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Search Publications by: Christopher Stafford ()

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Displaying 1 - 25 of 394

Surface photooxidation of polypropylene-based photovoltaic backsheets: A comprehensive spectroscopic investigation

December 8, 2024
Author(s)
Karissa Jensen, Ashlee Aiello, Stefan Mitterhofer, Chiara Barretta, Gernot Oreski, Christopher Stafford, Xiaohong Gu
The prospect of cost reduction, enhanced performance, and improved sustainability has been driving innovation in the development of new backsheet materials for photovoltaic (PV) modules in recent years. Among the materials of interest, polypropylene (PP)

New Method to Probe the Surface Properties of Polymer Thin Films by Two-Dimensional (2D) Inverse Gas Chromatography (iGC)

June 25, 2024
Author(s)
Whirang Cho, Lucas Flagg, Christopher Stafford, Jeremiah Woodcock, Daniel Burnett, Anett Kondor, Douglas Fox, John Hoffmann
Polymer-based functional surface coatings are extensively used in advanced technologies, including optics, energy, and environmental applications. Surface thermodynamic properties profoundly impact the molecular interactions that control interfacial

Measuring the Influence of CO2 and Water Vapor on the Dynamics in Polyethylenimine To Understand the Direct Air Capture of CO2 from the Environment

June 5, 2024
Author(s)
Avery Baumann, Takeshi Yamada, Kanae Ito, Chad R. Snyder, John Hoffman, Craig Brown, Christopher Stafford, Christopher Soles
Aminopolymer sorbents are leading candidates for extracting CO2 directly from the atmosphere under ambient conditions. For effective carbon capture, this requires not only that the CO2 actively binds with amine groups of the polymer under low gas

Assessing Composite Structure in Metal-Organic Framework-Polymer Mixed-Matrix Membranes

March 15, 2024
Author(s)
Avery Baumann, Peter Beaucage, Richard Vallery, David Gidley, Ryan Nieuwendaal, Chad R. Snyder, Jan Ilavsky, Fu Chen, Christopher Stafford, Christopher Soles
Metal-organic frameworks (MOFs) are renowned for their tunable structure, porosity, and internal chemistry with demonstrated applications in molecular separations, storage, and conversion. While they are widely usable, the powdery characteristics of MOF

Correlating the Diffusion of Water in Model Polyamides with Controlled Crosslink Densities to the Performance in Reverse Osmosis Membranes for Desalination

April 18, 2023
Author(s)
Velencia Witherspoon, Kanae Ito, Chad R. Snyder, Madhusudan (Madhu) Tyagi, Tyler Martin, Peter Beaucage, Ryan Nieuwendaal, Richard Vallery, David Gidley, Jeffrey Wilbur, Dean Welsh, Christopher Stafford, Christopher Soles
To elucidate robust design cues for improving the active polyamide (PA) filtration layers in reverse osmosis (RO) membrane for desalination, we systematically reduce the cross-link density of a PA network based on m-phenylene diamine by substituting a

Solvent Transport Model for Polyamide Nanofilm Membranes Based on Accurate Hansen Solubility Parameters

February 21, 2023
Author(s)
Min Gyu Shin, Wansuk Choi, June Huh, William Mulhearn, Jung Sun Hwang, Christopher Stafford, Jeong F Kim, Jung Hyun Lee
Polyamide (PA) nanofilm membranes for solvent filtration are widely used in various industries. However, reliable models that can describe solvent transport in PA membranes have yet to be developed owing to measurement challenges associated with the highly

Reproducible Sorbent Materials Foundry for Carbon Capture at Scale

September 22, 2022
Author(s)
Austin McDannald, Howie Joress, Brian DeCost, Avery Baumann, A. Gilad Kusne, Kamal Choudhary, Taner N. Yildirim, Daniel Siderius, Winnie Wong-Ng, Andrew J. Allen, Christopher Stafford, Diana Ortiz-Montalvo
We envision an autonomous sorbent materials foundry (SMF) for rapidly evaluating materials for direct air capture of carbon dioxide ( CO2), specifically targeting novel metal organic framework materials. Our proposed SMF is hierarchical, simultaneously

Specification for Interoperability Testing of Contactless Fingerprint Acquisition Devices

June 8, 2022
Author(s)
John M. Libert, Shahram Orandi, Bruce Bandini, Kenneth Ko, Craig I. Watson, Christopher Stafford, Matthew E. Staymates, John Grantham
This guidance specifies a protocol and associated metrics for the evaluation of contactless fingerprint acquisition device, and their interoperability with legacy devices. This protocol enables contactless fingerprint developers seeking certification of

A method to quantify composition, purity, and cross-link density of the polyamide active layer in reverse osmosis composite membranes using 13C cross-polarization magic angle spinning nuclear magnetic resonance spectroscopy

February 12, 2022
Author(s)
Ryan Nieuwendaal, Christopher Stafford, Jeff Wilbur
A method for harvesting and purifying the thin polyamide (PA) active layer from thin-film composite (TFC) reverse osmosis (RO) membranes was developed, enabling quantitative nuclear magnetic resonance (NMR) measurements of the composition and cross-linking

Orientation of Thin Polyamide Layer-by-Layer Films on Non-Porous Substrates

December 16, 2021
Author(s)
Tawanda J. Zimudzi, Sarah E. Sheffield, Kathleen E. Feldman, Peter Beaucage, Dean DeLongchamp, Douglas I. Kushner, Christopher Stafford, Michael A. Hickner
The orientation of polyamide thin films on non-porous substrates was investigated using Fourier transform infrared (FTIR) spectroscopy and corroborated by near edge X-ray absorption fine structure (NEXAFS) measurements. Polyamide films comprised of m
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