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Environment

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Displaying 276 - 300 of 537

Characterization of Surface Accumulation and Release of Nanosilica During Irradiation of Polymer Nanocomposites with Ultraviolet Light

August 12, 2012
Author(s)
Tinh Nguyen, Bastien T. Pellegrin, Coralie Bernard, Savelas A. Rabb, Paul E. Stutzman, Justin M. Gorham, Xiaohong Gu, Lee L. Yu, Joannie W. Chin
Nanofillers are increasingly used for enhancing multiple properties of polymeric materials in many applications. However, polymers are susceptible to photodegradation by solar ultraviolet (UV) radiation Therefore, nanofillers in a polymer nanocomposite

SEABIRD TISSUE ARCHIVAL AND MONITORING PROJECT: Egg Collections and Analytical Results for 2006-2009

August 2, 2012
Author(s)
Stacy S. Schuur, Paul R. Becker, Sylvain Berail, Russell D. Day, Olivier F. Donard, Keith A. Hobson, Amanda J. Moors, Rebecca S. Pugh, Lauren B. Rust, David G. Roseneau
Since 1999, the Seabird Tissue Archival and Monitoring Project (STAMP) has collected, banked, and analyzed seabird eggs using established protocols to monitor chlorinated pesticides, polychlorinated biphenyls (PCBs), brominated flame retardants, and

The winter time South Pole tropospheric water vapor column: Comparisons of radiosonde and recent terahertz radiometry, use of the saturated column as a proxy measurement; and inference of decadal trends

July 7, 2012
Author(s)
Richard A. Chamberlin, Erich N. Grossman
We use a fifty year record of winter time radiosonde observations at the South Pole to estimate the precipitable water vapor column (PWV) over the entire period. Humidity data from older radiosondes is of limited reliability; however, we think an

Anisotropic Field Evaporation of Diatomic Species from Oxides and Nitrides

May 21, 2012
Author(s)
Matthew D. Brubaker, David R. Diercks, R Kirchofer, Kristine A. Bertness, Norman A. Sanford, Brian Gorman
Recent work using laser-assisted atom probe tomography on non-metallic materials has indicated that for many data collection conditions, anisotropic evaporation can occur. In some cases this can be attributed to a high laser energy leading to uneven

Environmental Metabolomics

March 15, 2012
Author(s)
Daniel W. Bearden
The application of metabolomics in the field of environmental science or ecology, which has developed based substantially on NMR spectroscopic approaches, is a fast paced, rapidly developing field which seems to be poised to help re-frame the discussion of

Spatial distribution of bottlenose dolphins (Tursiops truncatus) inferred from stable isotopes and priority organic pollutants

February 15, 2012
Author(s)
Rachel Wilson, John Kucklick, Brian C. Balmer, Randall Wells, Jeffery Chanton, Doug Nowacek
Differences in priority organic pollutants (POPs), analyzed by gas chromatography-mass spectrometry, and stable isotope ratios (δ¹³C, δ³⁴S, and δ¹⁵N; analyzed by isotope ratio-mass spectrometry), divide 77 bottle- nose dolphins (Tursiops truncatus) from

2-Bromo-3,3,3-Trifluoropropene: OH Reaction Rate Constant, IR Absorption Spectrum, Ozone Depletion Potentials and Global Warming Potentials

December 30, 2011
Author(s)
Kenneth O. Patten, Victor Khamaganov, Vladimir L. Orkin, Steven L. Baughcum, Donald J. Wuebbles
The rate constant for the gas phase reaction of OH radicals with BTP (2-Bromo-3,3,3-trifluoropropene, CH2=CBrCF3) was measured using a flash photolysis resonance-fluorescence technique over the temperature range 220 K to 370 K. The Arrhenius plot was found

Determination of Moisture Content of Single-Wall Carbon Nanotubes

October 17, 2011
Author(s)
Rolf L. Zeisler, Rabia Oflaz, Ralph E. Sturgeon, Rick L. Paul, Brian E. Lang, Jeffrey A. Fagan, Joseph W. Lam, Anthony Windust, P Grinberg, Benoit Simard, Christopher T. Kingston
Several techniques were evaluated for the establishment of reliable water/moisture content of single-wall carbon nanotubes. Karl Fischer titration (KF) provides for a direct measure of the water content and was used for benchmarking against results

Comparison of Gas Velocity Measurements and CFD Predictions in the Exhaust Duct of a Stationary Source

