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Displaying 576 - 600 of 913

Frequency-agile, rapid scanning spectroscopy

April 28, 2013
Author(s)
Gar W. Truong, Kevin O. Douglass, Stephen E. Maxwell, Roger D. van Zee, David F. Plusquellic, Joseph T. Hodges, David A. Long
Challenging applications in trace gas analyses require high precision and acquisition rates.1-4 Many continuous-wave laser spectroscopy techniques exhibit significant sensitivity and potential;5 however, their scanning rates are slow because they rely upon

Evaluation of Pacific White Shrimp (Litopenaeus vannamei) Health During a Superintensive Aquaculture Growout using NMR-based Metabolomics

March 27, 2013
Author(s)
Tracey B. Schock, Dan Bearden, Jessica Duke, Abby Goodson, Daryl Weldon, Jeff Brunson, John Leffler
Success of the shrimp aquaculture industry requires technological advances that increase production and environmental sustainability. Indoor, superintensive, aquaculture systems have been developed that permit year-round production of farmed shrimp at high

Detection of E-cyanomethanimine (HCN-dimer) towards Sagittarius B2(N) from the GBT PRIMOS Survey

March 20, 2013
Author(s)
Francis J. Lovas, Daniel P. Zaleski, Nathan A. Seifert, Amanda L. Steber, Matt T. Muckle, Ryan A. Loomis, Joanna F. Corby, Oscar Martinez, Kyle Crabtree, Phillip R. Jewell, Jan M. Hollis, David Vasquez, Jolie Nyiramahirwe, Nicole Sciortino, Kennedy Johnson, Michael C. McCarthy, Anthony J. Remijan, Brooks H. Pate
An understanding of the formation, distribution and overall excitation of large molecules in astronomical environments remains in question even though more than 170 distinct chemical compounds have been detected in astronomical environments. Furthermore, a

Light polarization and quantum interference effects in unresolvable atomic lines: application to a precise measurement of the 6,7Li D2 lines.

March 7, 2013
Author(s)
Roger C. Brown, Saijun Wu, James V. Porto, Craig J. Sansonetti, Clayton Simien, Samuel M. Brewer, Joseph N. Tan, John D. Gillaspy
We characterize the effect of quantum interference of light scattering on the line shapes and measured line positions in atomic spectra. These effects occur when the excited state splittings are of order the excited state line widths, and represent an

The Detection of Interstellar Ethanimine (CH3CHNH) from Observations taken during the GBT PRIMOS Survey

February 13, 2013
Author(s)
Francis J. Lovas, Ryan A. Loomis, Daniel P. Zaleski, Amanda L. Steber, Justin L. Neill, Matthew T. Muckle, Brent J. Harris, Jan M. Hollis, Phillip R. Jewell, Valerio Lattanzi, Oscar Martines, Michael C. McCarthy, Anthony J. Remijan, Brooks H. Pate
As the availab¬¬ility of publicly accessible spectral line surveys from radio astronomy increases, new approaches to the identification of molecules in the interstellar medium are possible. We have performed reaction product screening measurements using

Development of a New, Precise Near-infrared Doppler Wavelength Reference: A Fiber Fabry-Perot Interferometer

January 31, 2013
Author(s)
Samuel Halverson, Suvrath Mahadevan, Lawrence W. Ramsey, Stephen L. Redman, Gillian Nave, John C. Wilson , Fred Hearty, Jon Holtzman
We present the ongoing development of a commercially available Micron Optics ber-Fabry Perot Interferometer as a precise, stable, easy to use, and economic spectrograph reference with the goal of achieving 1 m s..1 long term stability. Fiber Fabry-Perot

Metallofullerene with a Distorted Shape: Structural Investigation of Y3N@C78

January 24, 2013
Author(s)
Dan Bearden, Jianyuan Zhang, Fuhrer Tim, Wujun Fu, Tianming Zuo, Liaosa Xu, Harry C. Dorn
In recent decades, the trimetallic nitride template endohedral metallofullerenes (TNT-EMFs),1 which consist of a trimetallic nitride cluster and a fullerene cage, have attracted extensive research interest due to their unique structural characteristics and

To Predict Vibrational Spectra, Are Anharmonic Calculations Worthwhile?

