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Appearance Potentials of Ions Produced by Electron-Impact Induced Dissociative Ionization of SF6 and Related Compounds
Published
Author(s)
Ken L. Stricklett, J. M. Kassoff, James K. Olthoff, Richard J. Van Brunt
Abstract
Methods are described, which are based on the use of a commercial mass spectrometer, for determination of ionization and fragment ion appearance potentials by electron impact. These methods are applied to the principal sulfur-bearing compounds produced by decomposition of SF6 by electrical discharges. The compounds investigated include: SF4, SO2, SOF2, SO2F2, SOF4, SF5Cl, S2F10, S2OF10, and S2O2F10, as well as SF6. Experimental conditions are recommended for improved sensitivity to trace levels of these decomposition by-products in SF6.
Stricklett, K.
, Kassoff, J.
, Olthoff, J.
and Van Brunt, R.
(1995),
Appearance Potentials of Ions Produced by Electron-Impact Induced Dissociative Ionization of SF<sub>6</sub> and Related Compounds, Proc., Intl. Symp. on Gaseous Dielectrics, Knoxville, TN, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=27876
(Accessed December 12, 2024)