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Materials

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Displaying 976 - 1000 of 2343

Long-Range Electric Field Control of Permalloy Layers in Strain-Coupled Composite Multiferroics

October 18, 2018
Author(s)
Michelle E. Jamer, Colin R. Rementer, Anthony Barra, Alexander Grutter, Kevin Fitzell, Daniel Gopman, Julie Borchers, Gregory P. Carman, Brian Kirby, Jane P. Chang
Artificial composite multiferroic materials can be created by interfacing magnetostrictive and piezoelectric materials, allowing for electric field control of magnetic properties. For multilayer device applications, addition of weakly magnetostrictive

Boosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal-Organic Frameworks

October 11, 2018
Author(s)
Rui-Biao Lin, Hui Wu, Libo Li, Xiao-Liang Tang, Zhiqiang Li, Junkuo Gao, Hui Cui, Wei Zhou, Banglin Chen
The separation of ethane from its analogous ethylene is of great importance in the petrochemical industry, but very challenging and energy-intensive. Adsorptive separation using C cH 6-selective porous materials can directly produce high purity C 2H 4 in a

reductus: A Stateless Python Data-Reduction Service with a Browser Frontend

October 1, 2018
Author(s)
Brian B. Maranville, William D. Ratcliff, Paul A. Kienzle
The online data reduction service reductus transforms measurements in experimental science from laboratory coordinates into physically meaningful quantities with accurate estimation of uncertainties based on instrumental settings and properties. This

Microscopic Identification of Micro-Organisms on Pre-Viking Swedish Hillfort Glass

September 30, 2018
Author(s)
Bruce Arey, Edward Vicenzi, Rolf Sjoblom, Robert Koestler, Paula DePriest, Thomas Lam, David Peeler, John McCloy, Albert Kruger, Jamie Weaver
Borborg Hillfort is a vitrified hillfort located in the Husby-Långhundra parish in Uppland Sweden (Fig. 1A). The site dates to the Great Migration Period, around 740 ± 100 CE. [1]. Two types of glasses have been identified within the ramparts – one that is

Reversible Flat to Rippling Phase Transition in Fe Containing Layered Battery Electrode Materials

September 26, 2018
Author(s)
Xi Chen, Sooyeon Hwang, Robin Chisnell, Yichao Wang, Fan Wu, Sooran Kim, Jeffrey W. Lynn, Dong Su, Xin Li
The Jahn-Teller effect in solid-state chemistry relates the symmetry of electronic configuration to the atomic arrangement around the individual transition metal ion. The collective behavior of many such Jahn-Teller active entities is of great interest in

Approaches for the Quantitative Analysis of Oxidation State in Cerium Oxide Nanomaterials

September 21, 2018
Author(s)
Christopher M. Sims, Russell A. Maier, Aaron C. Johnston-Peck, Justin M. Gorham, Vincent A. Hackley, Bryant C. Nelson
Cerium oxide nanomaterials (nanoceria, CNMs) are receiving increased attention from the research community due to their unique chemical properties, most prominent of which is their ability to alternate between the Ce3+ and Ce4+ oxidation states. While many

Natural Alteration of 6Li Neutron Shielding Glass

September 21, 2018
Author(s)
Jamie L. Weaver, Danyal J. Turkoglu
Li-6 alumino-silicate glass, a neutron shielding material, has been studied to determine if and to what extent it alters under natural conditions. Analyses included neutron depth profiling, prompt gamma activation analysis, x-ray diffraction, and scanning

On the mechanisms and the characterization of the pulsed electron grafting of styrene onto poly(tetrafluoroethylene-co-hexafluoropropylene) to synthesize a polymer electrolyte membrane

September 21, 2018
Author(s)
Byung N. Kim, Alia Weaver, Marina Chumakov, Ileana M. Pazos, Dianne L. Poster, Karen Gaskell, Do H. Han, Gunther Scherer, Michael A. Yandrasits, Byung C. Lee, Mohamad Al-Sheikhly
During the pulsed-electron beam direct grafting of neat styrene onto poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP) substrate, the radiolytically-produced styryl and carbon-centered FEP radicals undergo various desired and undesired competing

Structure, Rheology, and Microrheology of Wormlike Micelles made of PB-PEO Diblock Copolymers

September 21, 2018
Author(s)
Antonio Tavera-Vazquez, Brisa Arenas-Gomez, Cristina Garza, Yun Liu, Rolando Castillo
A diblock copolymer made of poly(but-2-ene-1,4-diyl)-block-poly(oxyethylene), with a degree of polymerization of the polybutadiene and polyethylene blocks of 37 and 57, respectively, self-assembles in water as worm-like micelles determined with small angle

Defect-Driven Extreme Magnetoresistance in an I-Mn-V Semiconductor

September 20, 2018
Author(s)
Junjie Yang, Aaron Wegner, Craig Brown, Despina Louca
Semiconducting electronics have been transformed in part due to progress in spin polarized transport. Central to modern day spintronics, contemporary magnetoresistive components are based on ferromagnetic multilayers. New directions in the search for the

