Wang, Z.
, Wang, H.
, Hsiao, B.
, Gersappe, D.
and Han, C.
(2002),
In-Situ Small-Angle X-Ray Scattering Study of Crystallization in Poly (Ethylene/Hexene) Copolymer Subjected to Step Shear, Journal of the American Chemical Society, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=851993
(Accessed October 17, 2025)
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In-Situ Small-Angle X-Ray Scattering Study of Crystallization in Poly (Ethylene/Hexene) Copolymer Subjected to Step Shear
Published
Author(s)
Z G. Wang, , B S. Hsiao, D Gersappe,
Abstract
Results from in-situ time-resolved SAXS measurement on PEH melt crystallization, subjected to a step shear, indicate that an oriented lamellar structure is formed at the initial crystallization stage upon cessation of the step shear. Randomly distributed lamellae are formed during the late stages. The value of long period estimated along the meridian during the shear-induced crystallization is close to that under the quiescent crystallization condition in PEH.Citation
Journal of the American Chemical Society
Volume
223
Pub Type
Journals
Download Paper
Keywords
crystallization, isotropic, orientation, Poly(ethylene-co-butylene), poly(ethylene-co-hexene), shearing, small-angle X-ray scattering
Citation
Issues
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Created March 31, 2002, Updated October 12, 2021