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Real Time Shape Evolution of Nanoimprinted Polymer Structures During Thermal Annealing
Published
Author(s)
Ronald L. Jones, T Hu, Christopher L. Soles, Eric K. Lin, R M. Reano, Stella W. Pang, D M. Casa
Abstract
The real time shape of nanoimprinted polymer patterns are measured as a function of annealing temperature and time using a new metrology technique, Critical Dimension Small Angle X-ray Scattering (CD-SAXS). Periodicity, linewidth, line height, and sidewall angle are reported both below and above the bulk glass transition temperature (TG) for a nanoimprinted line/space pattern of poly(methyl methacrylate) (PMMA). For T > TG, shape changes are accelerated in early stages due to the reduction of high energy corners, yielding to a slowed rate in longer time regimes.
Jones, R.
, Hu, T.
, Soles, C.
, Lin, E.
, Reano, R.
, Pang, S.
and Casa, D.
(2006),
Real Time Shape Evolution of Nanoimprinted Polymer Structures During Thermal Annealing, Nano Letters, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=852413
(Accessed October 9, 2025)