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Displaying 1626 - 1650 of 4041

Isotope Dilution Mass Spectrometry For Quantitative Elemental Analysis Of Powdered Samples By Radiofrequency Pulsed Glow Discharge Time Of Flight Mass Spectrometry

October 15, 2013
Author(s)
John L. Molloy, Julian Malherbe, Fanny Claverie, Beatriz Fernandez, Aitor Alvarez-Toral, Alfredo Sanz-Medel, Rosario Pereiro
In recent years particular effort is being devoted to the development of pulsed glow discharges (PGDs) for mass spectrometry because this powering operation mode could offer important ionization analytical advantages. However, the capabilities of

Time-Resolved Infrared Studies of a Trimethylphosphine Model Derivative of [FeFe]-Hydrogenase

October 1, 2013
Author(s)
Edwin J. Heilweil, Christopher J. Stromberg, Melissa Johnson, James Thuman, Roger G. Letterman, Webster E. Charles
Model compounds that structurally mimic the hydrogen-producing active site of [FeFe] hydrogenases have been explored. In order to explore potential ground-state electronic structure effects on reaction mechanisms compared to hexacarbonyl derivatives, the

Rapid scan absorption spectroscopy using a waveform-driven electro-optic phase modulator in the 1.6- 1.65 ym region

September 25, 2013
Author(s)
Kevin O. Douglass, Stephen Maxwell, Gar W. Truong, Roger D. van Zee, Joseph T. Hodges, David Long, David F. Plusquellic
A method is reported for performing fast optical frequency scans over a bandwidth of 36.9 GHz and at a sweep rate of 40 kHz using a single second-order sideband from an electro-optic phase modulator driven by an arbitrary waveform generator. Single

Effects of Desialylation on Human alpha1-Acid Glycoprotein-Ligand Interactions

September 16, 2013
Author(s)
Richard Y. Huang, Jeffrey W. Hudgens
Human α1-Acid Glycoprotein (AGP), an acute phase glycoprotein, exists predominantly in blood. With its ability to bind basic, lipophilic, and acidic drugs, AGP has served as a drug carrier. It has been shown that the carbohydrate composition of AGP changes

A Missing Link in the Cascade Formation of High Symmetry Fullerene Cages

September 15, 2013
Author(s)
Dan Bearden, Jianyuan Zhang, Harry C. Dorn
Before the discovery of graphene, many versions of a “bottom-up” fullerene formation mechanism had been advanced starting with carbide (C2) that forms small carbon cluster chains and rings. However, in recent years evidence is emerging suggesting a “top

Elemental analyses of soil and sediment fused with lithium borate using isotope dilution laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-IDMS)

September 2, 2013
Author(s)
John L. Molloy, Julian Malherbe, Fanny Claverie, Aitor Alvarez-Toral, Beatriz Fernandez, Rosario Pereiro
Quantitative analysis using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) remains challenging primarily due to elemental fractionation effects and to the lack of appropriate standards available for the wide variety of samples of
Displaying 1626 - 1650 of 4041
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