Wansleben, M.
, Vinson, J.
, Holfelder, I.
, Kayser, Y.
and Beckhoff, B.
(2018),
Valence-to-core XES of Ti, TiO and TiO2 by means of a double crystal von Hamos spectrometer, X-Ray Spectrometry, [online], https://doi.org/10.1002/xrs.3000
(Accessed March 13, 2025)
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Valence-to-core XES of Ti, TiO and TiO2 by means of a double crystal von Hamos spectrometer
Published
Author(s)
Malte Wansleben, , Ina Holfelder, Yves Kayser, Burkhard Beckhoff
Abstract
We present valence-to-core x-ray emission spectra (vtc-XES) of Ti, TiO and TiO2 by means of a double crystal von Hamos spectrometer based on full-cylinder highly-annealed pyrolytic graphite (HAPG) mosaic crystals. We demonstrate that the double crystal configuration ensures an energy resolution (E/ΔE ≈ 1250) high enough to identify and determine chemical shifts of the Kβ2,5 and Kβ" emission lines. The experimental results are supported by calculations with the ab initio package OCEAN and compared to literature values.Citation
X-Ray Spectrometry
Volume
48
Pub Type
Journals
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Created December 26, 2018, Updated October 12, 2021