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Quest for a Highly Connected Robust Porous Metal-Organic Framework on the Basis of a Bifunctional Linear Linker and a Rare Heptanuclear Zinc Cluster

Published

Author(s)

Wen-Yang Gao, Rong Cai, Le Meng, Lukasz Wojtas, Wei Zhou, Taner N. Yildirim, Xiaodong Shi, Shengqian Ma

Abstract

A strategy for achieving high-connected robust MOFs by linear ligands is exemplified by the construction of MTAF-4, a rare (6, 9)-connected 10 MOF based upon the custom-designed bifunctional linear ligand, 4-(1,2,3-triazol-4-yl)-benzoate that connects two types of high-connected zinc cluster moieties generated in situ. MTAF-4 is robust and permanently microporous and demonstrates interesting high-pressure gas 15 sorption performances.
Citation
Chemical Communications
Volume
49

Keywords

Metal organic frameworks, Gas adsorption

Citation

Gao, W. , Cai, R. , Meng, L. , Wojtas, L. , Zhou, W. , Yildirim, T. , Shi, X. and Ma, S. (2013), Quest for a Highly Connected Robust Porous Metal-Organic Framework on the Basis of a Bifunctional Linear Linker and a Rare Heptanuclear Zinc Cluster, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=914765 (Accessed May 29, 2024)

Issues

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Created November 17, 2013, Updated October 12, 2021