We employ novel pulsed optical measurement techniques to directly monitor carrier generation, migration and relaxation dynamics in semiconducting polymer and mixed organic/organometallic photovoltaic films. These studies are being conducted to measure (without contact) ultrafafast carrier dynamics in novel electronic photovoltaic materials being considered and developed for future solar cell, LED and energy capture applications. By applying UV-Visible excitation with time delayed THz probe pulses, we are able to identify candidate nanolayered materials and bulk organic mixtures that exhibit rapid exciton quenching, thermal energy relaxation and long-lived free carriers that could be amenable for higher efficiency solar-to-electricity applications.
Recent studies examined samples of nano-layered Zn-pthlalocyanine electron donor with C60 acceptors as a function of layer thickness and number of interfaces grown at NRL using chemical vapor deposition conditions. As the layer thickness decreases (to <5 nm), initially generated bi-excitons thermally relax recombine or are trapped within a few picoseconds, while free carriers provide a longer-lived signal proportional to their population measured by the transient THz absorption. This signal is directly proportional to the material conductivity suggesting that as the layer thickness decreases, initially generated excitons more readily dissociate to free carriers which are more highly mobile within the donor-acceptor interface.