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Displaying 226 - 250 of 379

Self-terminated Electrodeposition of Iridium Electrocatalysts

September 16, 2015
Author(s)
Thomas P. Moffat
A simple electrochemical process for submonolayer deposition of ultrathin catalytic iridum (Ir) films is demonstrated. The process enables effective utilization of one of nature’s rarest elements while different substrates facilitate the exploration of

Photovoltaic switching mechanism in lateral structure hybrid Perovskite solar cells

August 5, 2015
Author(s)
Yongbo Yuan, Jungseok Chae, Yuchuan Shao, Qi Wang, Zhengguo Xiao, Andrea Centrone, Jinsong Huang
Organometal trihalide perovskite solar cells with lateral device architecture recently attracted interest because of their switchable photovoltaic effect, which potentially could be leveraged to realize transparent-electrode-free solar cells. However, the

Thermochemical Characterization of Biodiesel Fuels using a Novel Laser-Heating Technique

August 4, 2015
Author(s)
Cary Presser, Ashot Nazarian, Thomas J. Bruno, Jacolin A. Murray, John L. Molloy
A state-of-the-art, rapid laser-heating technique, referred to as the laser-driven thermal reactor, was used to characterize National Institute of Standards and Technology Standard Reference Material (SRM) diesel and biodiesel fuels. Also described are the

Formic Acid oxidation on platinum- a simple mechanistic study

July 15, 2015
Author(s)
Kathleen A. Schwarz, Ravishankar Sundararaman, Thomas P. Moffat, Thomas C. Allison
The oxidation of organic acids on noble metal sur-faces is of importance for industrial processes and of academic interest, but the basic reaction mechanisms continue to be a matter of debate. Historically, mechanisms involving the formic acid molecule

Tuning Open-Circuit Voltage in Organic Solar Cells with Molecular Orientation

June 24, 2015
Author(s)
Brent Kitchen, Omar Awartani, Regis J. Kline, Terry McAfee, Harald Ade, Brendan T. O'Connor
The role of molecular orientation of a polar conjugated polymer in a polymer-fullerene organic photovoltaic (OPV) cells is investigated. A planar heterojunction (PHJ) OPV cell composed of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid

Economic impact of applying high strength steels in hydrogen gas pipelines

June 17, 2015
Author(s)
Jeffrey W. Sowards, James R. Fekete, Robert L. Amaro
Pipeline steel will likely be employed extensively to transport gaseous hydrogen in support of a future clean energy economy. To date, a hydrogen-specific cost analysis of pipeline installation has not been produced. This paper performs several cost

Real-time x-ray scattering studies of film formation in high performing small-molecule organic solar cells

May 23, 2015
Author(s)
Sebastian Engmann, Felicia A. Bokel, Andrew Herzing, Hyun W. Ro, Dean DeLongchamp, Lee J. Richter, Claudio Girotto, Bruno Caputo
We have studied the influence of the additive diiodoctane on the formation dynamics of high performance bulk heterojunction (BHJ) films based the small molecule donor 7,7'-(4,4bis(2- ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-5-(5

The Nature of Record Efficiency Fluid-Processed Nanotube-Silicon Heterojunctions

April 20, 2015
Author(s)
Jeffrey A. Fagan, Erik K. Hobbie, John M. Harris, Matthew R. Semler
The dark transport characteristics of heterojunctions assembled from type, chirality and length-purified single-wall carbon nanotubes (SWCNTs) are used to clarify the nature of nanotube-silicon diodes and solar cells. The freestanding films show remarkable

Direct correlation of charge transfer absorption with molecular donor:acceptor interfacial area via photothermal deflection spectroscopy

April 9, 2015
Author(s)
Lee J. Richter, Dean M. DeLongchamp, Natalie Stingelin, Alberto Salleo, Martin Heeney, Aram Amassian, John deMello, James Bannock, Fiona H. Scholes, Scott Watkins, Zhuping Fei, Koen Vandewal
ABSTRACT: Here, we show that the Charge Transfer (CT) absorption signal in bulk (BHJ) solar cell blends, measured by photothermal deflection spectroscopy (PDS), is directly proportional to the density of molecular donor/acceptor interfaces. Since the

Design Challenges of the NIST Net Zero Energy Residential Test Facility

March 26, 2015
Author(s)
Betsy Pettit, Cathy Gates, Arthur H. Fanney, William M. Healy
Homeowners and builders have increasingly strived to build low energy use and environmentally friendly homes. As materials and equipment have improved, energy reduction as a goal has increasingly been replaced with the goal of net-zero energy use. But the

Monitoring Techniques for the Net-Zero Energy Residential Test Facility

December 31, 2014
Author(s)
Mark W. Davis, William M. Healy, Matthew Boyd, Lisa Ng, William V. Payne, Harrison Skye, Tania Ullah
NIST has constructed a Net-Zero Energy Residential Test Facility that will be used as a testbed for investigating the measurement science related to systems, components, and operations that will lead to homes that generate as much energy over a course of a

Challenges of Irradiance-mode Spectral Response Measurements

October 16, 2014
Author(s)
Behrang H. Hamadani, John F. Roller, Brian P. Dougherty, Howard W. Yoon
Irradiance-mode spectral response measurements of solar cells are important because they provide a direct, reliable and accurate route for determination of the short circuit current (Isc) of solar cells under air mass 1.5 standard reference spectrum. In

Nanoscale Imaging of Photocurrent and Efficiency in CdTe Solar Cells

October 15, 2014
Author(s)
Leite Marina, maxim abashin, Henri Lezec, anthony gianfrancesco, Alec Talin, Nikolai Zhitenev
The local collection characteristics of grain interiors and grain boundaries in thin film CdTe polycrystalline solar cells are investigated using scanning photocurrent microscopy. The carriers are locally generated by light injected through a small
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