Laser-Assisted Vaporization Mass Spectrometry: Application to Thermochemistry at Very High Temperature

Published

September 1, 2001

Author(s)

John W. Hastie, D W. Bonnell, Peter K. Schenck

Abstract

Classical mass spectrometically-based approaches to the determination of high temperature thermochemical data and functions are limited in their applicable ranges of temperature and vapor pressure. An earlier laser-based mass spectrometric approach substantially overcame these limitations, but with reduced precision in temperature and pressure determination. Here, we present new methods that largely resolve the earlier limitations of laser-assisted vaporization mass spectrometry, thereby greatly expanding the scope of application of high temperature mass spectrometric technique.

Citation

NIST Interagency/Internal Report (NISTIR) - 6793

Report Number

6793

NIST Pub Series

NIST Interagency/Internal Report (NISTIR)

Pub Type

NIST Pubs

Keywords

high temperature, laser heating, mass spectrometry, thermodynamic data, vapor pressure

Citation

Hastie, J. , Bonnell, D. and Schenck, P. (2001), Laser-Assisted Vaporization Mass Spectrometry: Application to Thermochemistry at Very High Temperature, NIST Interagency/Internal Report (NISTIR), National Institute of Standards and Technology, Gaithersburg, MD (Accessed October 13, 2025)