Skip to main content

NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.

Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.

U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Improving Accuracy, Precision, Detection Limits, and Sample Throughput in PGAA Using Cold and Thermal Neutrons and Element Ratios

Published

Author(s)

Rick Paul

Abstract

A combination of thermal neutron (TN) and cold neutron (CN) PGAA has been used to improve accuracy, precision, detection limits, and sample throughput time in PGAA. CNPGAA was used to measure element ratios relative to a comparator element, while TNPGAA was used for measurement of the comparator element. Low-Z elements with normally poor sensitivity (C, N, and S) were measured with expanded uncertainties of < 2 % in coal and fuel oil using H as comparator element. Using the combined method, measurements can be made with good counting statistics in less than a third of the time needed for TNPGAA alone, with a 20-30 improvement in detection limits.
Citation
Journal of Radioanalytical and Nuclear Chemistry
Volume
318
Issue
3

Keywords

prompt gamma-ray activation analysis, thermal neutrons, cold neutrons, radiochemistry, analytical chemistry, hydrogen, carbon, nitrogen, sulfur, low-Z elements, elemental analysis

Citation

Paul, R. (2018), Improving Accuracy, Precision, Detection Limits, and Sample Throughput in PGAA Using Cold and Thermal Neutrons and Element Ratios, Journal of Radioanalytical and Nuclear Chemistry, [online], https://doi.org/10.1007/s10967-018-6212-7, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=925901 (Accessed October 2, 2025)

Issues

If you have any questions about this publication or are having problems accessing it, please contact [email protected].

Created December 28, 2018, Updated September 29, 2025
Was this page helpful?