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Single-pulse shock tube methods have been used to thermally generate hydrogen atoms and investigate the kinetics of their addition reactions with 1-butene at temperatures of 880 K to 1120 K and pressures of 145 kPa to 245 kPa. Rate parameters for the
Yong Zhou, Jun Liu, Steven Penoncello, Eric Lemmon
In this work, an equation of state for cyclohexane has been developed using the Helmholtz energy as the fundamental property with independent variables of density and temperature. Multi-property fitting technology was used to fit the equation of state that
The (p, ρ, T, x) behavior of three (methane + propane) mixtures was measured with a two-sinker magnetic suspension densimeter over the temperature range of (248.15 to 373.15) K with pressures up to the lesser of the dew point pressure or 6 MPa. The
Robert N. Goldberg, Jacob Schliesser, Ashutosh Mittal, Stephen R. Decker, Ana Filipa L. Santos, Vera L. Freitas, Aaron A. Urbas, Brian E. Lang, Christian Heisse, Maria D. Ribeiro da Silva, Brian F. Woodfield, Rui Katahira, Wei Wang, David K. Johnson
The thermochemistry of samples of amorphous cellulose, cellulose I, cellulose II, and cellulose III was studied by using oxygen bomb calorimetry, solution calorimetry in which the solvent was cadoxen, and with a Physical Property Measurement System (PPMS)
Thomas J. Bruno, Benjamin Kehimkar, Brendon Parsons, Jamin C. Hoggard, M. C. Billingsley, R. E. Synovec
Recent efforts in predicting rocket propulsion (RP-1) fuel performance through modeling put greater emphasis on obtaining detailed and accurate fuel properties, as well as to elucidate the relationships between fuel composition and their properties. Herein
Abstract Based on recent EPA Greenhouse Gas Inventories, releases of methane (CH4) from the natural gas supply chain in the United States account for approximately 23% of the total US CH4 emissions. However, there continue to be questions regarding the
Lubricity, or a substance's effect on friction and wear between two surfaces in relative motion, is affected by both chemical and physical mechanisms present at a sliding contact. The inherent lubricity of distillate motor fuels stems from surface-active
Benjamin G. Harvey, Heather A. Meylemans, Raina V. Gough, Roxanne L. Quintana, Michael Garrison, Thomas J. Bruno
Biosynthetic valencene, premnaspirodiene, and natural caryophyllene were hydrogenated and evaluated as high performance fuels. The parent sesquiterpenes were then isomerized to complex mixtures of hydrocarbons with the heterogeneous acid catalyst Nafion
Much of the gasoline sold in the U.S. is blended with ethanol. Some components associated with underground storage tanks (UST) dispensing these blended fuels (namely the sumps containing submersible pumps) are experiencing rapid degradation due to
E.K. Michailidou, Marc J. Assael, Marcia L. Huber, Ilmutdin M. Abdulagatov, Richard A. Perkins
This paper contains new, representative reference equations for the viscosity of n-heptane. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever
Andrew J. Allen, Jan Ilavsky, Pete R. Jemian, Artur Braun
Electrochemical interfaces are key to the direct conversion of fuels to electrical energy and lend energy converters like solid oxide fuel cells (SOFC) their functionality. Over extended operation at high temperatures, the microstructure of the underlying
Pyrolysis is an effective method of converting agricultural byproducts to a tarry complex fluid suitable for use as a liquid fuel. While superficially similar in appearance to crude petroleum, pyrolysis oil contains significantly more oxygenated and
NIST developed a prototype field test standard (FTS) that incorporates three test methods that could be used by state weights and measures inspectors to periodically test retail hydrogen dispensers, much as gasoline dispensers are tested today. The three
Peter Y. Hsieh, Jason A. Widegren, Tara Fortin, Thomas J. Bruno
Second-generation renewable fuels are synthesized through biochemical and thermochemical processes from non-food biomass feedstock. The resultant fuels are similar to aliphatic synthetic fuels produced through the Fischer-Tropsch process, which contain
Raina V. Gough, Jason A. Widegren, Thomas J. Bruno
The global thermal decomposition kinetics of JP-7, JP-TS and JP-900 were studied. Decomposition reactions were performed at 375, 400, 425, and 450 °C in stainless-steel ampule reactors. At each temperature, the extent of decomposition as a function of time
Peter Y. Hsieh, Jason A. Widegren, Tara Fortin, Thomas J. Bruno
The rising cost of petroleum is driving the development of alternative hydrocarbon fuels for transportation. Hydrotreated renewable fuels and Fischer-Tropsch synthetic fuels are promising alternatives to conventional petroleum, and are chemically similar
Peter Ciesielski, Michael Resch, Barron Hewetson, Jason Killgore, Alexandra Curtin, Nick Anderson, Ann Chiaramonti Debay, Donna C. Hurley, Aric Sanders, Michael Himmel, Clint Chapple, Nathan Mosier, Bryon Donohoe
Advances in genetic manipulation of the biopolymers that compose plant cell walls will facilitate more efficient production of biofuels and chemicals from biomass and lead to specialized biomaterials with tailored properties. Here we investigate several
Compressed-liquid densities of three alternative turbine fuels have been measured. The measurements were made from 270 K to 470 K, and 0.5 MPa to 50 MPa. The data have been correlated with a Tait equation, and parameters are given for each fuel. Results of
Petroleum is a complex fluid whose sulfur content varies considerably depending on its place of origin. Sour crude petroleum, which contains more than 0.5 % sulfur by mass, often requires additional processing due to the potential for corrosion and
In recent years, environmental considerations, the potential for supply disruptions, and rising fuel prices have led to the development of turbine fuels produced from non-petroleum feedstocks. To determine the suitability of an alternative turbine fuel, it
Steven J. Christopher, Stephen E. Long, Renata Amais, Joaquim N?ga
A method is described for quantification of sulfur at low concentrations on the order of 10 µg g-1 in biodiesel and diesel fuels using double isotope dilution and sector field inductively coupled plasma mass spectrometry (ID-SF-ICP-MS). Closed vessel
Andrew J. Slifka, Elizabeth S. Drexler, Nicholas Nanninga, Yaakov Levy, Joseph D. McColskey, Robert L. Amaro
Fatigue crack growth tests were conducted on two pipeline steel alloys, API 5L X52 and X100. Baseline tests were conducted in air, and those results were compared with tests conducted in pressurized hydrogen gas. All tests were run at (load ratio) R = 0.5
Robert L. Amaro, Elizabeth S. Drexler, Andrew J. Slifka
Hydrogen will likely play a key role in a future clean energy economy. However, fundamental understanding of the deleterious effects of hydrogen on the fatigue and fracture properties of pipeline steels is lacking. Furthermore, engineering tools for design
E.K. Michailidou, Marc J. Assael, Marcia L. Huber, Richard A. Perkins
This paper contains new, representative reference equations for the viscosity of n-hexane. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever