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Multivariate Zeolitic Imidazolate Frameworks with an Inverting Trend in Flexibility

Published

Author(s)

Arijit Halder, Ryan Klein, C. McGuirk, Rachel Lively

Abstract

Through systematic linker substitution in a flexible zeolitic imidazolate framework (ZIF) with step-shaped adsorption–desorption, structural intermediates between the known open and closed phases were isolated. Reflecting this, modulative sorption behaviour with an inverting adsorption pressure trend is observed, highlighting how linker substitution modifies the energetic landscape of framework flexibility.
Citation
Chemical Communications
Volume
58
Issue
81

Keywords

gas storage, flexible MOF, multivariate, metal–organic framework

Citation

Halder, A. , Klein, R. , McGuirk, C. and Lively, R. (2022), Multivariate Zeolitic Imidazolate Frameworks with an Inverting Trend in Flexibility, Chemical Communications, [online], https://doi.org/10.1039/d2cc04362a, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=935317 (Accessed April 23, 2024)
Created November 10, 2022, Updated March 11, 2024