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A simple electrochemical process for submonolayer deposition of ultrathin catalytic iridum (Ir) films is demonstrated. The process enables effective utilization of one of natures rarest elements while different substrates facilitate the exploration of
Materials and photoelectrode architectures that are highly efficient, extremely stable, and made from low cost materials are required for commercially viable photoelectrochemical (PEC) water-splitting technology. A key challenge is the heterogeneous nature
Organometal trihalide perovskite solar cells with lateral device architecture recently attracted interest because of their switchable photovoltaic effect, which potentially could be leveraged to realize transparent-electrode-free solar cells. However, the
Cary Presser, Ashot Nazarian, Thomas J. Bruno, Jacolin A. Murray, John L. Molloy
A state-of-the-art, rapid laser-heating technique, referred to as the laser-driven thermal reactor, was used to characterize National Institute of Standards and Technology Standard Reference Material (SRM) diesel and biodiesel fuels. Also described are the
Jeffrey A. Manion, David A. Sheen, Iftikhar A. Awan
Presented is a combined experimental and modeling study of the kinetics of the reactions of H and CH3 with n-butane, a representative aliphatic fuel. Abstraction of H from n-alkane fuels creates alkyl radicals that rapidly decompose at high temperatures to
Kathleen A. Schwarz, Ravishankar Sundararaman, Thomas P. Moffat, Thomas C. Allison
The oxidation of organic acids on noble metal sur-faces is of importance for industrial processes and of academic interest, but the basic reaction mechanisms continue to be a matter of debate. Historically, mechanisms involving the formic acid molecule
Brent Kitchen, Omar Awartani, Regis J. Kline, Terry McAfee, Harald Ade, Brendan T. O'Connor
The role of molecular orientation of a polar conjugated polymer in a polymer-fullerene organic photovoltaic (OPV) cells is investigated. A planar heterojunction (PHJ) OPV cell composed of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid
An easy to implement method for accurately utilizing pyranometer incidence angle dependent calibration factors, or responsivities (uV/W/m2), along with the associated uncertainties has been developed. This method uses algorithms for creating single
Tasshi Dennis, Brent Fisher, Matt Meitl, John Wilson
We describe the design and operation of a spectrally programmable solar simulator capable of being concentrated to very high irradiance for the testing of multi-junction concentrator solar cells. The simulator utilizes a spatially coherent, super-continuum
Jeffrey W. Sowards, James R. Fekete, Robert L. Amaro
Pipeline steel will likely be employed extensively to transport gaseous hydrogen in support of a future clean energy economy. To date, a hydrogen-specific cost analysis of pipeline installation has not been produced. This paper performs several cost
Sebastian Engmann, Felicia A. Bokel, Andrew Herzing, Hyun W. Ro, Dean DeLongchamp, Lee J. Richter, Claudio Girotto, Bruno Caputo
We have studied the influence of the additive diiodoctane on the formation dynamics of high performance bulk heterojunction (BHJ) films based the small molecule donor 7,7'-(4,4bis(2- ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-5-(5
The development of organic photovoltaic technologies would benefit from the introduction of non-fullerene materials to replace the dominant fullerene acceptors. However, efforts to replace fullerenes with non-fullerene polymers or small molecules have
Elisabeth Mansfield, Jeffrey W. Sowards, Wendy J. Crookes-Goodson
The Applied Chemicals and Materials Division of the National Institute of Standards and Technology (NIST) hosted a workshop to identify and prioritize testing and data challenges in the area of biocorrosion. Materials used to store and distribute
Jeffrey A. Fagan, Erik K. Hobbie, John M. Harris, Matthew R. Semler
The dark transport characteristics of heterojunctions assembled from type, chirality and length-purified single-wall carbon nanotubes (SWCNTs) are used to clarify the nature of nanotube-silicon diodes and solar cells. The freestanding films show remarkable
Lee J. Richter, Dean M. DeLongchamp, Natalie Stingelin, Alberto Salleo, Martin Heeney, Aram Amassian, John deMello, James Bannock, Fiona H. Scholes, Scott Watkins, Zhuping Fei, Koen Vandewal
ABSTRACT: Here, we show that the Charge Transfer (CT) absorption signal in bulk (BHJ) solar cell blends, measured by photothermal deflection spectroscopy (PDS), is directly proportional to the density of molecular donor/acceptor interfaces. Since the
William J. Bowman, Jiangtao Zhu, Renu Sharma, Peter A. Crozier
We characterize electrical conductivity, microstructure, nano-scale grain boundary structure and chemistry of ceria electrolytes with nominal compositions of Gd0.2Ce0.8O2-δ (GDC) and Gd0.11Pr0.04Ce0.85O2-δ (GPDC). The electrolytes are fabricated using
Joshua D. Kneifel, William V. Payne, Tania Ullah, Lisa C. Ng
The National Institute of Standards and Technology (NIST) received funding through the American Recovery and Reinvestment Act (ARRA) to construct a Net Zero Energy Residential Test Facility (NZERTF). The initial goal of the NZERTF is to demonstrate that a
Betsy Pettit, Cathy Gates, Arthur H. Fanney, William M. Healy
Homeowners and builders have increasingly strived to build low energy use and environmentally friendly homes. As materials and equipment have improved, energy reduction as a goal has increasingly been replaced with the goal of net-zero energy use. But the
Steven W. Robey, W. Jin, D. B. Dougherty, W. G. Cullen, J. E. Reutt-Robey, J. Weeks, Q. Liu
Serpentine chain C60 phases were observed in scanning tunneling microscopy (STM) images of C60 layers on ZnPc or pentacene covered Ag(111) and Au(111) surfaces. This low density, quasi-one-dimensional organization contrasts starkly with the close-packed
This study evaluates the thermal performance of an dual-tank domestic hot water (DHW) system designed for a net-zero home at the National Institute of Standards and Technology, Gaithersburg Maryland campus. Hot water demand for a virtual family of four in
Mark W. Davis, William M. Healy, Matthew Boyd, Lisa Ng, William V. Payne, Harrison Skye, Tania Ullah
NIST has constructed a Net-Zero Energy Residential Test Facility that will be used as a testbed for investigating the measurement science related to systems, components, and operations that will lead to homes that generate as much energy over a course of a
Single-pulse shock tube methods have been used to thermally generate hydrogen atoms and investigate the kinetics of their addition reactions with 1-butene at temperatures of 880 K to 1120 K and pressures of 145 kPa to 245 kPa. Rate parameters for the
Paul A. Lane, Paul D. Cunningham, Joseph S. Melinger, Edwin J. Heilweil
We present a study of charge transfer and carrier dynamics in nano-films of zinc phthalocyanine (ZnPc) and buckmisnster¬fullerene (C60) by investigated by time-resolved terahertz spectroscopy (TRTS). We compare terahertz photocon¬ductivity dynamics in
Behrang H. Hamadani, John F. Roller, Brian P. Dougherty, Howard W. Yoon
Irradiance-mode spectral response measurements of solar cells are important because they provide a direct, reliable and accurate route for determination of the short circuit current (Isc) of solar cells under air mass 1.5 standard reference spectrum. In
Leite Marina, maxim abashin, Henri Lezec, anthony gianfrancesco, Alec Talin, Nikolai Zhitenev
The local collection characteristics of grain interiors and grain boundaries in thin film CdTe polycrystalline solar cells are investigated using scanning photocurrent microscopy. The carriers are locally generated by light injected through a small