Orkin, V.
, Khamaganov, V.
and Larin, I.
(2020),
Study of the Reactions of OH with HCl, HBr, and HI between 298 K and 460 K., International Journal of Chemical Kinetics, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=922052
(Accessed October 14, 2025)
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Study of the Reactions of OH with HCl, HBr, and HI between 298 K and 460 K.
Published
Author(s)
, , Igor Larin
Abstract
The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 K to 460 K by using a discharge flow – electron paramagnetic resonance technique. The rate constants at room temperature were found to be kHCl(298 K) = (7.9± 1.3)×10-13 cm3 molecule-1 s- 1 with a weak positive temperature dependence, kHBr(298 K – 460 K) = (1.04± 0.2)×10-11 cm3 molecule-1 s-1, and kHI(298 K) = (3.0± 0.3)×10-13 cm3 molecule-1 s-1, respectively with a weak negative temperature dependence.Citation
International Journal of Chemical Kinetics
Pub Type
Journals
Download Paper
Citation
Issues
If you have any questions about this publication or are having problems accessing it, please contact [email protected].
Created November 24, 2020, Updated September 26, 2023