NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.
Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.
An official website of the United States government
Here’s how you know
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Properties of Gases and Liquids. Chapter 3. Pure-component constants
Published
Author(s)
Vladimir Diky, Thomas Knotts, Vincent Wilding, Rich Elliott
Abstract
The properties of pure components are important for all aspects of process design and optimization. Pure-component properties also underlie much of the observed behavior of mixtures. For example, property models intended for the whole range of composition must give pure component properties at the pure component limits. In addition, pure-component property constants are often used as the basis for models such as corresponding states correlations. As a r esult, w e fi rst s tudy methods for obtaining pure-component constants of the more commonly used properties and show how they can be estimated if no experimental data are available. These include the vapor-liquid critical properties, atmospheric melting and boiling temperatures, the acentric factor, and dipole moments.
Diky, V.
, Knotts, T.
, Wilding, V.
and Elliott, R.
(2023),
Properties of Gases and Liquids. Chapter 3. Pure-component constants, McGraw-Hill, New York, NY, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=934087
(Accessed October 22, 2025)