Mass spectrometric study of aromatic derivatives of cycloalkanes and cycloalkanols
Anzor I. Mikaia, Vladimir G. Zaikin, Evgenyi Finkelstein, Valentin Vdovin
General and specific fragmentation pathways of arylcyclanes with three, four, five and six membered saturated rings under electron ionization are determined. The resulting characteristic ions are useful for structure elucidation. The measured appearance energies for styrene radical cations increase with the decrease of a ring strain.
Russian Chemical Bulletin
Mass spectra, Electron ionization, Fragmentation mechanism, Appearance energy, Cyclopropane, Cyclobutane
, Zaikin, V.
, Finkelstein, E.
and Vdovin, V.
Mass spectrometric study of aromatic derivatives of cycloalkanes and cycloalkanols, Russian Chemical Bulletin
(Accessed November 28, 2023)