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Robert D. Chirico, Russell D. Johnson III, William Steele
Measurements leading to the calculation of the standard thermodynamic properties for gaseous 2,6-dimethylquinoline (Chemical Abstracts registry number [877-43-0]) are reported. Experimental methods included adiabatic heat-capacity calorimetry, vibrating
Densities, vapor pressures, and the critical point were measured for dimethyl ether, thus filling several gaps in the thermodynamic data for this compound. Densities were measured with a computer-controlled high temperature, high-pressure vibrating-tube
Michael D. Frenkel, Robert D. Chirico, Vladimir Diky, Chris D. Muzny, Qian Dong, K N. Marsh, John H. Dymond, William A. Wakeham, Stephen E. Stein, Erich Koenigsberger, Anthony R. Goodwin, Joe W. Magee, Michiel Thijssen, William M. Haynes, Suphat Watanasiri, Marco Satyro, Martin Schmidt, Andrew I. Johns, Gary R. Hardin
Thermodynamic data often represent a key resource in the search for new relationships between properties of chemical systems that constitutes the basis of the scientific discovery process. In addition, thermodynamic information is critical for development
In previous work, several significant improvements in the measurement of distillation curves for complex fluids were introduced. The modifications to the classical measurement provide for (1) temperature and volume measurement(s) of low uncertainty, and
In previous work, several significant improvements in the measurement of distillation curves for complex fluids were introduced. The modifications to the classical measurement provide for (1) temperature and volume measurement(s) of low uncertainty, (2)
The development of technical equations of state using the 12-parameter Span-Wagner functional form for four siloxanes is presented in two parts. The fluids under investigation include hexamethyldisiloxane (MM), tetradecamethylhexasiloxane (MD4M)
In this short note we present a method and a simple apparatus for use with simple, fractional and steam distillation operations in which the operator requires a precise measurement of instantaneous distillate composition as the distillation proceeds. There
We used a quasi-spherical cavity as an acoustic and microwave resonator to measure the thermodynamic temperatures T of the triple points of mercury, argon, neon, and equilibrium hydrogen, and to measure the difference T - T90, in the range 7 K to 273 K.
Michael D. Frenkel, Robert D. Chirico, Vladimir Diky, Xinjian Yan, Qian Dong, Chris D. Muzny
The first full-scale software implementation of the dynamic data evaluation concept {ThermoData Engine (TDE)} is described for thermophysical and thermochemical property data. This concept requires the development of large electronic databases capable of
Water and aqueous systems are widely used in metrology, which is a major focus of the National Institute of Standards and Technology (NIST). Standards such as those produced by IAPWS can be used to calibrate instruments and validate protocols. In this work
Vladimir Rohac, Kvetoslav Ruzicka, Vlastimil Ruzicka, Dzmitry H. Zaitsau, Gennady J. Kabo, Vladimir Diky, Karel Aim
Measurements of vapour pressure in the liquid phase and of enthalpy of vaporisation and results of calculation of ideal gas properties for diethyl phthalate are reported. The method of comparative ebulliometry, the static method, and the Knudsen mass loss