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Search Publications by: Vladimir L. Orkin (Fed)

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Displaying 1 - 25 of 42

Study of the Reactions of OH with HCl, HBr, and HI between 298 K and 460 K.

November 24, 2020
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Igor Larin
The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 K to 460 K by using a discharge flow – electron paramagnetic resonance technique. The rate constants at room temperature were found to be kHCl(298 K) = (7.9

Hydrofluorocarbons (HFCs)

December 31, 2018
Author(s)
Vladimir L. Orkin, Stephen A. Montzka, Guus J. Velders, Paul B. Krummel, Malte Meinshausen, J. Muhle, Sunyoung Park

Deriving global OH abundance and atmospheric lifetimes for long-lived gases: A search for the alternative reference gas for CH3CCl3.

November 3, 2017
Author(s)
Qing Liang, Martyn P. Chipperfield, Eric L. Fleming, Luke Abraham, Peter Braesicke, James B. Burkholder, John S. Daniels, Sandip Dhomse, Steven C. Hardiman, Charles H. Jackman, Douglas E. Kinnison, Stephen A. Montzka, Olaf Morgenstern, Archie McCulloch, Paul A. Newman, Vladimir L. Orkin, Giovanni Pitari, Matthew Rigby, Eugene Rozanov, Fiona Tummon, Guus J. Velders, Daniele Visioni
An accurate estimate of global hydroxyl radical (OH) abundance is important for projections of air quality, climate, and stratospheric ozone layer recovery. As atmospheric concentration of methyl chloroform (MCF), the commonly used reference gas for OH

Deriving global mean OH and atmospheric lifetimes for ozone-depleting substances and greenhouse gases using observed CH3CCl3 and chemistry-climate models

November 3, 2017
Author(s)
Vladimir L. Orkin, Qing Liang, Martyn P. Chipperfield, Matthew Rigby, Olaf Morgenstern, Guus J. Velders, Luke Abraham, Sandip Dhomse, Eric L. Fleming, Steven C. Hardiman, Daniela Iachetti, Charles H. Jackman, Douglas E. Kinnison, Giovanni Pitari, Eugene Rozanov, Andrea Stenke, Fiona Tummon, James B. Burkholder
Tests using flux-based methyl chloroform (MCF) concentrations from four state-of-the-art chemistry-climate models (CCMs) in the two-dimensional 12-box Bayesian inversion model (IM) indicate that the 12-box IM provides a reasonable estimate of global mean

Photochemical Properties of CH2=CH-CFCl-CF2Br (4-bromo-3-chloro-3,4,4-trifluoro-1-butene) and CH3-O-CH-(CF3)2 (methyl 2,2,2-trifluoroethyl-1-trifluoromethyl ether): OH Reaction Rate Constant, UV and IR Absorption Spectra.

July 7, 2017
Author(s)
Vladimir L. Orkin, Larissa E. Martynova, Michael J. Kurylo III
Abstract Rate constants for the reactions of hydroxyl radicals (OH) with methyl 2,2,2-trifluoroethyl-1-trifluoromethyl ether (CH3-O-CH-(CF3)2 and 4-bromo-3-chloro-3,4,4-trifluoro-1-butene (CH2=CH-CFCl-CF2Br) have been measured over the temperature range

Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18

October 30, 2015
Author(s)
Vladimir L. Orkin, James B. Burkholder, S. P. Sander, J. P. D. Abbatt D. Abbatt, J. R. Barker, Robert E. Huie, C E. Kolb, Michael J. Kurylo III, David M. Wilmouth, P. H. Wine
This is the eighteenth in a series of evaluated sets of rate constants, photochemical cross sections, heterogeneous parameters, and thermochemical parameters compiled by the NASA Panel for Data Evaluation. The data are used primarily to model stratospheric

The impact of current CH4 and N2O atmospheric loss process uncertainties on calculated ozone abundances and trends

May 29, 2015
Author(s)
Vladimir L. Orkin, Eric L. Fleming, Christian George, Dwayne E. Heard, Charles H. Jackman, Michael J. Kurylo , Abdelwahid Mellouki , J B. Burkholder
The atmospheric loss processes of N2O and CH4, their estimated uncertainties, lifetimes, and impacts on ozone abundance and long-term trends are examined using atmospheric model calculations and updated kinetic and photochemical parameters and uncertainty

Update on Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the Montreal Protocol, Chapter 1 in Scientific Assessment of Ozone Depletion: 2014, Global Ozone Research and Monitoring Project-Report No.55, 416 pp., World Meteorological Organiz

December 30, 2014
Author(s)
Lucy J. Carpenter, Stefan Reimann, Andreas Engel, Stephen Montzka, James B. Burkholder, Cathy Clerbaux, Bradley Hall, Shari A. Yvon-Lewis, Donald R. Blake, Marcel Dorf, Geoffre S. Dutton, Paul J. Fraser, Lucien Froidevaux, Fran?ois Hendrick, Jianxin Hu, Ashley Jones, Paul B. Krummel, Lambert J. Kuijpers, Michael J. Kurylo, Qing Liang, Emmanuel Mahieu, Jens M?hle, Simon O?Doherty, Keiichi Ohnishi, Vladimir L. Orkin, Klaus Pfeilsticker, Matt Rigby, Isobel J. Simpson, Yoko Yokouchi
Changes in the global atmospheric abundance of a substance are determined by the balance between its emissions and removal. Declines observed for ozone-depleting substances (ODSs) controlled under the Montreal Protocol are due to global emission reductions

Photochemical Properties of Hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: Reactivity toward OH, IR Absorption Cross Sections, Atmospheric Lifetimes and Global Warming Potentials

September 22, 2014
Author(s)
Vladimir L. Orkin, Victor Khamaganov, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially fluorinated ethers, CH3OCF3 (kHFE-143a), CH3OCHF2 (kHFE-152a), and CHF2OCH2CF3 (kHFE-245fa), were measured using a discharge flow – electron paramagnetic resonance technique

Chapter 3 Evaluation of Atmospheric Loss Processes

December 31, 2013
Author(s)
Vladimir L. Orkin, James B. Burkholder, Wahid Mellouki, Eric L. Fleming, Christian George, Charles H. Jackman, Timothy J. Wallington , Michael J. Kurylo , Dwayne E. Heard, William H. Swartz
Hydroxyl radical (OH), electronically excited atomic oxygen (O(1D)), and atomic chlorine (Cl) reaction rate coefficient data were evaluated and the estimated uncertainties in the recommended parameters reduced, in general, from those currently recommended

Photochemical Properties of Some Cl-Containing Halogenated Alkanes

May 31, 2013
Author(s)
Vladimir L. Orkin, Victor Khamaganov, E. E. Kasimovskaya, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially halogenated alkanes, CHCl3 (kMC), CHFClCFCl2 (k122a), and CH2CFCl2 (k132c), were measured using a discharge flow – electron paramagnetic resonance technique over the temperature