Baranov, Y.
, Lafferty, W.
, Fraser, G.
and Vigasin, A.
(2003),
On the Origin of the Band Structure Observed in the Collision-Induced Absorption Bands of CO<sub>2</sub>, Journal of Molecular Spectroscopy
(Accessed December 13, 2024)
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On the Origin of the Band Structure Observed in the Collision-Induced Absorption Bands of CO2
Published
Author(s)
Y I. Baranov, , , A A. Vigasin
Abstract
A more complete analysis of the dimer structure observed on top of the collision-induced absorption bands of carbon dioxide is presented. The analysis treats the carbon dioxide dimer as an asymmetric rotor with a and b type infrared transitions and rotational constants similar to that observed in a molecular beam spectrum of the dimer, in contrast to a previous modeling which considered the dimer as a prolate symmetric rotor with a pure a-type infrared band. The analysis does not require invoking a large change in the C C bond length previously determined in the molecular beam study.Citation
Journal of Molecular Spectroscopy
Volume
218
Issue
No. 2
Pub Type
Journals
Keywords
carbon dioxide dimmer, collision-induced absorption, dimer profile
Citation
Issues
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Created March 31, 2003, Updated October 12, 2021