Nyden, M.
, Forney, G.
and Brown, J.
(1992),
Molecular Modeling of Polymer Flammability: Application to the Design of Flame-Resistant Polyethylene, Macromolecules, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=912809
(Accessed October 27, 2025)
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Molecular Modeling of Polymer Flammability: Application to the Design of Flame-Resistant Polyethylene
Published
Author(s)
, ,
Abstract
Molecular dyanmic simulations of the thermal degradation of polyethylene were used to idenfity factors which might be effective in reducing polymer flammability by promoting the formation of a residual char. Computer movies of the calculated trajectories indicate that corss-linked polymers, such as those obtained from exposure of polyethylene to ionizing radiation, will undergo further corss-linking when burned, eventually forming a high molecular weight, thermally stable char. This prediction was confirmed in flammability tests of gamma-ray-irradiated polyethylene.Citation
Macromolecules
Volume
25
Issue
No. 6
Pub Type
Journals
Download Paper
Keywords
polyethylenes, flammability, thermal degradation, char, crosslinking, molecular weight, simulation, validation, ionizing radiation
Citation
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Created January 1, 1992, Updated February 19, 2017