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Tailoring the Pore Geometry and Chemistry in Microporous Metal-Organic Frameworks for High Methane Storage Working Capacity

Published

Author(s)

Kai Shao, Jiyan Pei, Jia-Xin Wang, Yu Yang, Yuanjing Cui, Wei Zhou, Taner N. Yildirim, Bin Li, Banglin Chen, Guodong Qian

Abstract

We realize that tailoring pore size/geometry and Chemistry, by virture of alkynl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm3 (STP) cm-3 at 298 K and 5-80 bar.
Citation
Chemical Communications
Volume
55
Issue
76

Keywords

Porous material, Pore engineering, Gas storage

Citation

Shao, K. , Pei, J. , Wang, J. , Yang, Y. , Cui, Y. , Zhou, W. , Yildirim, T. , Li, B. , Chen, B. and Qian, G. (2019), Tailoring the Pore Geometry and Chemistry in Microporous Metal-Organic Frameworks for High Methane Storage Working Capacity, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=928738 (Accessed June 18, 2024)

Issues

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Created November 12, 2019, Updated October 12, 2021