Shao, K.
, Pei, J.
, Wang, J.
, Yang, Y.
, Cui, Y.
, Zhou, W.
, Yildirim, T.
, Li, B.
, Chen, B.
and Qian, G.
(2019),
Tailoring the Pore Geometry and Chemistry in Microporous Metal-Organic Frameworks for High Methane Storage Working Capacity, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=928738
(Accessed October 9, 2025)
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Tailoring the Pore Geometry and Chemistry in Microporous Metal-Organic Frameworks for High Methane Storage Working Capacity
Published
Author(s)
Kai Shao, Jiyan Pei, Jia-Xin Wang, Yu Yang, Yuanjing Cui, , , Bin Li, Banglin Chen, Guodong Qian
Abstract
We realize that tailoring pore size/geometry and Chemistry, by virture of alkynl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm3 (STP) cm-3 at 298 K and 5-80 bar.Citation
Chemical Communications
Volume
55
Issue
76
Pub Type
Journals
Download Paper
Keywords
Porous material, Pore engineering, Gas storage
Citation
Issues
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Created November 12, 2019, Updated October 12, 2021