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Displaying 2051 - 2075 of 2105
Anzor Mikaia, Vladimir G. Zaikin, Vladimir Trusov, Andrei Nekhaev, Vladimir Tyurin
Under electron ionization conditions decarbonylation precedes the fragmentation of ligands in iron hexacarbonyl complexes and involves a rupture of metal-ligand bonds.
Decomposition of cyclopropane and cyclobutane containing compounds with Carbon, Silicon and Germanium atoms under mass spectrometry conditions is discussed.
Anzor Mikaia, Lyudmila Medvedkova, Vladimir G. Zaikin, Valentin Vdovin, A Kamisheva
A GC-MS method for structure elucidation of cyclopropane compounds is developed. The method includes the use of hydrogenolysis microreactor in the inlet system of a GC-MS and H2 or D2 as carrier and reagent gas.
Anzor Mikaia, Elena Trusova, Lyudmila Perepelitchenko, Vladimir G. Zaikin
The stereospecificity of fragmentation for isomeric dialkyl- and methyl,phenylthiacyclohexanes under electron ionization are established. Experimentally obtained relative Ionization and appearance energies for the stereoisomers are in agreement with