NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.
Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.
An official website of the United States government
Here’s how you know
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
A thermochemical study of dissociative ionization of 4,4,-dimethyl-1-thia-4-silacyclohexane and 2,3,3-trimethyl-1-thiacyclopentane. decomposition pathways produce a dimethylsilanethione ion-radical [Me2Si=S]+
Published
Author(s)
Natalya Tarasenko, Vera Volkova, Vladimir G. Zaikin, Alexander Tishenkov, Vitaly Avakyan, leonid Guselnikov, Mikhael Voronkov, SV Kirpichenko, EN Suslova, Anzor I. Mikaia
Abstract
Electron impact and photoionization mass spectrometry methods are employed for the study of dissociative ionization of 4,4-dimethyl-l-thia-4-silacyclohexane and 2,3,3- trimethyl-l-thia-3- silacyclopentane. The ionization energies and appearance energies of major decomposition products are determined.
Citation
Journal of Organometallic Chemistry
Pub Type
Journals
Keywords
Mass spectrometry, Electron ionization, Photoionization, Ionization energy
Tarasenko, N.
, Volkova, V.
, Zaikin, V.
, Tishenkov, A.
, Avakyan, V.
, Guselnikov, L.
, Voronkov, M.
, Kirpichenko, S.
, Suslova, E.
and Mikaia, A.
(1985),
A thermochemical study of dissociative ionization of 4,4,-dimethyl-1-thia-4-silacyclohexane and 2,3,3-trimethyl-1-thiacyclopentane. decomposition pathways produce a dimethylsilanethione ion-radical [Me2Si=S]+, Journal of Organometallic Chemistry
(Accessed October 12, 2025)