Ye, Y.
, Lin, R.
, Cui, H.
, Alsalme, A.
, Zhou, W.
, Yildirim, T.
, Zhang, Z.
, Xiang, S.
and Chen, B.
(2020),
A Microporous Metal-Organic Framework with Naphthalene Diimide Groups for High Methane Storage, Dalton Transactions, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=928325
(Accessed April 25, 2024)
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A Microporous Metal-Organic Framework with Naphthalene Diimide Groups for High Methane Storage
Published
Author(s)
Yingxiang Ye, Rui-Biao Lin, Hui Cui, Ali Alsalme, , , Zhangjing Zhang, Shengchang Xiang, Banglin Chen
Abstract
We reported a microporous MOF FJU-101 with open naphthalene diimide functional groups for room temperature (RT) high methane storage. At RT and 65 bar, the total volumetric CH4 storage capacity of 212 cm-3 in FJU-101a is significantly higher than the isoreticular MFM-130a and UTSA-40a. The enhanced methane uptake in FJU-101a is attributed to the polar carbonyl sites, which can generate strong electrostatic interactions with CH4 molecules.Citation
Dalton Transactions
Volume
49
Issue
12
Pub Type
Journals
Download Paper
Keywords
porous materials, gas storage
Citation
Created March 27, 2020, Updated October 12, 2021