Quantifying Stability of Trace Explosives under Different Environmental Conditions

Edward R. Sisco; Marcela N. Najarro; Daniel V. Samarov; Jeffrey A. Lawrence

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PUBLICATIONS

Quantifying Stability of Trace Explosives under Different Environmental Conditions

Published

April 1, 2017

Author(s)

Edward R. Sisco, Marcela N. Najarro, Daniel V. Samarov, Jeffrey A. Lawrence

Abstract

This work investigates the stability of trace deposits of six explosives (ETN, PETN, RDX, HMX, TNT, and Tetryl) to determine environmental stabilities and lifetimes. Explosives were inkjet printed directly onto PTFE coated fiberglass substrates and exposed to one of seven environmental conditions for 42 days. The remaining explosives were then quantified using electrospray ionization mass spectrometry (ESI-MS) to determine stability of the explosive as a function of time and environmental exposure. Stability was found to be exposure and compound dependent with lowest sample losses observed for HMX, RDX, and PETN while substantial and rapid losses were observed for ETN and TNT. The results of this work highlights the potential fate of explosive traces when exposed to various environments.

Citation

Talanta

Volume

165

Pub Type

Journals

Download Paper

https://doi.org/10.1016/j.talanta.2016.12.029

Keywords

Trace Explosives, Mass Spectrometry, Degradation, Stability, Quantification

Analytical chemistry

Created April 1, 2017, Updated November 10, 2018