Quest for a Highly Connected Robust Porous Metal-Organic Framework on the Basis of a Bifunctional Linear Linker and a Rare Heptanuclear Zinc Cluster
Wen-Yang Gao, Rong Cai, Le Meng, Lukasz Wojtas, Wei Zhou, Taner N. Yildirim, Xiaodong Shi, Shengqian Ma
A strategy for achieving high-connected robust MOFs by linear ligands is exemplified by the construction of MTAF-4, a rare (6, 9)-connected 10 MOF based upon the custom-designed bifunctional linear ligand, 4-(1,2,3-triazol-4-yl)-benzoate that connects two types of high-connected zinc cluster moieties generated in situ. MTAF-4 is robust and permanently microporous and demonstrates interesting high-pressure gas 15 sorption performances.
, Cai, R.
, Meng, L.
, Wojtas, L.
, Zhou, W.
, Yildirim, T.
, Shi, X.
and Ma, S.
Quest for a Highly Connected Robust Porous Metal-Organic Framework on the Basis of a Bifunctional Linear Linker and a Rare Heptanuclear Zinc Cluster, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=914765
(Accessed November 29, 2023)