman, D.M., and Han, C.C., Journal of Molecular Biology301, 525 (2000)
  2. Quantum rotation of hydrogen in single-wall carbon nanotubes
    Brown, C.M., Yildirim, T., Neumann, D.A., Heben, M.J., Gennett, T., Dillon, A.C., Alleman, J.L., and Fischer, J.E., Chemical Physics Letters 329, 311 (2000)
  3. Anomalous High Pressure Properties in Fullerene Superconductors
    Obu, T.T., Shimoda, H., Iwasa, Y., Mitani, T., Kosaka, M., Tanigaki, K.U., Brown, C.M., and Prassides, K., Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals340, 599 (2000)
  4. Powder diffraction and inelastic neutron scattering studies of the Na2RbC60 fulleride
    Prassides, K., Brown, C.M., Margadonna, S., Kordatos, K., Tanigaki, K., Suard, E., Dianoux, A.J., and Knudsen, K.D., Journal of Materials Chemistry 10, 1443 (2000)


  1. Rotational tunneling of ammonia in (NH3)K3C60
    Margadonna, S., Prassides, K., Brown, C.M., Shimoda, H., Iwasa, Y., and Casalta, H., The Journal of Chemical Physics 111, 10969 (1999)
  2. Structural and Electronic Properties of the Noncubic Superconducting Fullerides A 4 ′ C 60 ( A ′ = Ba , Sr )
    Brown, C.M., Taga, S., Gogia, B., Kordatos, K., Margadonna, S., Prassides, K., Iwasa, Y., Tanigaki, K., Fitch, A.N., and Pattison, P., Physical Review Letters 83, 2258 (1999)
  3. Superconductivity in Li x CsC 60 fullerides
    Kosaka, M., Tanigaki, K., Prassides, K., Margadonna, S., Lappas, A., Brown, C.M., and Fitch, A.N., Physical Review B 59, R6628 (1999)
  4. Pressure dependence of superconductivity in the Na 2 Rb 0.5 Cs 0.5 C 60 fulleride
    Brown, C.M., Takenobu, T., Kordatos, K., Prassides, K., Iwasa, Y., and Tanigaki, K., Physical Review B 59, 4439 (1999)
  5. Neutron diffraction study of the polymeric structure of Na2RbC60
    Lappas, A., Brown, C.M., Kordatos, K., Suard, E., Tanigaki, K., and Prassides, K., Journal of Physics: Condensed Matter 11, 371 (1999)
  6. Current Issues of Intercalation and Superconductivity in Solid State Fullerenes
    Iwasa, Y., Shimoda, H., Takenobu, T., Honjo, S., Mitani, T., Tou, H., Maniwa, Y., Brown, C.M., and Prassides, K., Fullerene Science and Technology 7, 587 (1999)
  7. Band filling and width control in fullerides
    Iwasa, Y., Taga, S., Takenobu, T., Shimoda, H., Mitani, T., Prassides, K., and Brown, C.M., Synthetic Metals 103, 2462 (1999)
  8. Pressure and Temperature Evolution of the Structure of the Superconducting Na2CsC60 Fulleride
    Margadonna, S., Brown, C.M., Lappas, A., Prassides, K., Tanigaki, K., Knudsen, K.D., Le Bihan, T., and Mézouar, M., Journal of Solid State Chemistry 145, 471 (1999)
  9. Temperature and pressure dependence of orientational disorder and bonding in Li2CsC60
    Margadonna, S., Brown, C.M., Prassides, K., Fitch, A.N., Knudsen, K.D., Bihan, T.L., Mézouar, M., Hirosawa, I., and Tanigaki, K., International Journal of Inorganic Materials 1, 157 (1999)


  1. Crystal Structure of the Higher Fullerene C 84
    Margadonna, S., Brown, C.M., Dennis, T.J.S., Lappas, A., Pattison, P., Prassides, K., and Shinohara, H., Chemistry of Materials 10, 1742 (1998)
  2. Fulleride polymerisation at ambient and elevated pressure
    Margadonna, S., Brown, C.M., Lappas, A., Kordatos, K., Tanigaki, K., and Prassides, K., in AIP Conf. Proc. (AIP, 1998), pp. 327–330


  1. Effects of Pressure on the Azafullerene (C 59 N) 2 Molecular Solid to 22 GPa
    Brown, C.M., Beer, E., Bellavia, C., Cristofolini, L., González, R., Hanfland, M., Häusermann, D., Keshavarz-K, M., Kordatos, K., Prassides, K., and Wudl, F., Journal of the American Chemical Society 118, 8715 (1996)
  2. On the Crystal Structure of Azafullerene (C 59 N) 2
    Brown, C.M., Cristofolini, L., Kordatos, K., Prassides, K., Bellavia, C., González, R., Keshavarz-K., M., Wudl, F., Cheetham, A.K., Zhang, J.P., Andreoni, W., Curioni, A., Fitch, A.N., and Pattison, P., Chemistry of Materials 8, 2548 (1996)
  3. Interfullerene vibrations in the polymeric fulleride CsC60
    Cristofolini, L., Brown, C.M., Dianoux, A.J., Kosaka, M., Prassides, K., Tanigaki, K., and Vavekis, K., Chemical Communications 2465 (1996)




Polyoxocationic Antimony Oxide Cluster with Acidic Protons

Yuki Watanabe, Kim Hyeon-Deuk, Takafumi Yamamoto, Masayoshi Yabuuchi, Olesia M. Karakulina, Yasuto Noda, Takuya Kurihara, I-Ya Chang, Masanobu Higashi, Osamu Tomita, Cedric Tassel, Daichi Kato, Jingxin Xia, Tatsuhiko Goto, Craig Brown, Yuto Shimoyama, Naoki Ogiwara, Joke Hadermann, Artem M. Abakumov, Sayaka Uchida, Ryu Abe, Hiroshi Kageyama
The success and continued expansion of research in polyoxometalates (POMs) owe largely to their structural richness and wide range of functions. However, while

Magnetic-Field-Induced Dielectric Anomalies in Cobalt-Containing Garnets

Abbey J. Neer, Joanna Milam-Guerrero, Veronika A. Fischer, Michelle Zheng, Nicole R. Spence, Clayton Cozzan, Mingqiang Gu, James M. Rondinelli, Craig Brown, Brent C. Melot
We present a comparative study of the magnetic and crystal chemical proper-ties of two Co2+ containing garnets.CaY2Co2Ge3O12 and NaCa2Co2V3O12 both exhibit the

Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor

Elias Sebti, Hayden Evans, Hengning Chen, Peter Richardson, Kelly White, Raynald Giovine, Krishna P. Koirala, Yaobin Xu, Eliovardo Gonzalez-Correa, Chongmin Wang, Craig Brown, Anthony Cheetham, Pieremanuele Canepa, Raphaele Clement
In the pursuit of urgently-needed, energy dense solid-state batteries for electric vehicle and portable electronics applications, halide solid electrolytes
Created July 30, 2019, Updated February 2, 2023