Quantification of Carbon Nanotube Liquid Crystal Morphology via Neutron Scattering

September 11, 2018
Author(s)
Francesca Mirri, Rana N. Ashkar, Vida Jamali, Lucy Liberman, Robert A. Pinnick, Paul van der Schoot, Yeshayahu Talmon, Paul Butler, Matteo Pasquali
Liquid phase assembly is among the most industrially attractive routes for scalable carbon nanotube (CNT) processing. Chlorosulfonic acid (CSA) was found to be an ideal solvent for CNTs, spontaneously dissolving them without compromising their properties

Scaling Behavior of Anisotropy Relaxation in Deformed Polymers

September 11, 2018
Author(s)
Christopher N. Lam, Wen-Sheng Xu, Wei-Ren Chen, Zhe Wang, Christopher B. Stanley, Jan-Michael Y. Carrillo, David Uhrig, Weiyu Wang, Kunlun Hong, Yun Liu, Lionel Porcar, Changwoo Do, Gregory S. Smith, Bobby G. Sumpter, Yangyang Wang
Drawing an analogy to the paradigm of quasi-elastic neutron scattering, we present a general approach for quantitatively investigating the spatiotemporal dependence of structural anisotropy relaxation in deformed polymers by using small-angle neutron

Resolving Interfacial Charge Transfer in Titanate Superlattices using Resonant X-Ray Reflectometry

September 6, 2018
Author(s)
Ryan F. Need, P. B. Marshall, E. Weschke, Alexander J. Grutter, Dustin Allen Gilbert, E. Arenholz, P. Shafer, S. Stemmer, Stephen D. Wilson
Oxide interfaces, where strong electron-electron correlations lead to emergent phase behavior, have been the subject of intense study in recent years. However, the buried nature of heterointerfaces often makes them challenging to probe directly. Addressing

Strain-Induced Competition between Ferromagnetism and Emergent Antiferromagnetism in (Eu,Sr)MnO 3

September 4, 2018
Author(s)
Alexander J Grutter, Steven M. Disseler, E. J. Moon, Dustin Allen Gilbert, E. Arenholz, A. Suter, T. Prokscha, Z. Salman, Brian J Kirby, S. J. May
We demonstrate emergent antiferromagnetic interactions is strained thin films of the mixed valence manganite (Eu,SR)MnO 3. Although the composition studied, Eu 0.7Sr 0.3MnO 3, will nominally yield a ferromagnetic phase in bulk, we observe significant

High-efficiency Coherence-Preserving Harmonic Rejection with Crystal Optics

September 1, 2018
Author(s)
Fan Zhang, Andrew J. Allen, Lyle E. Levine, Gabrielle G. Long, Ivan Kuzmenko, Jan Ilavsky
We report a harmonic rejection scheme based on the combination of Si (111) monochromator and Si (220) harmonic-rejection crystal optics. This approach is of importance to a wide range of X- ray applications in all three major branches of modern X-ray

Protocols for Determining the Mechanical Properties of High Strength Copolymer Aramid Fibers

September 1, 2018
Author(s)
Amanda L. Forster, Viviana Rodriguez Cardenas, Ajay Krishnamurthy, Amy E. Engelbrecht-Wiggans, Zois Tsinas
The primary goal of the manuscript is to develop a protocol to prepare consistent specimens for accurate mechanical testing of high strength copolymer aramid fibers, by removing a coating and disentangling the individual fiber strands without introducing

SEIRAS Study of Chloride Mediated Polyether Adsorption on Cu

August 31, 2018
Author(s)
Thomas P. Moffat, Daniel Josell, Lee J. Richter
Surface enhanced infrared absorption spectroscopy (SEIRAS) was used to examine the co- adsorption of a selection of polyethers with Cl- under conditions relevant to superconformal Cu electrodeposition in CuSO4-H2SO4 electrolytes. In 0.1 mol/L H2SO4 a

Kinetic Separation of Propylene over Propane in a Microporous Metal-Organic Framework

August 30, 2018
Author(s)
Libo Li, Xiaoqing NMN Wang, Wei Zhou, Litao Jia, Banglin Chen
Propylene (C 3H 6)/propane (C 3H 8) separation is one of the most challenging as well as most energy-intensive separation processes in the petrochemical industry. Herein we report a microporous metal-organic framework ELM-12 with appropriate channels where

Nanoparticle Architecture Preserves Magnetic Properties during Coating to Enable Robust Multi-Modal Functionality

August 23, 2018
Author(s)
Lauren E. Woodard, Cindi L. Dennis, Julie Borchers, Anilchandra Attaluri, Esteban Velarde, Charlene Dawidczyk, Peter C. Searson, Martin G. Pomper, Robert Ivkov
Mixed metal/metal oxide nanoparticles offer potential as multifunctional platforms for disease diagnosis and therapy, or 'theranostics' [1-9]. We describe the synthesis and characterization of gold/silica/iron oxide core-shell nanoparticles, for which the
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