Halder, A.
, Klein, R.
, McGuirk, C.
and Lively, R.
(2022),
Multivariate Zeolitic Imidazolate Frameworks with an Inverting Trend in Flexibility, Chemical Communications, [online], https://doi.org/10.1039/d2cc04362a, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=935317
(Accessed April 27, 2024)
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Multivariate Zeolitic Imidazolate Frameworks with an Inverting Trend in Flexibility
Published
Author(s)
Arijit Halder, , C. McGuirk, Rachel Lively
Abstract
Through systematic linker substitution in a flexible zeolitic imidazolate framework (ZIF) with step-shaped adsorption–desorption, structural intermediates between the known open and closed phases were isolated. Reflecting this, modulative sorption behaviour with an inverting adsorption pressure trend is observed, highlighting how linker substitution modifies the energetic landscape of framework flexibility.Citation
Chemical Communications
Volume
58
Issue
81
Pub Type
Journals
Download Paper
Keywords
gas storage, flexible MOF, multivariate, metal–organic framework
Citation
Created November 10, 2022, Updated March 11, 2024