January 22, 2013
Author(s)
Ruth L. Jacobsen, Karl K. Irikura, Russell D. Johnson III, Raghu N. Kacker
Anharmonic calculations using vibrational perturbation theory are known to provide near-spectroscopic accuracy when combined with high-level ab initio potential energy functions. However, performance with economical, popular electronic structure methods is

Further Studies with Isolated Absolute Infrared Spectra of Bacteriorhodopsin Photocycle Intermediates: Conformational Changes and Possible Role of a New Proton-Binding Center

January 1, 2013
Author(s)
Richard W. Hendler, Curtis W. Meuse, Paul Smith, John W. Kakareka
We recently published procedures describing the isolation of absolute infrared spectra for the intermediates of the bacteriorhodopsin (BR) photocycle and from these, obtaining transitional difference spectra between consecutive intermediates. In that work

Single bead detection with a NMR micro capillary probe

December 6, 2012
Author(s)
Yoshihiro Nakashima, Michael A. Boss, Stephen E. Russek, John M. Moreland
We have developed a nuclear magnetic resonance (NMR) microcapillary probe for the detection of single magnetic microbeads. The geometry of the probe has been optimized so that the signal from the background water has a similar magnitude compared to the

Broad-band frequency references in the near-infrared: accurate dual comb spectroscopy of methane and acetylene

December 1, 2012
Author(s)
Alexander M. Zolot, Fabrizio R. Giorgetta, Esther Baumann, William C. Swann, Ian R. Coddington, Nathan R. Newbury
The Doppler-limited spectra of methane between 176 THz and 184 THz (5870-6130 cm −1) and acetylene between 193 THz and 199 THz (6430-6630 cm −1) are acquired via comb-tooth resolved dual comb spectroscopy with frequency accuracy traceable to atomic

Immobilization of Proteins on Carboxylic Acid-Functionalized Nanopatterns

November 28, 2012
Author(s)
John Peter Ngunjiri, Daniel J. Stark, Tian Tian, Kimberly Briggman, Jayne C. Garno
The immobilization of proteins on nanopatterned surfaces was investigated using in situ atomic force microscopy (AFM) and ex situ infrared reflectance-absorption spectroscopy (IRAS). The AFM-based lithography technique of nanografting provided control of

EUV magnetic-dipole lines from highly-charged high-Z ions with an open $3d$ shell

November 27, 2012
Author(s)
Yuri Ralchenko, John D. Gillaspy, Joseph Reader, Dmitry D. Osin
The electron beam ion trap (EBIT) at the National Institute of Standards and Technology was used to produce highly-charged ions of hafnium, tantalum and gold with an open $3d$ shell. The extreme-ultraviolet (EUV) spectra from these ions were recorded with

Absolute line intensities for ethylene from 1800 to 2350 cm-1.

November 17, 2012
Author(s)
Walter J. Lafferty, Jean-Marie Flaud, A. Ben Hassen, F. K. Kwabia Tchana, X Landsheere, H Aroui
Fourteen Fourier transform spectra of ethylene (C2H4) have been recorded in the 1800-2350 spectral domain with different path-lengths and pressures and used to derive individual line intensities for lines belonging to the ν7 + ν8, ν4 + ν8 , ν6 + ν10, ν6 +

High-resolution infrared studies of the V10, V11, V14, and V18 levels of [1.1.1] propellane

November 15, 2012
Author(s)
Robynne Kirkpatrick, Tony Masiello, Mathew A. Martin, Joseph W. Nibler, Arthur Maki, Alfons Weber, Thomas A. Blake
This paper is a continuation of earlier work for which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions

EUV spectra of Rb-like to Cu-like gadolinium ions in an electron beam ion trap

October 8, 2012
Author(s)
Yuri Ralchenko, Deirdre Kilbane, G. O'Sullivan, John D. Gillaspy, Joseph Reader
Measurements of extreme ultraviolet radiation from highly-charged gadolinium ions were made at the National Institute of Standards and Technology. The ions were produced and confined in an electron beam ion trap (EBIT) and the spectra were recorded with a

Biosynthesis of Athmu, a alpha,gamma-hydroxy-ss-amino acid of pahayokolides A-B

October 2, 2012
Author(s)
Li Liu, Dan Bearden, Juan C. Rodriguez, Kathleen S. Rein
Pahayokolides A-B are cyanobacteria derived non-ribosomal peptides which exhibit cytotoxicity against a number of cancer cell lines. The biosynthetic origin of the 3-amino-2,5,7,8- tetrahydroxy-10-methylundecanoic acid (Athmu) moiety has been investigated
Displaying 576 - 600 of 913
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