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Search Publications by: Andrea Centrone (Fed)

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Displaying 1 - 25 of 48

Mid-Infrared, Near-Infrared, and Visible Nanospectroscopy of Hydrogen-Intercalated MoO3

August 21, 2023
Author(s)
Jeffrey Schwartz, Sergiy Krylyuk, Devon Jakob, Albert Davydov, Andrea Centrone
Control over the local chemical composition and spatial heterogeneities in nanomaterials provides a means to impart new functions and to tailor their properties in many applications. For two-dimensional (2D) van der Waals materials, intercalation is one

Evaluating the thermal performance of perovskite SrSnO3 field effect transistors

July 13, 2023
Author(s)
Bivek Bista, Prafful Golani, Fengdeng Liu, Tristan Truttmann, Georges Pavlidis, Andrea Centrone, Bharat Jalan, Steven Koester
Given the ever increasing, global electricity consumption, improving the efficiency and reliability of high-power electronics is of paramount importance. Ultra-wide band gap (> 3.4 eV) semiconductors have shown the potential to be used in the next

Direct Visualization of Chemically Resolved Multilayered Domains in Mixed-Linker Metal-Organic Frameworks

June 15, 2023
Author(s)
Andrea Centrone, Belen Lerma-Berlanga, Adam Biacchi, Carmen Fernandez Conde, Georges Pavlidis, Carlos Marti-Gastaldo
The modular synthesis approach for assembling inorganic nodes and organic multidentate linkers into reticular solids enables rational engineering in porous materials known as metal-organic frameworks (MOFs). Incorporation of two or more linker types in MOF

Thermal environment impact on HfOx RRAM operation: A nanoscale thermometry and modeling study

May 8, 2023
Author(s)
Matthew West, Georges Pavlidis, Robert Montgomery, Fabia Farlin Athena, Muhammad Jamil, Andrea Centrone, Samuel Graham, Eric Vogel
As the demand for computing applications capable of processing large datasets increases, there is a growing need for new in-memory computing technologies that avoid the von Neumann bottleneck. Oxide-based resistive random-access memory (RRAM) devices are a

Beating thermal noise in a dynamic signal measurement by a nanofabricated cavity-optomechanical sensor

March 15, 2023
Author(s)
Mingkang Wang, Diego Perez Morelo, Georg Ramer, Georges Pavlidis, Jeffrey Schwartz, Liya Yu, Robert Ilic, Andrea Centrone, Vladimir Aksyuk
Thermal fluctuations often impose both fundamental and practical measurement limits on high-performance sensors, motivating the development of techniques that bypass the limitations imposed by thermal noise outside cryogenic environments. Here, we

High throughput nanoimaging of thermal conductivity and interfacial thermal conductance

May 17, 2022
Author(s)
Mingkang Wang, Georg Ramer, Diego Perez, Georges Pavlidis, Jeffrey Schwartz, Liya Yu, Robert Ilic, Vladimir Aksyuk, Andrea Centrone
Thermal properties of materials are often determined by measuring thermalization processes. Measuring such properties at the nanoscale, however, requires high sensitivity, high temporal, and high spatial resolutions concurrently, which is beyond the

Micro to nano: multiscale IR analyses reveal zinc soap heterogeneity in a 19th-century painting by Corot

February 9, 2022
Author(s)
Xiao Ma, Georges Pavlidis, Eoghan Dillon, Victoria Beltran, Jeffrey Schwartz, Mathieu Thoury, Ferenc Borondics, Christophe Sandt, Kevin Kjoller, Barbara Berrie, Andrea Centrone
The formation and aggregation of metal carboxylates (metal-soaps) can degrade the appearance and integrity of oil paints and frequently poses a challenge to the conservation of painted works of art. Efforts to understand the root cause of metal-soap

Experimental confirmation of long hyperbolic polariton lifetimes in monoisotopic (10B) hexagonal boron nitride at room temperature

September 14, 2021
Author(s)
Georges Pavlidis, Jeffrey Schwartz, Joseph Matson, Thomas Folland, Song Liu, James Edgar, Joshua Caldwell, Andrea Centrone
Hyperbolic phonon polaritons (HPhPs) enable arbitrarily high confinements, low losses, and directional propagation – providing opportunities from hyperlensing to flat optics, and other advanced nanophotonics applications. In this work, two near-field

Substrate-mediated hyperbolic phonon polaritons in MoO3

February 15, 2021
Author(s)
Jeffrey Schwartz, Son T. Le, Sergiy Krylyuk, Curt A. Richter, Albert Davydov, Andrea Centrone
Hyperbolic phonon polaritons (HPhPs) are hybrid excitations of light and coherent charge oscillations that exist in strongly optically anisotropic, two-dimensional materials (e.g., MoO3). These polaritons propagate through the material's volume with long

The joint automated repository for various integrated simulations (JARVIS) for data-driven materials design