July 13, 2011
Author(s)
Rodney A. Bryant, Olatunde B. Sanni, Elizabeth F. Moore, Robert P. Borthwick, Marco G. Fernandez, Iosif I. Shinder, Jiann C. Yang, Aaron N. Johnson
Two series of independent flow measurements were conducted for cross validation of flow velocity in the exhaust duct of the NIST Large Fire Laboratory. In the first series, two pressure measurement probe types, an S probe and a 3-D probe, were used to

Examination of United States Carbon Dioxide Emission Databases

June 10, 2011
Author(s)
Robert P. Borthwick, James Whetstone, Jiann C. Yang, Antonio Possolo
This paper compared carbon dioxide emissions from plants obtained in two ways, first from the US Department of Energy, Energy Information Administration EIA-767 database and EIA-1605 Greenhouse Gas Reporting Program guidelines and second from the U.S. Envi

Physicochemical characterization and in vitro hemolysis evaluation of silver nanoparticles

June 7, 2011
Author(s)
Vytautas Reipa, Jonghoon Choi, Nam S. Wang, Victoria M. Hitchins, Peter L. Goering, Robert Malinauskas
In anticipation of the increased use of various forms of silver as an antimicrobial agent in medical devices, the objective of this study was to evaluate the in vitro hemolytic potential of silver nanoparticles in dilute human blood, and to relate particle

Anemia, Hypothyroidism and Immune Suppression Associated with Polychlorinated Biphenyl Exposure in Bottlenose Dolphins (Tursiops truncatus)

May 25, 2011
Author(s)
John Kucklick, Lori Schwacke, Eric Zolman, Brian C. Balmer, Sylvain De Guise, Clay George, Jennifer Hoguet, Steve Lamb, Milton Levin, J. L. Litz, W E. McFee, Ned Place, Forrest Townsend, Teresa Rowles, Randall Wells, Aleta Hohn
Background: Polychlorinated biphenyls (PCBs) and other legacy organohalogens are often monitored in marine mammals both to understand health risks for populations of these protected species and as an indication of marine food web contamination. Bottlenose

MSEL Sustainability Seminar Series (2009)

May 15, 2011
Author(s)
Winnie K. Wong-Ng, Kathryn L. Beers, Richard E. Ricker, Martin L. Green
An MSEL Sustainability Seminar Series took place in 2009, aimed at the following goals: (1) to introduce this important subject matter to our staff and (2) to learn and discuss the metrology needs for materials for sustainability applications. Since

Selective Adsorption of CO2 from Light Gas Mixtures Using a Structurally Dynamic Porous Coordination Polymer

April 29, 2011
Author(s)
Winnie K. Wong-Ng, Andrew J. Allen, Laura Espinal, Kristi L. Kauffman, Jeffrey T. Culp, Angela Goodman, Thomas G. Brown, Mark P. Bernardo, Russel J. Pancoast, Danielle Chirdon, Christopher Matranga
The selective adsorption of CO2 from binary mixtures of N2 and CH4 was investigated using a structurally dynamic porous coordination polymer, catena-bis(dibenzoylmethanato)-(4,4’bipyridyl)nickel (II), ‘NiDBM-Bpy’, as the separation sorbent. A third gas

High Pressure Viscosity Measurements of 1,1,1,2-Tetrafluoroethane

April 27, 2011
Author(s)
Arno R. Laesecke, Scott Bair
Viscosity measurements have been carried out with a falling-cylinder instrument in the compressed liquid and supercritical region of the hydrofluorocarbon 1,1,1,2-tetrafluoroethane (R134a). A highly pure sample was used. The measurement region at

Ozone-Depleting Substances (ODSs) and Related Chemicals, Chapter 1 in Scientific Assessment of Ozone Depletion: 2010, Global Ozone Research and Monitoring Project-Report No.52, 516 pp., World Meteorological Organization, Geneva, Switzerland, 2011.

March 30, 2011
Author(s)
Stephen A. Montzka, S. Reimannander, Andreas Engel, Kirstin Kruger, O?Doherty Simon, William T. Sturges , Donald R. Blake , Marcel Dorf Dorf, Paul J. Fraser , Lucien Froidevaux , Kenneth Jucks, Karin Kreher, Michael J. Kurylo III, Abdelwahid Mellouki , John Miller , Ole J. Nielsen , Vladimir L. Orkin, Ronald G. Prinn , Robert Rhew , Michelle L. Santee , Andreas Stohl , Daniel P. Verdonik
The present document will be part of the information upon which the Parties to the United Nations Montreal Protocol will base their future decisions regarding protection of the stratospheric ozone layer. OVERVIEW It has been recognized since the 1970s that

High Accuracy Measurements of OH Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols.

March 4, 2011
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the
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