Understanding Cantilever Transduction Efficiency and Spatial Resolution in Nanoscale Infrared Microscopy
Jeffrey Schwartz, Georges Pavlidis, Andrea Centrone
Photothermal induced resonance (PTIR), also known as AFM IR, enables nanoscale infrared (IR) imaging and spectroscopy by using the tip of an atomic force microscope to transduce the local photothermal expansion and contraction of a sample. The signal transduction efficiency and spatial resolution of PTIR depend on a multitude of sample, cantilever, and illumination source parameters in ways that are not yet well understood. Here, we elucidate and separate the effects of laser pulse length, pulse shape, sample thermalization time (τ), interfacial thermal conductance, and cantilever detection frequency by devising analytical and numerical models that link a sample's photothermal excitations to the cantilever dynamics over a broad bandwidth (10 MHz). The models indicate that shorter laser pulses excite probe oscillations over broader bandwidths and should be preferred for measuring samples with shorter thermalization times. Furthermore, we show that the spatial resolution critically depends on the interfacial thermal conductance at the interface between dissimilar materials and improves monotonically, but not linearly, with increasing cantilever detection frequencies. The resolution can be enhanced for samples that do not fully thermalize between pulses (i.e., laser repetition rates ≳1⁄3τ) as the probed depth becomes smaller than the film thickness. We believe that the insights presented here will accelerate the adoption and impact of PTIR analyses across a wide range of applications by informing experimental designs and measurement strategies as well as by guiding future technical advances.
, Pavlidis, G.
and Centrone, A.
Understanding Cantilever Transduction Efficiency and Spatial Resolution in Nanoscale Infrared Microscopy, Analytical Chemistry, [online], https://doi.org/10.1021/acs.analchem.2c02612, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=934978
(Accessed November 29, 2023)