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Ionization and appearance potentials in organic chemistry. 3. Determination of the difference between the enthalpies of formation of cis- and trans-isomers of bicyclo[4.3.0]- nonane and bicyclo[4.4.0]decane Using Appearance Potentials

Published

Author(s)

Anzor I. Mikaia, Vladimir G. Zaikin

Abstract

The first adiabatic potentials of the ionization of cis and trans iosmers with respect to the linkage of the rings of bicyclo[4.3.0]nonane and bicyclo[4.4.0]decane are practically identical. for the stereoisomers of these two series have been measured. The difference in the appearance potentials of the ions with a mass at 96 Da is equal to the difference in the enthalpy of formation of the geometric isomers, with a reversed sign.
Citation
Russian Chemical Bulletin
Volume
6

Keywords

Electron ionization, Adiabatic potential, Appearance energy”, ”bicyclo[4.3.0]nonane”, ”bicyclo[4.4.0]decane”

Citation

Mikaia, A. and Zaikin, V. (1980), Ionization and appearance potentials in organic chemistry. 3. Determination of the difference between the enthalpies of formation of cis- and trans-isomers of bicyclo[4.3.0]- nonane and bicyclo[4.4.0]decane Using Appearance Potentials, Russian Chemical Bulletin (Accessed June 19, 2024)

Issues

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Created June 1, 1980, Updated January 27, 2020