November 12, 2020
Author(s)
Kamal Choudhary, Kevin Garrity, Andrew C. Reid, Brian DeCost, Adam Biacchi, Angela R. Hight Walker, Zachary Trautt, Jason Hattrick-Simpers, Aaron Kusne, Andrea Centrone, Albert Davydov, Francesca Tavazza, Jie Jiang, Ruth Pachter, Gowoon Cheon, Evan Reed, Ankit Agrawal, Xiaofeng Qian, Vinit Sharma, Houlong Zhuang, Sergei Kalinin, Ghanshyam Pilania, Pinar Acar, Subhasish Mandal, David Vanderbilt, Karin Rabe
The Joint Automated Repository for Various Integrated Simulations (JARVIS) is an integrated infrastructure to accelerate materials discovery and design using density functional theory (DFT), classical force-fields (FF), and machine learning (ML) techniques

Infrared and Raman chemical imaging and spectroscopy at the nanoscale

May 19, 2020
Author(s)
Dmitry Kurouski, Alexandre Dazzi, Renato Zenobi, Andrea Centrone
The advent of nanotechnology, and the need to understand the chemical composition at the nanoscale, has stimulated the convergence of IR and Raman spectroscopy with scanning probe methods, resulting in new nanospectroscopy paradigms. Here we review two of

High-Q dark hyperbolic phonon-polaritons in hexagonal boron nitride nanostructures

May 18, 2020
Author(s)
Georg Ramer, Mohit Tuteja, Joseph R. Matson, Marcelo I. Davanco, Thomas G. Folland, Andrey Kretinin, Takashi Taniguchi, Kenji Watanabe, Kostya Novoselov, Joshua D. Caldwell, Andrea Centrone
The anisotropy of hexagonal boron nitride (hBN) crystals gives rise to hyperbolic phonon polaritons (HPhPs), notable for their volumetric frequency-dependent angular propagation and strong confinement. For frustum (truncated nanocone) structures, theory

Chemical Identification of Interlayer Contaminants within van der Waals Heterostructures

June 24, 2019
Author(s)
Jeffrey Schwartz, ?Hsun-Jen Chuang, Matthew R. Rosenberger, Saujan V. Sivaram, Kathleen M. McCreary, B.T. Jonker, Andrea Centrone
Van der Waals heterostructures (vdWHs) leverage the characteristics of two-dimensional (2D) material building blocks to create a myriad of structures with unique and desirable properties. Several commonly employed fabrication strategies rely on polymeric

Revealing the distribution of metal carboxylates in oil paint from the micro- to the nanoscale

June 21, 2019
Author(s)
Xiao Ma, Victoria Beltran, Georg Ramer, Georges Pavlidis, dilworth parkinson, Mathieu Thoury, Tyler Meldrum, Andrea Centrone, Barbara H. Berrie
Oil paints comprise pigments, drying oils, and additives that together confer desirable properties, but can react forming metal carboxylates (soaps) that, over time, may damage artworks. Despite substantial research to understand these phenomena, soap

Spontaneous current constriction in threshold switching devices

April 9, 2019
Author(s)
Jonathan Goodwill, Georg Ramer, Dasheng Li, Brian Hoskins, Georges Pavlidis, Jabez J. McClelland, Andrea Centrone, James A. Bain, Marek Skowronski
Threshold switching devices exhibit extremely non-linear current-voltage characteristics, which are of increasing importance for a number of applications including solid-state memories and neuromorphic circuits. It has been proposed that such non-linear

Nanoscale partitioning of Paclitaxel in Hybrid Lipid-Polymer Membranes

August 6, 2018
Author(s)
Mohit Tuteja, Minjee Kang, Cecilia Leal, Andrea Centrone
Paclitaxel is a powerful drug against restenosis and many forms of cancer. However, its clinical application hinges on the ability to achieve suitable stabilized drug concentrations in an aqueous suspension while hindering drug crystallization. To engineer

Determination of polypeptide conformation in water with nanoscale resolution in water

July 24, 2018
Author(s)
Georg Ramer, Francesco Ruggeri, Aviad Levin, Toumas Knowles, Andrea Centrone
The conformational structure and folding of proteins are central to many biological processes. However, misfolding of proteins and peptides can lead to toxic aggregates that are involved in Alzheimer’s and other neurodegenerative disorders. Methods to

Nanoscale mapping and spectroscopy of non-radiative hyperbolic modes in hexagonal boron nitride nanostructures

March 14, 2018
Author(s)
Lisa Brown, Marcelo I. Davanco, Zhiyuan Sun, Andrey Kretinin, Yiguo Chen, Joseph R. Matson, Igor Vurgaftman, Nicholas Sharac, Alexander Giles, Michael Fogler, Takashi Taniguchi, Kenji Watanabe, Kostya Novoselov, Stefan Maier, Andrea Centrone, Joshua D. Caldwell
Because of its inherent crystal anisotropy, hexagonal boron nitride (hBN) supports naturally hyperbolic phonon polaritons, i.e. polaritons that can propagate with arbitrarily large wavevectors within the material volume, thereby enabling optical

Nanostructured lipid-based films for substrate-mediated applications in biotechnology

January 10, 2018
Author(s)
Minjee Kang, Mohit Tuteja, Andrea Centrone, Daniel Topgaard, Cecilia Leal
Amphiphilic in nature, lipids spontaneously self-assemble into a range of nanostructures in the presence of water. Among lipid self-assembled structures, liposomes and supported lipid bilayers have long held scientific interest for their main applications