Gao, W.
, Cai, R.
, Meng, L.
, Wojtas, L.
, Zhou, W.
, Yildirim, T.
, Shi, X.
and Ma, S.
(2013),
Quest for a Highly Connected Robust Porous Metal-Organic Framework on the Basis of a Bifunctional Linear Linker and a Rare Heptanuclear Zinc Cluster, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=914765
(Accessed October 17, 2025)
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Quest for a Highly Connected Robust Porous Metal-Organic Framework on the Basis of a Bifunctional Linear Linker and a Rare Heptanuclear Zinc Cluster
Published
Author(s)
Wen-Yang Gao, Rong Cai, Le Meng, Lukasz Wojtas, , , Xiaodong Shi, Shengqian Ma
Abstract
A strategy for achieving high-connected robust MOFs by linear ligands is exemplified by the construction of MTAF-4, a rare (6, 9)-connected 10 MOF based upon the custom-designed bifunctional linear ligand, 4-(1,2,3-triazol-4-yl)-benzoate that connects two types of high-connected zinc cluster moieties generated in situ. MTAF-4 is robust and permanently microporous and demonstrates interesting high-pressure gas 15 sorption performances.Citation
Chemical Communications
Volume
49
Pub Type
Journals
Download Paper
Keywords
Metal organic frameworks, Gas adsorption
Citation
Issues
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Created November 17, 2013, Updated October 12, 2021