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Effects of stereoisomerism in the mass spectra of 2,4-disubstituted thiacyclohexanes

Published

Author(s)

Anzor I. Mikaia, Elena Trusova, Lyudmila Perepelitchenko, Vladimir G. Zaikin

Abstract

The stereospecificity of fragmentation for isomeric dialkyl- and methyl,phenylthiacyclohexanes under electron ionization are established. Experimentally obtained relative Ionization and appearance energies for the stereoisomers are in agreement with fragmentation mechanisms.
Citation
Chemistry of Heterocyclic Compounds
Volume
17
Issue
3

Keywords

Mass spectra, Ionization energy, Appearance energy, Thiacyclohexanes, Fragmentation mechanism

Citation

Mikaia, A. , Trusova, E. , Perepelitchenko, L. and Zaikin, V. (1980), Effects of stereoisomerism in the mass spectra of 2,4-disubstituted thiacyclohexanes, Chemistry of Heterocyclic Compounds, [online], https://doi.org/10.1007/BF00505985 (Accessed December 3, 2024)

Issues

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Created July 9, 1980, Updated November 10, 2018